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Acta Metall Sin  2014, Vol. 50 Issue (9): 1146-1152    DOI: 10.11900/0412.1961.2014.00159
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INFLUENCE OF INTERFACE EFFECT ON ADHESION OF CHLORELLA ON TITANIUM ALLOY SURFACE
LIAN Feng(), REN Hongmei, GUAN Shankun, ZHANG Huichen
College of Transportation Equipments and Ocean Engineering, Dalian Maritime University, Dalian 116026
Cite this article: 

LIAN Feng, REN Hongmei, GUAN Shankun, ZHANG Huichen. INFLUENCE OF INTERFACE EFFECT ON ADHESION OF CHLORELLA ON TITANIUM ALLOY SURFACE. Acta Metall Sin, 2014, 50(9): 1146-1152.

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Abstract  

Laser etching technique was used to build three microstructures of grid, line and dot on Ti6Al4V alloy surface, and sol-gel method was used to coat SiO2 nanoparticles on the microstructure to build the hydrophobic/superhydrophobic surface with the micro/micro-nano structure. Adhesion area of the chlorella on the surfaces was used to evaluate the antifouling performance of the halobios, and dynamic wash test was used to evaluate the adhesion strength of the chlorella. It is shown that the hydrophobic/superhydrophobic surfaces with the microstructure are in accordance with Wenzel model, the superhydrophobic surfaces with the micro-nano structure are in accordance with Cassie model, and have stronger antifouling and less adhesion strength. The grid surfaces have the strongest superhydrophobic and self-cleaning performance, flowed by the line surfaces and then the dot surfaces. The contact angles decrease, the roll angles increase, the antifouling performance gets small and the adhesion strength increase with the increment of space of the microstructure.

Key words:  hydrophobic      super hydrophobic      titanium alloy      chlorella      adhesion     
ZTFLH:  TH117.1  
Fund: Supported by National Natural Science Foundation of China (Nos.51275064 and 50975036), Fundamental Research Funds for the Central Universities (No.3132014303) and Industrial Research Program of Liaoning Province (No.2012220006)

URL: 

https://www.ams.org.cn/EN/10.11900/0412.1961.2014.00159     OR     https://www.ams.org.cn/EN/Y2014/V50/I9/1146

Fig.1  3D morphologies of laser etching specimens for dot (a, b), line (c, d) and grid (e, f) with spaces of 150 μm (a, c, e) and 450 μm (b, d, f)
Fig.2  Maximum altitudes of the laser etching specimens for dot, line and grid with different spaces
Fig.3  FESEM image (a) and corresponding EDS analysis (rectangle in Fig.3a) (b) of coating on polish specimen
Fig.4  Contact angles of specimens with and without SiO2 (a) and roll angles of specimens with SiO2 (b)
Fig.5  Immersion pictures of specimens with space 450 μm
Fig.6  Areas of adhesion of specimens
Fig.7  Fall all times of chlorella of specimens
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