高熵合金的低温塑性变形机制及强韧化研究进展

doi:10.11900/0412.1961.2022.00598

金属学报

2023, Vol. 59

Issue (6): 727-743 DOI: 10.11900/0412.1961.2022.00598

综述

本期目录 | 过刊浏览

高熵合金的低温塑性变形机制及强韧化研究进展

刘俊鹏¹(

), 陈浩¹, 张弛¹, 杨志刚¹, 张勇²^,³, 戴兰宏⁴

¹清华大学材料学院教育部先进材料重点实验室北京 100084
²北京科技大学新金属材料国家重点实验室北京 100083
³北京材料基因工程高精尖创新中心北京 100083
⁴中国科学院力学研究所非线性力学国家重点实验室北京 100190

Progress of Cryogenic Deformation and Strengthening-Toughening Mechanisms of High-Entropy Alloys

LIU Junpeng¹(

), CHEN Hao¹, ZHANG Chi¹, YANG Zhigang¹, ZHANG Yong²^,³, DAI Lanhong⁴

¹Key Laboratory of Advanced Materials of Ministry of Education, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
²State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
³Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing 100083, China
⁴State Key Laboratory of Nonlinear Mechanics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China

引用本文:

刘俊鹏, 陈浩, 张弛, 杨志刚, 张勇, 戴兰宏. 高熵合金的低温塑性变形机制及强韧化研究进展[J]. 金属学报, 2023, 59(6): 727-743.
Junpeng LIU, Hao CHEN, Chi ZHANG, Zhigang YANG, Yong ZHANG, Lanhong DAI. Progress of Cryogenic Deformation and Strengthening-Toughening Mechanisms of High-Entropy Alloys[J]. Acta Metall Sin, 2023, 59(6): 727-743.

全文: PDF(4309 KB) HTML

摘要:

高熵合金是由多种主要元素组成的新型金属材料，固有的多主元和构型熵高等特点，使其具备诸多优异的力学及物理化学性能，从而引起了研究人员的广泛关注。在低温工程应用方面，高熵合金优异的强塑性、良好的韧性和抗冲击能力、较高的相稳定性等特点使其在深空探测、低温超导、气体工业等领域极具应用前景。本文综述了高熵合金的低温研究进展，详细总结了高熵合金在低温环境的变形机制及强韧化机理，并结合传统低温工程材料的性能对比，展望了高熵合金未来低温工程应用的主要方向。

关键词 ：高熵合金, 低温性能, 变形机理, 强韧化策略

Abstract：

Owing to the multi-principal element and higher intrinsic configurational entropy, high-entropy alloys exhibit excellent mechanical and physicochemical performance, which has garnered extensive attention from researchers. By virtue of the excellent performances in terms of superior strength, ductility, toughness, impact resistance property, and adjustable phase stability, especially in cryogenic environments, high-entropy alloys have broad application prospects in fields such as deep-space exploration, low temperature superconducting, and the gas industry. In this paper, the deformation and strengthening-toughening mechanisms of high-entropy alloys are summarized by reviewing the cryogenic progress. Furthermore, the promising research directions of high-entropy alloys in cryogenic engineering application combined with the performance of traditional cryogenic materials are also presented.

Key words： high-entropy alloy cryogenic property deformation mechanism strengthening-toughening strategy

收稿日期: 2022-11-21

ZTFLH:

TG139

基金资助:国家重点研发计划项目(2022YFE0110800);国家重点研发计划项目(2021YFB3702300);国家自然科学基金项目(52101169);国家自然科学基金项目(52273280)

通讯作者: 刘俊鹏，liujunpeng@mail.tsinghua.edu.cn，主要从事高熵合金的基础研究

Corresponding author: LIU Junpeng, Tel:(010)62781646, E-mail: liujunpeng@mail.tsinghua.edu.cn

作者简介: 刘俊鹏，男，1988年生，博士

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	刘俊鹏
	陈浩
	张弛
	杨志刚
	张勇
	戴兰宏
44.8K

链接本文:

https://www.ams.org.cn/CN/10.11900/0412.1961.2022.00598 或 https://www.ams.org.cn/CN/Y2023/V59/I6/727

图1 具有严重晶格畸变特征的高熵合金化学无序原子结构示意图[3]Color online

图2 低温轧制后CoCrFeNiMn高熵合金的室温及低温拉伸性能[9]Color online

图3 Ni30Co30Fe13Cr15Al6Ti6高熵合金低温变形后的位错组态[11]Color online(a) TEM image of the dislocation structure of the deformed alloy at 77 K(b) nano-spaced stacking fault (SF) network in the deformed alloy

图4 高熵合金中由位错反应生成的Lomer-Cottrell (L-C)锁[66]Color omline

图5 Al3.6Co27.3Cr18.2Fe18.2Ni27.3Ti5.4高熵合金中L12析出相低温变形后的孪晶特征[68]Color online(a) HRTEM image (b) enlarged image of the yellow rectangle in Fig.5a (c) SAED pattern of the twinning feature

图6 B掺杂Fe40Mn40Co10Cr10高熵合金低温变形组织中的短程有序结构[93]Color online(a) TEM image(b) SAED pattern of the SRO feature (The SRO-generated reflections are seen only under [112] zone axis marked by yellow arrows)

