综述：SiC/Al界面反应与界面结构演变规律及机制

doi:10.11900/0412.1961.2018.00292

金属学报

2019, Vol. 55

Issue (1): 87-100 DOI: 10.11900/0412.1961.2018.00292

本期目录 | 过刊浏览

综述：SiC/Al界面反应与界面结构演变规律及机制

邱丰, 佟昊天, 沈平, 丛晓霜, 王轶, 姜启川(

)

吉林大学材料科学与工程学院长春 130025

Overview: SiC/Al Interface Reaction and Interface Structure Evolution Mechanism

Feng QIU, Haotian TONG, Ping SHEN, Xiaoshuang CONG, Yi WANG, Qichuan JIANG(

)

Department of Materials Science and Engineering, Jilin University, Changchun 130025, China

引用本文:

邱丰, 佟昊天, 沈平, 丛晓霜, 王轶, 姜启川. 综述：SiC/Al界面反应与界面结构演变规律及机制[J]. 金属学报, 2019, 55(1): 87-100.
Feng QIU, Haotian TONG, Ping SHEN, Xiaoshuang CONG, Yi WANG, Qichuan JIANG. Overview: SiC/Al Interface Reaction and Interface Structure Evolution Mechanism[J]. Acta Metall Sin, 2019, 55(1): 87-100.

全文: PDF(2627 KB) HTML

摘要:

高温制备过程中熔融Al与SiC直接接触,二者间界面反应发生的可能性与多向性直接影响复合材料的界面结合状态。全面了解Al和SiC之间的界面结合、界面反应、界面结构等对于提高材料性能有着极其重要的作用。尽管人们对Al及其合金与SiC之间的润湿性和界面反应的研究很多,但很多结论仍存在分歧,且对Al与SiC真实润湿性的认识不够全面。Al与SiC之间界面反应发生的反应程度与反应时间、温度有很大关系,但是对于反应参数与反应程度之间的具体对应关系还没有系统的综述。合金元素的添加可以减弱界面反应的发生,然而在不同反应条件下,所添加合金元素的量与界面反应程度的关系,以及合金元素对于界面反应的影响机制还没有明确报道。本文系统地综述在确定的反应时间与反应温度条件下的界面反应、界面产物以及反应产物演变规律及机制等,Al以及添加不同合金元素的合金与SiC界面情况及界面润湿行为影响机制。从界面润湿、界面反应以及界面产物角度,为制备复合材料过程中所选择的工艺参数提供实验依据。

关键词 ： SiC/Al, 铝基复合材料, 界面反应, 界面结构, 润湿行为

Abstract：

During the high-temperature melting process, Al is in full contact with SiC. The interface bonding properties of composites are closely related to the possibility and multi-directionality of interface reaction between them. A comprehensive understanding of the interfacial bonding, interfacial reaction, and interface structure between Al and SiC is of great significance for improving the material properties.There have been many researches on the wettability and interface reaction between Al or its alloys and SiC. However, there are still some differences and disputes on some issues, and the understanding of the true wettability of Al and SiC is not systematic enough. Reaction time and temperature have a great influence on the degree of interface reaction between Al and SiC, but there is still no systematic review on the specific relationship between reaction parameters and reaction degree. The addition of alloying elements can weaken the occurrence of interfacial reactions. However, under different reaction conditions, the relationship between the amount of alloying elements added and the reaction degree, and the mechanism of action of alloying elements on interface reaction have not been clearly reported. This article systematically reviews the interfacial reactions, interfacial products and reaction product evolution rules and mechanisms under specific reaction conditions, Al and the addition of different alloying elements to the SiC interface and interface wetting behavior. From the aspects of interfacial wetting, interfacial reaction and interfacial product, this article provided experimental data, theoretical references for the selection of process parameters during the preparation of composite.

