非晶态Ni80P20合金的玻璃转变和过冷液体性质

doi:10.11900/0412.1961.2020.00379

金属学报

2021, Vol. 57

Issue (4): 553-558 DOI: 10.11900/0412.1961.2020.00379

研究论文

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非晶态Ni₈₀P₂₀合金的玻璃转变和过冷液体性质

杨群¹, 彭思旭¹^,², 卜庆周¹, 于海滨¹(

)

^1.华中科技大学国家脉冲强磁场科学中心和物理学院武汉 430074
^2.湖北大学化学化工学院武汉 430062

Revealing Glass Transition and Supercooled Liquid in Ni₈₀P₂₀ Metallic Glass

YANG Qun¹, PENG Sixu¹^,², BU Qingzhou¹, YU Haibin¹(

)

^1.Wuhan National High Magnetic Field Center and School of Physics, Huazhong University of Science and Technology, Wuhan 430074, China
^2.School of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China

引用本文:

杨群, 彭思旭, 卜庆周, 于海滨. 非晶态Ni₈₀P₂₀合金的玻璃转变和过冷液体性质[J]. 金属学报, 2021, 57(4): 553-558.
Qun YANG, Sixu PENG, Qingzhou BU, Haibin YU. Revealing Glass Transition and Supercooled Liquid in Ni₈₀P₂₀ Metallic Glass[J]. Acta Metall Sin, 2021, 57(4): 553-558.

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摘要:

镍磷(Ni₈₀P₂₀)金属玻璃是最典型和被研究最多的金属玻璃成分之一。然而，由于镍磷金属玻璃在加热过程中玻璃转变过程被晶化所阻断，到目前为止其过冷液体性质还没有被探测和表征。本工作通过具有高升温速率的超快量热仪，避免了Ni₈₀P₂₀金属玻璃在玻璃转变过程中的晶化，直接探测其整个玻璃转变过程和一定温度宽度的过冷液相区，为揭示其超冷液体性质提供了可能。通过超快量热测量，获得了Ni₈₀P₂₀金属玻璃在5个数量级升温速率变化下的相形成规律和液体脆度，它的超冷液体展现出比大部分块体金属玻璃更“脆”的一种液体行为，这种“脆”性液体行为可能导致其差的玻璃形成能力。

关键词 ：金属玻璃, 超快量热, 超冷液体, 脆度, 玻璃形成能力

Abstract：

Nickel-phosphorus metallic glass (MG) is one of the most typical MGs, and is also one of the most popular studied MG components, especially in the process of establishing the structure model of amorphous alloys and computer simulations. Although it appears throughout the history of amorphous alloy research, its glass transition temperature and liquid properties have not yet been determined due to its low ability to form glass. In this work, we bypassed the crystallization of Ni₈₀P₂₀ MG during the glass transition process by an ultrafast calorimeter with heating rates up to thousands of Kelvin per second and directly detected its glass transition process. This method offers an opportunity to expose the nature of the Ni₈₀P₂₀ MG supercooled liquid. The liquid fragility of the metallic glass Ni₈₀P₂₀ was determined by the Vogel-Fulcher-Tammann equation based on the dependence of the glass transition temperature at different heating rates. The results show that the liquid fragility of Ni₈₀P₂₀ MG is 93 ± 4, which is obviously a very “fragile” liquid compared with other bulk MGs. It is suggested that this “fragile” liquid behavior of Ni₈₀P₂₀ MG may lead to its low glass-forming ability.

Key words： metallic glass ultrafast scanning calorimetry supercooled liquid fragility glass forming ability

收稿日期: 2020-09-21

ZTFLH:

TG139

基金资助:中央高校基本科研业务费专项资金项目(2018KFYXKJC009)

作者简介: 杨群，男，1994年生，博士生

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图1 Ni80P20金属玻璃条带的XRD谱，及Ni80P20金属玻璃分别在高升温速率下的FSC和低升温速率下的DSC热流曲线

图2 Ni80P20金属玻璃在不同升温速率下的FSC热流曲线及Ni80P20金属玻璃在不同升温速率下的相图

图3 Ni80P20金属玻璃分别在DSC和FSC的升温速率范围内的晶化Kissinger图，及不同升温速率下的玻璃转变温度的变化与VFT方程拟合

图4 升温速率为700 K/s时，通过高温传感器测量的Ni80P20金属玻璃的比热曲线及熔化热流曲线

图5 金属玻璃的液体脆度和玻璃形成能力之间的非线性关系

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