图7 CoCrFeNi高熵合金极低温变形时的孪晶及相变特征[10]Color online(a) TEM image and SAED pattern (inset), showing the twins and fcc-hcp phase transition occur in the sample(b) HRTEM image (T—twins)(c) atomic image of the enlarged red rectangle in Fig.7b, witness the hcp SF appears in the sample

图8 高熵合金和其他低温金属材料的超低温性能对比[10]Color online

图9 铁基中熵合金的低温硬化机制示意图[95]Color online

图10 Fe55Co17.5Cr12.5Ni10Mo3C2高熵合金的微观形貌、力学性能及低温组织演变特征[91]Color online(a) TEM image and SAED patterns of the M6C (inset A) and M23C6 (inset B) precipitates in the original sample(b) tensile properties at room and cryogenic temperatures(c) EBSD images of HEA alloy during the tensile test at 77 K (εT—true strain)

图11 AlCoCrFeNi2.1高熵合金的共晶组织[98]

图12 Al19Co20Fe20Ni41共晶高熵合金两相组织的低温变形特点[100]

图13 热拉拔CoCrNi丝材的室温及低温力学性能[49]

图14 AlCoCrFeNi2.1共晶高熵合金丝材低温拉伸时的组织特征[102](a) deformation twins (DT) and dislocation cells (DC) in fcc matrix and microstructure refinement deriving from dense dislocation cross-slip in B2 phase of EHEA wire during cryogenic tension(b) SAED pattern of B2 phase (green circle) in Fig.14a