Key words： SiC/Al aluminum matrix composite interfacial reaction interface structure wetting behavior

收稿日期: 2018-06-29

ZTFLH:

TB333

基金资助:国家重点研发计划项目No.2017YFB0703101

作者简介:

作者简介邱丰,男,1980年生,教授,博士

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	邱丰
	佟昊天
	沈平
	丛晓霜
	王轶
	姜启川
44.8K

链接本文:

https://www.ams.org.cn/CN/10.11900/0412.1961.2018.00292 或 https://www.ams.org.cn/CN/Y2019/V55/I1/87

图1 Si—C双原子层结构及6H-SiC晶体结构示意图

图2 973~1173 K温度范围内熔融Al在6H-SiC单晶Si终结面和C终结面上接触角随时间的变化[21]

图3 1173 K时Al/多晶SiC与Al/SiO2体系接触角随时间变化曲线对比[20]

图4 Al-Si/SiC初始及(准)平衡黏着功的实验值与房鑫[49]所计算理论值的比较

图5 Al-Cu/SiC初始及(准)平衡黏着功的实验值与房鑫[49]所计算理论值的比较

图6 Al-Mg/SiC和Al-Mg/SiCox初始及(准)平衡黏着功的实验值与房鑫[49]所计算理论值的比较

图7 Al-Ti/SiC初始及(准)平衡黏着功的实验值与房鑫[49]所计算理论值的比较

[1]	Taya M, Arsenault R J.A comparison between a shear lag type model and an eshelby type model in predicting the mechanical properties of a short fiber composite[J]. Scr. Metall., 1987, 21: 349
[2]	Luo C P, Sui X D, Ouyang L Z, et al.Crvstallographic orientation relationship between SiC and Al in SiCp/Al-Si composites[J]. Acta Metall. Sin., 1999, 35: 343(罗承萍, 隋贤栋, 欧阳柳章等. SiCp/Al-Si复合材料中SiC/Al的晶体学位向关系[J]. 金属学报, 1999, 35: 343)
[3]	Lü W J, Bian Y J, Zhang D, et al.Growth mechanism of reinforcement in in situ processed TiC/Ti composites[J]. Acta Metall. Sin., 1999, 35: 536(吕维洁, 卞玉君,张荻等. 原位合成TiC/Ti基复合材料增强体的生长机制[J]. 金属学报, 1999, 35: 536)
[4]	Fan G L, Yu Z Y, Tan Z Q, et al.Evolution, control, and effects of interface in CNT/Al composites: A review[J]. Acta Metall. Sin.(Engl. Lett.), 2014, 27: 839
[5]	Qian F.An investigation on fabrication of SiCp/Al composite materials with pressureless infiltration techniques [D]. Nanjing: Nanjing University of Science and Technology, 2008(钱凤. 无压浸渗法制备SiCp/Al复合材料的研究 [D]. 南京: 南京理工大学, 2008)
[6]	Nie J H, Fan J Z, Zhang S M, et al.Tensile and fracture properties of 15 vol% SiCp/2009Al composites fabricated by hot isostatic pressing and hot extrusion processes[J]. Acta Metall. Sin.(Engl. Lett.), 2014, 27: 875
[7]	Shi Z L, Ochiai S, Gu M Y, et al.Interfacial microstructure evolution in aluminium matrix composites reinforced with unoxidized and oxidized SiC particles[J]. Surf. Interface Anal., 2001, 31: 375
[8]	Gupta M, Surappa M K, Qin S.Effect of interfacial characteristics on the failure-mechanism mode of a SiC reinforced A1 based metal-matrix composite[J]. J. Mater. Process. Technol., 1997, 67: 94
[9]	Rado C, Kalogeropoulou S, Eustathopoulos N.Bonding and wetting in non-reactive metal/SiC systems: Weak or strong interfaces[J]. Mater. Sci. Eng., 2000, A276: 195
[10]	Luo Z P, Song Y G, Zhang S Q.A TEM study of the microstructure of SiCP/Al composite prepared by pressureless infiltration method[J]. Scr. Mater., 2001, 45: 1183
[11]	Shi Z L, Gu M Y, Liu J Y, et al.Interfacial reaction between the oxidized SiC particles and Al-Mg alloy[J]. Chin. Sci. Bull., 2001, 46: 1161(施忠良, 顾明元, 刘俊友等. 氧化的碳化硅与铝镁合金之间的界面反应[J]. 科学通报, 2001, 46: 1161)
[12]	Wu G H, Su J, Gou H S, et al.Study on graphite fiber and Ti particle reinforced Al composite[J]. J. Mater. Sci., 2009, 44: 4776
