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金属学报  2009, Vol. 45 Issue (6): 737-743    
  论文 本期目录 | 过刊浏览 |
半固态条件下球晶生长形态的稳定性
统雷雷; 林鑫; 赵力宁;黄卫东
(西北工业大学凝固技术国家重点实验室; 西安 710072)
MORPHOLOGICAL STABILITY OF GLOBULAR CRYSTAL DURING SEMI--SOLID PROCESSING
TONG Leilei; LIN Xin; ZHAO Lining; HUANG Weidong
State Key Laboratory of Solidification Processing; Northwestern Polytechnical University; Xi'an 710072
引用本文:

统雷雷 林鑫 赵力宁 黄卫东. 半固态条件下球晶生长形态的稳定性[J]. 金属学报, 2009, 45(6): 737-743.
, , , . MORPHOLOGICAL STABILITY OF GLOBULAR CRYSTAL DURING SEMI--SOLID PROCESSING[J]. Acta Metall Sin, 2009, 45(6): 737-743.

全文: PDF(1618 KB)  
摘要: 

采用类金属丁二腈 (SCN) 和H2O配制的SCN--5%H2O (摩尔分数) 透明合金研究了不同过冷度和搅拌速率下半固态球晶生长的形态稳定性. 结果表明,随着搅拌速率的提高, 球晶形成的孕育期急剧减小. 在低搅拌速率下, 随着过冷度的提高, 球晶形成的孕育期明 显减小; 而在高搅拌速率下, 过冷度的作用并不明显. 随着搅拌速率的增大, 球晶的固相分数先增加、后减小. 当搅拌速率增加到一定值后, 球晶组织将完全消失. 球--枝转变存在一个临界的过冷度. 采用高搅拌速率得到稳定的孤立球晶后停止搅拌并保温, 可以发现当过冷度为2.9℃时,球晶可以一直生长到100 μm以上时才失去相对稳定性, 并发生球--枝转化; 但过冷度为1.9℃时, 球晶生长到一定尺寸后将不再长大, 而且这个尺寸远远小于100 μm. 根据这些生长行为, 可以通过控制搅拌速率和过冷度从而优化半固态过程的凝固组织形态.

关键词 半固态 球晶 形态稳定性 过冷度 搅拌速率    
Abstract

With the intensive development of semisolid metal processing technology, an important near--net--shape processing technology, the interaction between melt flow and solidification microstructure becomes gradually one of the important fundamental research fields in materials science. The most important characteristic of semisolid processing is as follows: the solidification microstructure changes markedly under either mechanical stirring or electromagnetic stirring, from dendritic growth under traditional conditions to non--dendritic or globular growth. However, understanding and modeling of the nucleation and crystal growth during semisolid solidification are more difficult than in conventional casting processes due to complicated effects of strong convection. Hence, to date, the formation mechanism of this kind of globular microstructure has not yet been much studied. In the present work, morphological stability of globular crystal was experimentally studied using a succinonitrile--5%H2O (molar fraction) transparent alloy under different undercoolings and stirring rates. Succinonitrile--5%H2O transparent alloy was heated to 55℃ (5.1℃ above the liquidus temperature) and held for\linebreak 30 min. The melt was then cooled to a temperature below the liquidus temperature at a cooling rate of 0.1℃/min and a series of stirring rates.  In~situ observation was performed using a stereomicroscope and JVC video camera. The results show that the incubation time for the formation of globular crystal decreases rapidly with the increase of stirring rate. When the stirring rate is low, the incubation time for the formation of globular crystal decreases obviously with the increase of undercooling. When the stirring rate is high, the effect of undercooling on the incubation time for the formation of globular crystal is weak. With the increase of stirring rate, the solid fraction of globular crystal increases at first, and then decreases. When the stirring rate increases to a certain value, the globular crystal will completely disappear. There is a critical undercooling for the transition of growth behaviour of globular crystals. Under the present experimental condition, when the undercooling is larger than the critical value, the size of globular crystal can increase to above 100 μm without globular/dendritic transition. But when the undercooling is less than the critical value, globular crystal will grow to a definite size much smaller than 100 μm. According to the growth behaviors of globular crystal, the semi--solid microstructure could be refined well under an optimized stirring rate and undercooling.

Key wordssemi-solid;morphological instability;globular crystals;undercooling;stirring rate
收稿日期: 2008-11-27     
ZTFLH: 

TG244

 
基金资助:

国家自然科学基金项目50771083和新世纪优秀人才支持计划项目06--0879资助

作者简介: 统雷雷, 男, 1983年生, 硕士生

[1] Flemings M C. Metall Trans, 1991; 22B: 957
[2] Spencer D B, Mehrabian R, Flemings M C. Metall Trans,1972; 3A: 1925
[3] Doherty R D, Lee H I, Feest E A. Mater Sci Eng, 1984; 65: 181
[4] Hellawell A. In: Kirkwood D H, Kapranos P eds., Proc 4th Int Conf on Semi–Solid Processing of Alloys and Composites. Sheffield, UK: The University of Sheffield, 1996: 60
[5] Van Dam J C, Mischgofsky F H. J Mater Sci, 1982; 17: 989
[6] Fan Z. Int Mater Rev, 2002; 47: 49
[7] Li T, Lin X, Huang W D. Acta Mater, 2006; 54: 481
[8] Lin X, Li T, Huang W D. Solid State Phenom, 2006; 16–17: 155
[9] Li T, Huang W D, Lin X. Chin J Nonferrous Met, 2000; 10: 635
(李 涛, 黄卫东, 林 鑫. 中国有色金属学报, 2000; 10: 635)
[10] Ji S, Fan Z, Bevis M J. Mater Sci Eng, 2001; A299: 210
[11] Martinez R A, Flemings M C. Metall Mater Trans, 2005;36A: 2205
[12] James E S J, Donald O F, William F K. Scr Metall, 1984; 18: 677
[13] Trivedi R. J Cryst Growth, 1980; 48: 93
[14] Schulze T P, Davis S H. J Cryst Growth, 1995; 149: 253
[15] Turnbull D, Fisher J C. J Chem Phys,1949; 17: 71
[16] Liu Z E. Foundations of Materials Science. Xi’an: Northwestern Polytechnical University Press, 2000: 81
(刘智恩. 材料科学基础. 西安: 西北工业大学出版社, 2000: 81)
[17] Li T, Lin X, Wang L L, Xue L, Zhao X M, Huang W D.J Mater Sci Eng, 2003; 21: 741
(李涛, 林 鑫, 王琳琳, 薛蕾, 赵晓明, 黄卫东. 材料科学与工程学报, 2003; 21: 741)
[18] Iida T, Guthrie R I L. The Physical Properties of Liquid Metal. Oxford: Clarenpon Press, 1993: 173

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