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EFFECTS OF Ca ADDITION ON THE MICROSTRUCTURES AND MECHANICAL PROPERTIES OF Mg-5Al-0.4Zn BASED CASTING ALLOY |
YANG Guangyu; HAO Qitang; JIE Wanqi; JIA Wenping; HE Zhi |
College of Materials Science and Engineering; Northwestern Polytechnical University; Xi'an 710072 |
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Cite this article:
YANG Guangyu; HAO Qitang; JIE Wanqi; JIA Wenping; HE Zhi. EFFECTS OF Ca ADDITION ON THE MICROSTRUCTURES AND MECHANICAL PROPERTIES OF Mg-5Al-0.4Zn BASED CASTING ALLOY. Acta Metall Sin, 2005, 41(9): 933-939 .
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Abstract In the sand-casting magnesium alloys Mg-5Al-0.4Zn-0.2Mn-Sr-Ti-xCa , existed α-Mg, (α + Al2Ca) eutectic and Mg17Al12 when x=0.37, 0.70, 0.93, 1.69, or α-Mg and (α+(Mg, Al)2Ca) eutectic when x=2.93. With increasing x, the room temperature mechanical properties (σb, δ) of the alloys decreased, meanwhile the strength at 200 ℃ increased first and then decreased slightly, and the elongation decreased rapidly. The yield strength at 200 ℃ (σ0.2, 200 ℃) of the alloys was greatly
improved with the increase of x value. DSC analysis proved that the thermal stability of Mg17Al12 phase was improved by dissolution of Ca. The grain boundary strength at 200 ℃ was
improved through the formation of the Al2Ca or (Mg, Al)2Ca phases at the grain boundary. TEM analysis shows that the dislocations slip not only at the basal slip plane (0001), but also at the (10-10) prismatic slip plane
and (-1-121) pyramidal slip plane at 200 ℃.
The dislocation can be piled up by Al2Ca phases at the grain boundary resulting in the higher yield strength of the alloy containing Ca than those without Ca at 200 ℃.
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Received: 31 January 2005
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