图15 不同类型高熵合金的低温强度-延伸率Ashby图

1	Cantor B, Chang I T H, Knight P, et al. Microstructural development in equiatomic multicomponent alloys [J]. Mater. Sci. Eng., 2004, A375-377: 213
2	Yeh J W, Chen S K, Lin S J, et al. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes [J]. Adv. Eng. Mater., 2004, 6: 299 doi: 10.1002/(ISSN)1527-2648
3	Zhang Y, Zuo T T, Tang Z, et al. Microstructures and properties of high-entropy alloys [J]. Prog. Mater. Sci., 2014, 61: 1 doi: 10.1016/j.pmatsci.2013.10.001
4	Otto F, Dlouhý A, Somsen C, et al. The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy [J]. Acta Mater., 2013, 61: 5743 doi: 10.1016/j.actamat.2013.06.018
5	Zaddach A J, Niu C, Koch C C, et al. Mechanical properties and stacking fault energies of NiFeCrCoMn high-entropy alloy [J]. JOM, 2013, 65: 1780 doi: 10.1007/s11837-013-0771-4
6	Huang S, Li W, Lu S, et al. Temperature dependent stacking fault energy of FeCrCoNiMn high entropy alloy [J]. Scr. Mater., 2015, 108: 44 doi: 10.1016/j.scriptamat.2015.05.041
7	Gludovatz B, Hohenwarter A, Thurston K V S, et al. Exceptional damage-tolerance of a medium-entropy alloy CrCoNi at cryogenic temperatures [J]. Nat. Commun., 2016, 7: 10602 doi: 10.1038/ncomms10602 pmid: 26830651
8	Li D Y, Li C X, Feng T, et al. High-entropy Al_0.3CoCrFeNi alloy fibers with high tensile strength and ductility at ambient and cryogenic temperatures [J]. Acta Mater., 2017, 123: 285 doi: 10.1016/j.actamat.2016.10.038
9	Liu J P. Cryogenic deformation mechanisms and serration behavior of CoCrFeNi FCC high-entropy alloys [D]. Beijing: University of Science and Technology Beijing, 2018
9	刘俊鹏. CoCrFeNi系面心立方高熵合金的低温变形机制及锯齿流变行为 [D]. 北京: 北京科技大学, 2018
10	Liu J P, Guo X X, Lin Q Y, et al. Excellent ductility and serration feature of metastable CoCrFeNi high-entropy alloy at extremely low temperatures [J]. Sci. China Mater., 2019, 62: 853 doi: 10.1007/s40843-018-9373-y
11	Yang T, Zhao Y L, Luan J H, et al. Nanoparticles-strengthened high-entropy alloys for cryogenic applications showing an exceptional strength-ductility synergy [J]. Scr. Mater., 2019, 164: 30 doi: 10.1016/j.scriptamat.2019.01.034
12	Naeem M, He H Y, Harjo S, et al. Temperature-dependent hardening contributions in CrFeCoNi high-entropy alloy [J]. Acta Mater., 2021, 221: 117371 doi: 10.1016/j.actamat.2021.117371
13	Liu D, Yu Q, Kabra S, et al. Exceptional fracture toughness of CrCoNi-based medium- and high-entropy alloys at 20 kelvin [J]. Science, 2022, 378: 978 doi: 10.1126/science.abp8070 pmid: 36454850
14	Zhou Y J, Zhang Y, Wang Y L, et al. Solid solution alloys of AlCoCrFeNiTi _x with excellent room-temperature mechanical properties [J]. Appl. Phys. Lett., 2007, 90: 181904 doi: 10.1063/1.2734517
15	Qiao J W, Ma S G, Huang E W, et al. Microstructural characteristics and mechanical behaviors of AlCoCrFeNi high-entropy alloys at ambient and cryogenic temperatures [J]. Mater. Sci. Forum., 2011, 688: 419 doi: 10.4028/www.scientific.net/MSF.688
16	Gludovatz B, Hohenwarter A, Catoor D, et al. A fracture-resistant high-entropy alloy for cryogenic applications [J]. Science, 2014, 345: 1153 doi: 10.1126/science.1254581 pmid: 25190791
17	Hemphill M A, Yuan T, Wang G Y, et al. Fatigue behavior of Al_0.5CoCrCuFeNi high entropy alloys [J]. Acta Mater., 2012, 60: 5723 doi: 10.1016/j.actamat.2012.06.046
18	Li J M, Yang X, Zhu R L, et al. Corrosion and serration behaviors of TiZr_0.5NbCr_0.5V _x Mo _y high entropy alloys in aqueous environments [J]. Metals, 2014, 4: 597 doi: 10.3390/met4040597
19	Xia S Q, Yang X, Yang T F, et al. Irradiation resistance in Al _x CoCrFeNi high entropy alloys [J]. JOM, 2015, 67: 2340 doi: 10.1007/s11837-015-1568-4
20	Shi Y Z, Yang B, Xie X, et al. Corrosion of Al _x CoCrFeNi high-entropy alloys: Al-content and potential scan-rate dependent pitting behavior [J]. Corros. Sci., 2017, 119: 33 doi: 10.1016/j.corsci.2017.02.019
21	Luo H, Sohn S S, Lu W J, et al. A strong and ductile medium-entropy alloy resists hydrogen embrittlement and corrosion [J]. Nat. Commun., 2020, 11: 3081 doi: 10.1038/s41467-020-16791-8 pmid: 32555177
22	Pu Z, Chen Y, Dai L H. Strong resistance to hydrogen embrittlement of high-entropy alloy [J]. Mater. Sci. Eng., 2018, A736: 156
23	Yao Y G, Huang Z H, Xie P F, et al. Carbothermal shock synthesis of high-entropy-alloy nanoparticles [J]. Science, 2018, 359: 1489 doi: 10.1126/science.aan5412 pmid: 29599236
24	Cheng Z, Wang S Z, Wu G L, et al. Tribological properties of high-entropy alloys: A review [J]. Int. J. Miner. Metall. Mater., 2022, 29: 389 doi: 10.1007/s12613-021-2373-4
25	Luan H W, Shao Y, Li J F, et al. Phase stabilities of high entropy alloys [J]. Scr. Mater., 2020, 179: 40 doi: 10.1016/j.scriptamat.2019.12.041
26	Song H Q, Tian F Y, Hu Q M, et al. Local lattice distortion in high-entropy alloys [J]. Phys. Rev. Mater., 2017, 1: 023404