[13]	Song M H, Wu G H, Yang W S, et al.Mechanical properties of Cf/Mg composites fabricated by pressure infiltration method[J]. J. Mater. Sci. Technol., 2010, 26: 931
[14]	Cong X S.Wettability of silicon carbide by molten aluminum or aluminum alloys and their interfacial microstructures [D]. Changchun: Jilin University, 2014(丛晓霜. Al及其合金与多晶α-SiC陶瓷的润湿及界面结构 [D]. 长春: 吉林大学, 2014)
[15]	Wang W M, Pan F S, Sun X W, et al.Advance in research on interfacial reaction in SiCp/Al composites[J]. J. Chongqing Univ.: Nat. Sci. Ed., 2004, 27: 108(王文明, 潘复生, 孙旭炜等. SiCp/Al复合材料界面反应研究现状[J]. 重庆大学学报: 自然科学版, 2004, 27: 108)
[16]	Viala J C, Fortier P, Bouix J.Stable and metastable phase equilibria in the chemical interaction between aluminium and silicon carbide[J]. J. Mater. Sci., 1990, 25: 1842
[17]	Viala J C, Bosselet F, Laurent F, et al.Mechanism and kinetics of the chemical interaction between liquid aluminium and silicon-carbide single crystals[J]. J. Mater. Sci., 1993, 28: 5301
[18]	Peteves S D, Tambuyser P, Helbach P, et al.Microstructure and microchemistry of the Al/SiC interface[J]. J. Mater. Sci., 1990, 25: 3765
[19]	Iseki T, Kameda T, Maruyama T.Interfacial reactions between SiC and aluminium during joining[J]. J. Mater. Sci., 1984, 19: 1692
[20]	Cong X S, Shen P, Wang Y, et al.Wetting of polycrystalline SiC by molten Al and Al-Si alloys[J]. Appl. Surf. Sci., 2014, 317: 140
[21]	Shen P, Wang Y, Ren L H, et al.Influence of SiC surface polarity on the wettability and reactivity in an Al/SiC system[J]. Appl. Surf. Sci., 2015, 355: 930
[22]	Laurent V, Chatain D, Eustathopoulos N.Wettability of SiC by aluminium and Al-Si alloys[J]. J. Mater. Sci., 1987, 22: 244
[23]	Laurent V, Rado C, Eustathopoulos N.Wetting kinetics and bonding of Al and Al alloys on α-SiC[J]. Mater. Sci. Eng., 1996, A205: 1
[24]	Ferro A C, Derby B.Wetting behaviour in the Al-Si/SiC System: Interface reactions and solubility effects[J]. Acta Metall. Mater., 1995, 43: 3061
[25]	Hashim J, Looney L, Hashmi M S J. The wettability of SiC particles by molten aluminium alloy[J]. J. Mater. Process. Technol., 2001, 119: 324
[26]	Landry K, Rado C, Eustathopoulos N.Influence of interfacial reaction rates on the wetting driving force in metal/ceramic systems[J]. Metall. Mater. Trans., 1996, 27A: 3181
[27]	Wang Y.Wettability of SiC single crystal and carbon nanotubes by molten aluminum and their interfacial microstructures [D]. Changchun: Jilin University, 2015(王轶. Al在单晶SiC和碳纳米管上的润湿性及界面结构 [D]. 长春: 吉林大学, 2015)
[28]	Liu J S.Wettability of silicon carbide and silica by molten aluminum alloys and their interfacial microstructures [D]. Changchun: Jilin University, 2016(刘精深. Al合金与SiC和SiO2的润湿性及界面结构 [D]. 长春: 吉林大学, 2016)
[29]	Dezellus O, Hodaj F, Eustathopoulos N.Chemical reaction-limited spreading: The triple line velocity versus contact angle relation[J]. Acta Mater., 2002, 50: 4741
[30]	Cassie A B D. Contact angle[J]. Discuss. Faraday Soc., 1948, 3: 11
