高熵合金涂层研究进展

doi:10.11900/0412.1961.2021.00193

金属学报

2022, Vol. 58

Issue (1): 17-27 DOI: 10.11900/0412.1961.2021.00193

综述

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高熵合金涂层研究进展

崔洪芝¹^,²(

), 姜迪²

^1. 中国海洋大学材料科学与工程学院青岛 266100
^2. 山东科技大学材料科学与工程学院青岛 266590

Research Progress of High-Entropy Alloy Coatings

CUI Hongzhi¹^,²(

), JIANG Di²

^1. School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
^2. School of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China

引用本文:

崔洪芝, 姜迪. 高熵合金涂层研究进展[J]. 金属学报, 2022, 58(1): 17-27.
Hongzhi CUI, Di JIANG. Research Progress of High-Entropy Alloy Coatings[J]. Acta Metall Sin, 2022, 58(1): 17-27.

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摘要:

制备各类涂层对材料表面进行强化是提高材料服役性能的重要途径，可根据服役环境要求，在不影响基体性能的前提下，通过调控工艺改变涂层成分、组织结构，从而改善其性能，延长部件的使用寿命。高熵合金及其涂层是近年来材料领域的研究热点，具有优异的强度、韧性、耐蚀性、耐磨性等特点，在表面工程领域的应用发展迅速。通过设计不同体系的高熵合金涂层，开发高效的制备工艺方法，将其应用于表面工程领域，有望成为耐磨、耐蚀、耐热等极端环境装备关键部件表面强化的理想手段。本文从高熵合金涂层的分类与制备方法出发，详细介绍了目前高熵合金涂层的最新研究成果，归纳了高熵合金涂层的成分、组织结构、性能以及磨损与腐蚀机理，并对其在表面工程领域应用亟待解决的问题及未来发展方向进行了展望。

关键词 ：高熵合金涂层, 磨损, 腐蚀

Abstract：

Preparing various types of coatings to strengthen the surface of materials is an effective technique to increase the materials' service performance. The qualities of the coatings can be considerably improved based on the service environment by altering their composition and microstructure without impacting the substrate's performance, thereby extending the equipment's service life. Recently, high- entropy alloys (HEAs) and their coatings have been the focus in materials science. The applications in surface engineering have developed rapidly owing to their outstanding strength, toughness, corrosion resistance, and wear resistance. By designing different HEA coatings and developing efficient preparation methods for surface engineering, HEA coatings are expected to be an ideal candidate for surface strengthening of key components suffering from wear, corrosion, and elevated temperature in an extreme environment. In this paper, the latest research results are detailed and the compositions, structures, properties, and wear and corrosion mechanisms of HEA coating from the characters viewpoint, classification, and preparation methods of HEA coatings are summarized. In addition, the issues that must be solved in the surface engineering field and the developing direction in the future were proposed.

Key words： high-entropy alloy (HEA) coating wear corrosion

收稿日期: 2021-05-07

ZTFLH:

TG178

基金资助:国家自然科学基金项目(51971121);山东省重大科技创新工程项目(2019JZZY010303)

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表1 非晶/高熵非晶合金涂层[30~46]

图1 激光熔覆CoCrFeNiSiB高熵非晶合金涂层凝固组织[42]

图2 等离子熔覆(CoCrFeMnNi)85Ti15高熵合金涂层[52]

图3 高速火焰喷涂 Fe49.7Cr18Mn1.9Mo7.4W1.6B15.2C3.8Si2.4非晶涂层的SEM像[55]

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