27	Lee C, Song G, Gao M C, et al. Lattice distortion in a strong and ductile refractory high-entropy alloy [J]. Acta Mater., 2018, 160: 158 doi: 10.1016/j.actamat.2018.08.053
28	Tong Y, Jin K, Bei H, et al. Local lattice distortion in NiCoCr, FeCoNiCr and FeCoNiCrMn concentrated alloys investigated by synchrotron X-ray diffraction [J]. Mater. Des., 2018, 155: 1 doi: 10.1016/j.matdes.2018.05.056
29	Sohn S S, Da Silva A K, Ikeda Y, et al. Ultrastrong medium-entropy single-phase alloys designed via severe lattice distortion [J]. Adv. Mater., 2019, 31: 1807142 doi: 10.1002/adma.v31.8
30	Lee C, Chou Y, Kim G, et al. Lattice-distortion-enhanced yield strength in a refractory high-entropy alloy [J]. Adv. Mater., 2020, 32: 2004029 doi: 10.1002/adma.v32.49
31	Li J, Chen Y, He Q F, et al. Heterogeneous lattice strain strengthening in severely distorted crystalline solids [J]. Proc. Natl. Acad. Sci., 2022, 119: e2200607119 doi: 10.1073/pnas.2200607119
32	Tsai M H, Wang C W, Lai C H, et al. Thermally stable amorphous (AlMoNbSiTaTiVZr)₅₀N₅₀ nitride film as diffusion barrier in copper metallization [J]. Appl. Phys. Lett., 2008, 92: 052109
33	Hsiao Y T, Tung C H, Lin S J, et al. Thermodynamic route for self-forming 1.5 nm V-Nb-Mo-Ta-W high-entropy alloy barrier layer: Roles of enthalpy and mixing entropy [J]. Acta Mater., 2020, 199: 107 doi: 10.1016/j.actamat.2020.08.029
34	Yao M J, Pradeep K G, Tasan C C, et al. A novel, single phase, non-equiatomic FeMnNiCoCr high-entropy alloy with exceptional phase stability and tensile ductility [J]. Scr. Mater., 2014, 72-73: 5 doi: 10.1016/j.scriptamat.2013.09.030
35	Tang Z, Gao M C, Diao H Y, et al. Aluminum alloying effects on lattice types, microstructures, and mechanical behavior of high-entropy alloys systems [J]. JOM, 2013, 65: 1848 doi: 10.1007/s11837-013-0776-z
36	Ranganathan S. Alloyed pleasures: Multimetallic cocktails [J]. Curr. Sci., 2003, 85: 1404
37	Lei Z F, Liu X J, Wu Y, et al. Enhanced strength and ductility in a high-entropy alloy via ordered oxygen complexes [J]. Nature, 2018, 563: 546 doi: 10.1038/s41586-018-0685-y
38	Lin Q Y, Liu J P, An X H, et al. Cryogenic-deformation-induced phase transformation in an FeCoCrNi high-entropy alloy [J]. Mater. Res. Lett., 2018, 6: 236 doi: 10.1080/21663831.2018.1434250
39	Pu Z, Xie Z C, Sarmah R, et al. Spatio-temporal dynamics of jerky flow in high-entropy alloy at extremely low temperature [J]. Philos. Mag., 2021, 101: 154 doi: 10.1080/14786435.2020.1822557
40	Nutor R K, Xu T D, Wang X L, et al. Liquid helium temperature deformation and local atomic structure of CoNiV medium entropy alloy [J]. Mater. Today Commun., 2022, 30: 103141
41	Wang S B, Wu M X, Shu D, et al. Mechanical instability and tensile properties of TiZrHfNbTa high entropy alloy at cryogenic temperatures [J]. Acta Mater., 2020, 201: 517 doi: 10.1016/j.actamat.2020.10.044
42	Kim D G, Jo Y H, Yang J H, et al. Ultrastrong duplex high-entropy alloy with 2 GPa cryogenic strength enabled by an accelerated martensitic transformation [J]. Scr. Mater., 2019, 171: 67 doi: 10.1016/j.scriptamat.2019.06.026
43	Zhang Y W, Stocks G M, Jin K, et al. Influence of chemical disorder on energy dissipation and defect evolution in concentrated solid solution alloys [J]. Nat. Commun., 2015, 6: 8736 doi: 10.1038/ncomms9736 pmid: 26507943
44	Parkin C, Moorehead M, Elbakhshwan M, et al. In situ microstructural evolution in face-centered and body-centered cubic complex concentrated solid-solution alloys under heavy ion irradiation [J]. Acta Mater., 2020, 198: 85 doi: 10.1016/j.actamat.2020.07.066
45	Gali A, George E P. Tensile properties of high- and medium-entropy alloys [J]. Intermetallics, 2013, 39: 74 doi: 10.1016/j.intermet.2013.03.018
46	Lyu Z Y, Fan X S, Lee C, et al. Fundamental understanding of mechanical behavior of high-entropy alloys at low temperatures: A review [J]. J. Mater. Res., 2018, 33: 2998 doi: 10.1557/jmr.2018.273
47	Moon J, Qi Y S, Tabachnikova E, et al. Microstructure and mechanical properties of high-entropy alloy Co₂₀Cr₂₆Fe₂₀Mn₂₀Ni₁₄ processed by high-pressure torsion at 77 K and 300 K [J]. Sci. Rep., 2018, 8: 11074 doi: 10.1038/s41598-018-29446-y
48	Nutor R K, Cao Q P, Wei R, et al. A dual-phase alloy with ultrahigh strength-ductility synergy over a wide temperature range [J]. Sci. Adv., 2021, 7: eabi4404 doi: 10.1126/sciadv.abi4404
49	Liu J P, Chen J X, Liu T W, et al. Superior strength-ductility CoCrNi medium-entropy alloy wire [J]. Scr. Mater., 2020, 181: 19 doi: 10.1016/j.scriptamat.2020.02.002
50	Tian Y Z, Peng S Y, Chen S F, et al. Temperature-dependent tensile properties of ultrafine-grained C-doped CoCrFeMnNi high-entropy alloy [J]. Rare Met., 2022, 41: 2877 doi: 10.1007/s12598-022-01972-9