[31]	León C, Drew R.The influence of nickel coating on the wettability of aluminum on ceramics[J]. Composites, 2002, 33A: 1429
[32]	Zhou J, Dru?d?el A T, Duszczyk J.The effect of extrusion parameters on the fretting wear resistance of Al-based composites produced via powder metallurgy[J]. J. Mater. Sci., 1999, 34: 5089
[33]	Shi Z, Ochiai S, Gu M, et al.The formation and thermostability of MgO and MgAl2O4 nanoparticles in oxidized SiC particle-reinforced Al-Mg composites[J]. Appl. Phys., 2002, 74A: 97
[34]	Xu X Y, Wang H Y, Zha M, et al.Effects of Ti, Si, Mg and Cu additions on interfacial properties and electronic structure of Al(111)/4H-SiC(0001) interface: A first-principles study[J]. Appl. Surf. Sci., 2018, 437: 103
[35]	Beer S Z.Liquid Metals: Chemistry and Physics[M]. New York: Marcel Dekker, 1972: 127
[36]	Lee J C, Ahn J P, Shim J H, et al.Interfacial phenomena in the SiC/2024Al composite: II Tailoring the interface[J]. Korea Inst. Met. Mater., 2000, 38: 322
[37]	Pai B C, Ramani G, Pillai R M, et al.Role of magnesium in cast aluminium alloy matrix composites[J]. J. Mater. Sci., 1995, 30: 1903
[38]	Guo J.The effects and mutual action of alloy elements and SiC particulate surface condition on the interface of SiCp/Al composites [D]. Zhengzhou: Zhengzhou University, 2003(郭建. 合金元素及增强体表面状况对SiCp/Al复合材料界面的影响及其交互作用 [D]. 郑州: 郑州大学, 2003)
[39]	Guo J, Shen N F.Control of detrimental interface reaction in SiCp/Al composite materials[J]. Mater. Sci. Eng., 2002, 20: 605(郭建, 沈宁福. SiC颗粒增强Al基复合材料中有害界面反应的控制[J]. 材料科学与工程, 2002, 20: 605)
[40]	Pech-Canul M I, Katz R N, Makhlouf M M, et al. The role of silicon in wetting and pressureless infiltration of SiCp preforms by aluminum alloys[J]. J. Mater. Sci., 2000, 35: 2167
[41]	Ramani G, Pillai R M, Pai B C, et al.Effect of mixing conditions and reactive elements on the porosity and dispersion of SiC particulate in cast Al-SiCp composites[J]. J. Mater. Sci., 1993, 12: 1117
[42]	Ferro A C, Derby B.Wetting behaviour in the Al-Si/SiC System: Interface reactions and solubility effects[J]. Acta Metall. Mater., 1995, 43: 3061
[43]	Lee J C, Byun J Y, Park S B, et al.Prediction of Si contents to suppress the formation of Al4C3 in the SiCp/Al composite[J]. Acta Mater., 1998, 46: 1771
[44]	Fang X, Fan T X, Zhang D.Work of adhesion in Al/SiC composites with alloying element addition[J]. Metall. Mater. Trans., 2013, 44A: 5192
[45]	Lee J C, Byun J Y, Oh C S, et al.Effect of various processing methods on the interfacial reactions in SiCp/2024 Al composites[J]. Acta Mater., 1997, 45: 5303
[46]	Han D S, Jones H, Atkinson H V.The wettability of silicon carbide by liquid aluminium: The effect of free silicon in the carbide and of magnesium, silicon and copper alloy additions to the aluminium[J]. J. Mater. Sci., 1993, 28: 2654
[47]	Candan E.Effect of alloying elements to aluminium on the wettability of Al/SiC system[J]. Turk. J. Eng. Environ. Sci., 2002, 26: 1
