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Acta Metall Sin  2014, Vol. 50 Issue (5): 531-539    DOI: 10.3724/SP.J.1037.2013.00709
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EFFECT OF ALLOY ELEMENTS PARTITIONING BEHAVIOR ON RETAINED AUSTENITE AND MECHANICAL PROPERTY IN LOW CARBON HIGH STRENGTH STEEL
TIAN Yaqiang1, ZHANG Hongjun1, CHEN Liansheng1(), SONG Jinying1, XU Yong1,2, ZHANG Shihong2
1 Hebei Key Laboratory of Modern Metallurgy Technology, Hebei United University, Tangshan 063009
2 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
Cite this article: 

TIAN Yaqiang, ZHANG Hongjun, CHEN Liansheng, SONG Jinying, XU Yong, ZHANG Shihong. EFFECT OF ALLOY ELEMENTS PARTITIONING BEHAVIOR ON RETAINED AUSTENITE AND MECHANICAL PROPERTY IN LOW CARBON HIGH STRENGTH STEEL. Acta Metall Sin, 2014, 50(5): 531-539.

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Abstract  

The C content in high strength steel must be controlled at a lower level for the good weldability. However, the lower level of C content will reduce the C partitioning efficiency and influence the stability of retained austenite, which leads to the decrease of the product of tensile strength and elongation of high strength steel. A novel preparation mechanism of high strength steel is to employ some kind of substitutional alloying elements, for example Mn, instead of C to partitioning to enhance the austenitic stability, which would not remarkably reduce the weldability of the steel. One low alloy C-Si-Mn steel was used in present work. The Mn partitioning behavior and its effect on the stability of the retained austenite and the mechanical property were studied by means of intercritical annealing, subsequent austenitizing, then quenching and partitioning process (I&Q&P). The results show that in the process of intercritical annealing at 760 ℃, by extending the annealing time, austenite volume fraction increases gradually until it reaches the saturation, meanwhile the Mn partitioning behavior occurs and Mn content increases gradually from ferrite to austenite until it reaches the chemical potential balance in two phases. The sample is heated to 930 ℃ for 120 s, then rapidly quenching to 220 ℃, the carbon diffuses from martensite to austenite phase in the process of partitioning. After I&Q&P process, the tensile strength of experimental steel is 1310 MPa, elongation up to 12%, the product of strength and elongation up to more than 15000 MPa.%. The steel only contains a small amount of retained austenite by only C partitioning after traditional Q&P process, while the steel contains more Mn-rich retained austenite after I&Q&P process. Hence, the content and stability of retained austenite of steel can be improved significantly, which enhance the formability at room temperature.

Key words:  high strength steel      intercritical annealing      Mn partitioning      C partitioning      retained austenite      mechanical property     
Received:  07 November 2013     
ZTFLH:  TG156  
Fund: Supported by National Natural Science Foundation of China (Nos.51254004 and 51304186) and Natural Science Foundation of Hebei Province (No.E2014209191)

URL: 

https://www.ams.org.cn/EN/10.3724/SP.J.1037.2013.00709     OR     https://www.ams.org.cn/EN/Y2014/V50/I5/531

Fig.1  

不同热处理工艺流程图

Fig.2  

760 ℃保温不同时间并淬火后钢的SEM像

Fig.3  

不同保温时间对马氏体体积分数的影响

Fig.4  

760 ℃保温不同时间并淬火后钢的EBSD像

Fig.5  

760 ℃保温不同时间并淬火后钢中Mn元素分布的EMPA像

Fig.6  

760 ℃保温不同时间并淬火后钢中马氏体的Mn含量变化趋势

Fig.7  

不同工艺处理后钢的SEM像

Fig.8  

I&Q&P处理后钢中马氏体和残余奥氏体的Mn元素分布

Fig.9  

不同工艺下钢的XRD谱

Process Rm / MPa Rp0.2 / MPa A / % Rm·A / (MPa·%)
Original 640 505 26.0 16640
Q&P 1560 1150 8.3 12948
I&Q&P 1310 975 12.0 15720
表1  不同工艺处理后钢的力学性能
  

I&Q&P工艺各阶段组织演变过程模型

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