51	Shim S H, Moon J, Pouraliakbar H, et al. Toward excellent tensile properties of nitrogen-doped CoCrFeMnNi high-entropy alloy at room and cryogenic temperatures [J]. J. Alloys Compd., 2022, 897: 163217 doi: 10.1016/j.jallcom.2021.163217
52	Wang Y T, Li J B, Yang K H, et al. Research progress and prospects of interstitial atoms and particle enhanced CoCrFeMnNi high entropy alloy [J]. Trans. Mater. Heat Treat., 2022, 43: 1
52	王毅涛, 李建波, 杨凯华等. 间隙原子及颗粒增强CoCrFeMnNi高熵合金的研究进展及展望 [J]. 材料热处理学报, 2022, 43: 1
53	Li D Y, Zhang Y. The ultrahigh charpy impact toughness of forged Al _x CoCrFeNi high entropy alloys at room and cryogenic temperatures [J]. Intermetallics, 2016, 70: 24 doi: 10.1016/j.intermet.2015.11.002
54	Zhang Y, Peng W J. Microstructural control and properties optimization of high-entropy alloys [J]. Procedia Eng., 2012, 27: 1169 doi: 10.1016/j.proeng.2011.12.568
55	Stepanov N, Tikhonovsky M, Yurchenko N, et al. Effect of cryo-deformation on structure and properties of CoCrFeNiMn high-entropy alloy [J]. Intermetallics, 2015, 59: 8 doi: 10.1016/j.intermet.2014.12.004
56	Tang Q H, Huang Y, Huang Y Y, et al. Hardening of an Al_0.3CoCrFeNi high entropy alloy via high-pressure torsion and thermal annealing [J]. Mater. Lett., 2015, 151: 126 doi: 10.1016/j.matlet.2015.03.066
57	Yu P F, Cheng H, Zhang L J, et al. Effects of high pressure torsion on microstructures and properties of an Al_0.1CoCrFeNi high-entropy alloy [J]. Mater. Sci. Eng., 2016, A655: 283
58	Moon J, Qi Y S, Tabachnikova E, et al. Deformation-induced phase transformation of Co₂₀Cr₂₆Fe₂₀Mn₂₀Ni₁₄ high-entropy alloy during high-pressure torsion at 77 K [J]. Mater. Lett., 2017, 202: 86 doi: 10.1016/j.matlet.2017.05.065
59	Sathiyamoorthi P, Moon J, Bae J W, et al. Superior cryogenic tensile properties of ultrafine-grained CoCrNi medium-entropy alloy produced by high-pressure torsion and annealing [J]. Scr. Mater., 2019, 163: 152 doi: 10.1016/j.scriptamat.2019.01.016
60	Deng Y, Tasan C C, Pradeep K G, et al. Design of a twinning-induced plasticity high entropy alloy [J]. Acta Mater., 2015, 94: 124 doi: 10.1016/j.actamat.2015.04.014
61	Jo Y H, Jung S, Choi W M, et al. Cryogenic strength improvement by utilizing room-temperature deformation twinning in a partially recrystallized VCrMnFeCoNi high-entropy alloy [J]. Nat. Commun., 2017, 8: 15719 doi: 10.1038/ncomms15719 pmid: 28604656
62	Li Z M, Pradeep K G, Deng Y, et al. Metastable high-entropy dual-phase alloys overcome the strength-ductility trade-off [J]. Nature, 2016, 534: 227 doi: 10.1038/nature17981
63	Li D Y, Li Z M, Xie L, et al. Cryogenic mechanical behavior of a TRIP-assisted dual-phase high-entropy alloy [J]. Nano Res. 2022, 15: 4859 doi: 10.1007/s12274-021-3719-y
64	He J Y, Wang H, Huang H L, et al. A precipitation-hardened high-entropy alloy with outstanding tensile properties [J]. Acta Mater., 2016, 102: 187 doi: 10.1016/j.actamat.2015.08.076
65	Yang T, Zhao Y L, Tong Y, et al. Multicomponent intermetallic nanoparticles and superb mechanical behaviors of complex alloys [J]. Science, 2018, 362: 933 doi: 10.1126/science.aas8815 pmid: 30467166
66	Xu X D, Liu P, Tang Z, et al. Transmission electron microscopy characterization of dislocation structure in a face-centered cubic high-entropy alloy Al_0.1CoCrFeNi [J]. Acta Mater. 2018, 144: 107 doi: 10.1016/j.actamat.2017.10.050
67	Tong Y, Chen D, Han B, et al. Outstanding tensile properties of a precipitation-strengthened FeCoNiCrTi_0.2 high-entropy alloy at room and cryogenic temperatures [J]. Acta Mater., 2019, 165: 228 doi: 10.1016/j.actamat.2018.11.049
68	Liu H C, Kuo C M, Shen P K, et al. Disordering of L1₂ phase in high-entropy alloy deformed at cryogenic temperature [J]. Adv. Eng. Mater., 2021, 23: 2100564 doi: 10.1002/adem.v23.12
69	Jo Y H, Yang J H, Doh K Y, et al. Analysis of damage-tolerance of TRIP-assisted V₁₀Cr₁₀Fe₄₅Co₃₀Ni₅ high-entropy alloy at room and cryogenic temperatures [J]. J. Alloys Compd., 2020, 844: 156090 doi: 10.1016/j.jallcom.2020.156090
70	Zhang K S, Zhang X H, Zhang E G, et al. Strengthening of ferrous medium entropy alloys by promoting phase transformation [J]. Intermetallics, 2021, 136: 107265 doi: 10.1016/j.intermet.2021.107265
71	Wei C B, Lu Y P, Du X H, et al. Remarkable strength of a non-equiatomic Co₂₉Cr₂₉Fe₂₉Ni_12.5W_0.5 high-entropy alloy at cryogenic temperatures [J]. Mater. Sci. Eng., 2021, A818: 141446
72	Liu D, Jin X, Guo N, et al. Non-equiatomic FeMnCrNiAl high-entropy alloys with heterogeneous structures for strength and ductility combination [J]. Mater. Sci. Eng., 2021, A818: 141386
73	Dong Y, Duan S G, Huang X, et al. Excellent strength-ductility synergy in as-cast Al_0.6CoCrFeNi₂Mo_0.08V_0.04 high-entropy alloy at room and cryogenic temperatures [J]. Mater. Lett., 2021, 294: 129778 doi: 10.1016/j.matlet.2021.129778
74	Fiocchi J, Mostaed A, Coduri M, et al. Enhanced cryogenic and ambient temperature mechanical properties of CoCuFeMnNi high entropy alloy through controlled heat treatment [J]. J. Alloys Compd., 2022, 910: 164810 doi: 10.1016/j.jallcom.2022.164810
75	Pei B, Fan J P, Wang Z, et al. Excellent combination of strength and ductility in CoNiCr-based MP159 alloys at cryogenic temperature [J]. J. Alloys Compd., 2022, 907: 164144 doi: 10.1016/j.jallcom.2022.164144
76	Giwa A M, Aitken Z H, Liaw P K, et al. Effect of temperature on small-scale deformation of individual face-centered-cubic and body-centered-cubic phases of an Al_0.7CoCrFeNi high-entropy alloy [J]. Mater. Des., 2020, 191: 108611 doi: 10.1016/j.matdes.2020.108611
77	Sun S J, Tian Y Z, Lin H R, et al. Temperature dependence of the Hall-Petch relationship in CoCrFeMnNi high-entropy alloy [J]. J. Alloys Compd., 2019, 806: 992 doi: 10.1016/j.jallcom.2019.07.357
78	Ding Q Q, Fu X Q, Chen D K, et al. Real-time nanoscale observation of deformation mechanisms in CrCoNi-based medium- to high-entropy alloys at cryogenic temperatures [J]. Mater. Today, 2019, 25: 21 doi: 10.1016/j.mattod.2019.03.001
79	Jang M J, Kwak H, Lee Y W, et al. Plastic deformation behavior of 40Fe-25Ni-15Cr-10Co-10V high-entropy alloy for cryogenic applications [J]. Met. Mater. Int., 2019, 25: 277 doi: 10.1007/s12540-018-0184-6
80	Górecki K, Bała P, Bednarczyk W, et al. Cryogenic behaviour of the Al₅Ti₅Co₃₅Ni₃₅Fe₂₀ multi-principal component alloy [J]. Mater. Sci. Eng., 2019, A745: 346
81	Sun S J, Tian Y Z, Lin H R, et al. Achieving high ductility in the 1.7  GPa grade CoCrFeMnNi high-entropy alloy at 77 K [J]. Mater. Sci. Eng., 2019, A740-741: 336
82	Sun S J, Tian Y Z, An X H, et al. Ultrahigh cryogenic strength and exceptional ductility in ultrafine-grained CoCrFeMnNi high-entropy alloy with fully recrystallized structure [J]. Mater. Today Nano., 2018, 4: 46
83	Bönisch M, Wu Y, Sehitoglu H. Twinning-induced strain hardening in dual-phase FeCoCrNiAl_0.5 at room and cryogenic temperature [J]. Sci. Rep., 2018, 8: 10663 doi: 10.1038/s41598-018-28784-1 pmid: 30006547
84	Jo Y H, Choi W M, Sohn S S, et al. Role of brittle sigma phase in cryogenic-temperature-strength improvement of non-equi-atomic Fe-rich VCrMnFeCoNi high entropy alloys [J]. Mater. Sci. Eng., 2018, A724: 403
85	Lu Z P, Lei Z F, Huang H L, et al. Deformation behavior and toughening of high-entropy alloys [J]. Acta Metall. Sin., 2018, 54: 1553 doi: 10.11900/0412.1961.2018.00372
85	吕昭平, 雷智锋, 黄海龙等. 高熵合金的变形行为及强韧化 [J]. 金属学报, 2018, 54: 1553 doi: 10.11900/0412.1961.2018.00372
86	Abuzaid W, Egilmez M, Chumlyakov Y I. TWIP-TRIP effect in single crystalline VFeCoCrNi multi-principle element alloy [J]. Scr. Mater., 2021, 194: 113637 doi: 10.1016/j.scriptamat.2020.113637
87	Wu P F, Gan K F, Yan D S, et al. The temperature dependence of deformation behaviors in high-entropy alloys: A review [J]. Metals, 2021, 11: 2005 doi: 10.3390/met11122005
88	Rizi M S, Minouei H, Lee B J, et al. Effects of carbon and molybdenum on the nanostructural evolution and strength/ductility trade-off in Fe₄₀Mn₄₀Co₁₀Cr₁₀ high-entropy alloys [J]. J. Alloys Compd., 2022, 911: 165108 doi: 10.1016/j.jallcom.2022.165108
89	Park H D, Won J W, Moon J, et al. Fe₅₅Co_17.5Ni₁₀Cr_12.5Mo₅ high-entropy alloy with outstanding cryogenic mechanical properties driven by deformation-induced phase transformation behavior [J]. Met. Mater. Int., 2023, 29: 95 doi: 10.1007/s12540-022-01215-7
90	Jo Y H, Choi W M, Kim D G, et al. FCC to BCC transformation-induced plasticity based on thermodynamic phase stability in novel V₁₀Cr₁₀Fe₄₅Co _x Ni_35- _x medium-entropy alloys [J]. Sci. Rep., 2019, 9: 2948 doi: 10.1038/s41598-019-39570-y pmid: 30814569
91	Kwon H, Moon J, Bae J W, et al. Precipitation-driven metastability engineering of carbon-doped CoCrFeNiMo medium-entropy alloys at cryogenic temperature [J]. Scr. Mater., 2020, 188: 140 doi: 10.1016/j.scriptamat.2020.07.023
92	Wang Z W, Lu W J, Raabe D, et al. On the mechanism of extraordinary strain hardening in an interstitial high-entropy alloy under cryogenic conditions [J]. J. Alloys Compd., 2019, 781: 734 doi: 10.1016/j.jallcom.2018.12.061
93	Seol J B, Bae J W, Kim J G, et al. Short-range order strengthening in boron-doped high-entropy alloys for cryogenic applications [J]. Acta Mater., 2020, 194: 366 doi: 10.1016/j.actamat.2020.04.052
94	He Z F, Jia N, Wang H W, et al. Synergy effect of multi-strengthening mechanisms in FeMnCoCrN HEA at cryogenic temperature [J]. J. Mater. Sci. Technol., 2021, 86: 158 doi: 10.1016/j.jmst.2020.12.079
95	Bae J W, Seol J B, Moon J, et al. Exceptional phase-transformation strengthening of ferrous medium-entropy alloys at cryogenic temperatures [J]. Acta Mater., 2018, 161: 388 doi: 10.1016/j.actamat.2018.09.057
96	Jo Y H, Choi W M, Kim D G, et al. Utilization of brittle σ phase for strengthening and strain hardening in ductile VCrFeNi high-entropy alloy [J]. Mater. Sci. Eng., 2019, A743: 665
97	Du X H, Huo X F, Chang H T, et al. Superior strength-ductility combination of a Co-rich CoCrNiAlTi high-entropy alloy at room and cryogenic temperatures [J]. Mater. Res. Express, 2020, 7: 034001
98	Lu Y P, Dong Y, Guo S, et al. A promising new class of high-temperature alloys: Eutectic high-entropy alloys [J]. Sci. Rep., 2014, 4: 6200 doi: 10.1038/srep06200 pmid: 25160691
99	Lu Y P, Gao X Z, Jiang L, et al. Directly cast bulk eutectic and near-eutectic high entropy alloys with balanced strength and ductility in a wide temperature range [J]. Acta Mater., 2017, 124: 143 doi: 10.1016/j.actamat.2016.11.016
100	Li Y, Shi P J, Wang M Y, et al. Unveiling microstructural origins of the balanced strength-ductility combination in eutectic high-entropy alloys at cryogenic temperatures [J]. Mater. Res. Lett., 2022, 10: 602 doi: 10.1080/21663831.2022.2078169
101	Huo W Y, Fang F, Zhou H, et al. Remarkable strength of CoCrFeNi high-entropy alloy wires at cryogenic and elevated temperatures [J]. Scr. Mater., 2017, 141: 125 doi: 10.1016/j.scriptamat.2017.08.006
102	Chen J X, Li T, Chen Y, et al. Ultra-strong heavy-drawn eutectic high entropy alloy wire [J]. Acta Mater., 2023, 243: 118515 doi: 10.1016/j.actamat.2022.118515
103	Fan L, Yang T, Zhao Y L, et al. Ultrahigh strength and ductility in newly developed materials with coherent nanolamellar architectures [J]. Nat. Commun., 2020, 11: 6240 doi: 10.1038/s41467-020-20109-z pmid: 33288762
104	Du X H, Li W P, Chang H T, et al. Dual heterogeneous structures lead to ultrahigh strength and uniform ductility in a Co-Cr-Ni medium-entropy alloy [J]. Nat. Commun., 2020, 11: 2390 doi: 10.1038/s41467-020-16085-z pmid: 32404913
105	Wang S D, Wang J H, Yang Y, et al. Ultrastrong interstitially-strengthened chemically complex martensite via tuning phase stability [J]. Scr. Mater., 2023, 226: 115257 doi: 10.1016/j.scriptamat.2022.115257
106	Chung H, Choi W S, Jun H, et al. Doubled strength and ductility via maraging effect and dynamic precipitate transformation in ultrastrong medium-entropy alloy [J]. Nat. Commun., 2023, 14: 145 doi: 10.1038/s41467-023-35863-z pmid: 36627295
107	Liu X F, Tian Z L, Zhang X F, et al. "Self-sharpening" tungsten high-entropy alloy [J]. Acta Mater., 2020, 186: 257 doi: 10.1016/j.actamat.2020.01.005
108	Li Z, Zhao S, Diao H, et al. High-velocity deformation of Al_0.3CoCrFeNi high-entropy alloy: Remarkable resistance to shear failure [J]. Sci. Rep., 2017, 7: 42742 doi: 10.1038/srep42742 pmid: 28210000
109	Jiao Z M, Ma S G, Chu M Y, et al. Superior mechanical properties of AlCoCrFeNiTi _x high-entropy alloys upon dynamic loading [J]. J. Mater. Eng. Perform., 2016, 25: 451 doi: 10.1007/s11665-015-1869-3
110	Tang Y, Wang R X, Xiao B, et al. A review on the dynamic-mechanical behaviors of high-entropy alloys [J]. Prog. Mater. Sci., 2023, 135: 101090 doi: 10.1016/j.pmatsci.2023.101090
111	He J Y, Wang Q, Zhang H S, et al. Dynamic deformation behavior of a face-centered cubic FeCoNiCrMn high-entropy alloy [J]. Sci. Bull., 2018, 63: 362 doi: 10.1016/j.scib.2018.01.022 pmid: 36658873
112	Li Z Z, Zhao S T, Alotaibi S M, et al. Adiabatic shear localization in the CrMnFeCoNi high-entropy alloy [J]. Acta Mater., 2018, 151: 424 doi: 10.1016/j.actamat.2018.03.040
113	Wang L, Qiao J W, Ma S G, et al. Mechanical response and deformation behavior of Al_0.6CoCrFeNi high-entropy alloys upon dynamic loading [J]. Mater. Sci. Eng., 2018, A727: 208
114	Qiao Y, Chen Y, Cao F H, et al. Dynamic behavior of CrMnFeCoNi high-entropy alloy in impact tension [J]. Int. J. Impact Eng., 2021, 158: 104008 doi: 10.1016/j.ijimpeng.2021.104008
115	Zhao S T, Li Z Z, Zhu C Y, et al. Amorphization in extreme deformation of the CrMnFeCoNi high-entropy alloy [J]. Sci. Adv., 2021, 7: eabb3108 doi: 10.1126/sciadv.abb3108
116	Wang R X, Tang Y, Li S, et al. Research progress on deformation mechanisms under dynamic loading of high-entropy alloys [J]. Mater. Rep., 2021, 35: 17001
116	王睿鑫, 唐宇, 李顺等. 高熵合金动态载荷下变形机制的研究进展 [J]. 材料导报. 2021, 35: 17001
117	Qin S, Yang M X, Liu Y K, et al. Superior dynamic shear properties and deformation mechanisms in a high entropy alloy with dual heterogeneous structures [J]. J. Mater. Res. Technol., 2022, 19: 3287 doi: 10.1016/j.jmrt.2022.06.074
118	Huang A M, Fensin S J, Meyers M A. Strain-rate effects and dynamic behavior of high entropy alloys [J]. J. Mater. Res. Technol., 2023, 22: 307 doi: 10.1016/j.jmrt.2022.11.057
119	Hu M L, Song W D, Duan D B, et al. Dynamic behavior and microstructure characterization of TaNbHfZrTi high-entropy alloy at a wide range of strain rates and temperatures [J]. Int. J. Mech. Sci., 2020, 182: 105738 doi: 10.1016/j.ijmecsci.2020.105738
120	Qiao Y, Cao F H, Chen Y, et al. Impact tension behavior of heavy-drawn nanocrystalline CoCrNi medium entropy alloy wire [J]. Mater. Sci. Eng., 2022, A856: 144041

[1]	张海峰, 闫海乐, 方烽, 贾楠. FeMnCoCrNi高熵合金双晶微柱变形机制的分子动力学模拟[J]. 金属学报, 2023, 59(8): 1051-1064.
[2]	冯力, 王贵平, 马凯, 杨伟杰, 安国升, 李文生. 冷喷涂辅助感应重熔合成AlCo _x CrFeNiCu高熵合金涂层的显微组织和性能[J]. 金属学报, 2023, 59(5): 703-712.
[3]	苗军伟, 王明亮, 张爱军, 卢一平, 王同敏, 李廷举. AlCr_1.3TiNi₂ 共晶高熵合金的高温摩擦学性能及磨损机理[J]. 金属学报, 2023, 59(2): 267-276.
[4]	胡文滨, 张晓雯, 宋龙飞, 廖伯凯, 万闪, 康磊, 郭兴蓬. 共晶高熵合金AlCoCrFeNi_2.1 在H₂SO₄ 溶液中的腐蚀行为[J]. 金属学报, 2023, 59(12): 1644-1654.
[5]	韩林至, 牟娟, 周永康, 朱正旺, 张海峰. 热处理温度对Ti_0.5Zr_1.5NbTa_0.5Sn_0.2 高熵合金组织结构与力学性能的影响[J]. 金属学报, 2022, 58(9): 1159-1168.
[6]	赵晓峰, 李玲, 张晗, 陆杰. 热障涂层高熵合金粘结层材料研究进展[J]. 金属学报, 2022, 58(4): 503-512.
[7]	徐流杰, 宗乐, 罗春阳, 焦照临, 魏世忠. 难熔高熵合金的强韧化途径与调控机理[J]. 金属学报, 2022, 58(3): 257-271.
[8]	张金钰, 屈启蒙, 王亚强, 吴凯, 刘刚, 孙军. 金属/高熵合金纳米多层膜的力学性能及其辐照效应研究进展[J]. 金属学报, 2022, 58(11): 1371-1384.
[9]	安子冰, 毛圣成, 张泽, 韩晓东. 高熵合金跨尺度异构强韧化及其力学性能研究进展[J]. 金属学报, 2022, 58(11): 1441-1458.
[10]	孙士杰, 田艳中, 张哲峰. 析出强化Fe₅₃Mn₁₅Ni₁₅Cr₁₀Al₄Ti₂C₁ 高熵合金强韧化机制[J]. 金属学报, 2022, 58(1): 54-66.
[11]	崔洪芝, 姜迪. 高熵合金涂层研究进展[J]. 金属学报, 2022, 58(1): 17-27.
[12]	曹富荣, 丁鑫, 项超, 尚会会. Mg-4.4Li-2.5Zn-0.46Al-0.74Y合金高温变形流动应力、组织演变与本构分析[J]. 金属学报, 2021, 57(7): 860-870.
[13]	王洪伟, 何竹风, 贾楠. 非均匀组织FeMnCoCr高熵合金的微观结构和力学性能[J]. 金属学报, 2021, 57(5): 632-640.
[14]	杨勇, 赫全锋. 高熵合金中的晶格畸变[J]. 金属学报, 2021, 57(4): 385-392.
[15]	王一涵, 原园, 喻嘉彬, 吴宏辉, 吴渊, 蒋虽合, 刘雄军, 王辉, 吕昭平. 纳米晶合金热稳定性的熵调控设计[J]. 金属学报, 2021, 57(4): 403-412.

Viewed

Full text

Abstract

Cited

Shared

Discussed