[48]	Rodríguez-Reyes M, Pech-Canul M I, Rendón-Angeles J C, et al. Limiting the development of Al4C3 to prevent degradation of Al/SiCp composites processed by pressureless infiltration[J]. Compos. Sci. Technol., 2006, 66: 1056
[49]	Fang X.Thoeretical prediction of interfacial reaction and work of adhesion in SiC/Al composites [D]. Shanghai: Shanghai Jiao Tong University, 2013(房鑫. SiC/Al复合材料界面反应与粘着功理论预测研究 [D]. 上海: 上海交通大学, 2013)
[50]	Lee J C, Park S B, Seok H K, et al.Prediction of Si contents to suppress the interfacial reaction in the SiCp/2014 Al composite[J]. Acta Mater., 1998, 46: 2635
[51]	Li J G, Coudurier L, Eustathopoulos N.Work of adhesion and contact-angle isotherm of binary alloys on ionocovalent oxides[J]. J. Mater. Sci., 1989, 24: 1109
[52]	Zhong W M, L'Espérance G, Suéry M. Interfacial reactions in Al-Mg (5083)/Al2O3p composites during fabrication and remelting[J]. Metall. Mater. Trans., 1995, 26A: 2625
[53]	Ghosh P K, Ray S.Influence of annealing on the mechanical properties of compocast Al(Mg)-Al2O3 particulate composite[J]. J. Mater. Sci., 1993, 28: 3783
[54]	Sreekumar V M, Ravi K R, Pillai R M, et al.Thermodynamics and kinetics of the formation of Al2O3/MgAl2O4/MgO in Al-silica metal matrix composite[J]. Metall. Mater. Trans., 2008, 39A: 919
[55]	Lee K B, Kim Y S, Kwon H.Fabrication of Al-3 Wt pct Mg matrix composites reinforced with Al2O3 and SiC particulates by the pressureless infiltration technique[J]. Metall. Mater. Trans., 1998, 29A: 3087
[56]	Petitcorps Y L, Quenisset J M, Le Borgne G, et al.Segregation of magnesium in squeeze-cast aluminium matrix composites reinforced with alumina fibres[J]. Mater. Sci. Eng., 1991, A135: 37
[57]	Hallstedt B, ?gren J, Liu Z K.Fibre-matrix interactions during fabrication of Al2O3 Mg metal matrix composites[J]. Mater. Sci. Eng., 1990, A129: 135
[58]	Zuo R.The reaction and structure evolution at the interfaces of Al/Al alloy-SiC/SiCox [D]. Changchun: Jilin University, 2017(左蕊. Al/Al合金-SiC/SiCox界面反应与结构演变 [D]. 长春: 吉林大学, 2017)
[59]	Ribes H, Suéry M, L'esperance Q, et al. Microscopic examination of the interface region in 6061-Al/SiC composites reinforced with as-received and oxidized SiC particles[J]. Metall. Mater. Trans., 1990, 21A: 2489
[60]	Fishkis M.Interfaces and fracture surfaces in Saffil/Al-Mg-Cu metal-matrix composites[J]. J. Mater. Sci., 1991, 26: 2651
[61]	Lee J C, Lee H I, Ahn J P, et al.Modification of the interface in SiC/Al composites[J]. Metall. Mater. Trans., 2000, 31A: 2361
[62]	Ma X C, Wu J B.An investigation on wettability and interfacial phenomena of Al-SiC system[J]. Mater. Sci. Eng., 1994, 12(1): 37(马晓春, 吴锦波. Al-SiC系润湿性与界面现象的研究[J]. 材料科学与工程, 1994, 12(1): 37)
[63]	Pan F S, Zhang J, Chen H, et al.Effect of rare earth additions on the wettability of An-Al-Zn-Mg-Cu/Al2O3 system[J]. Acta Mater. Compos. Sin., 1998, 15(1): 46(潘复生, 张静, 陈晖等. 稀土对Al-Zn-Mg-Cu/Al2O3陶瓷界面润湿性的影响[J]. 复合材料学报, 1998, 15(1): 46)
[64]	Carotenuto G, Gallo A, Nicolais L.Degradation of SiC particles in aluminium-based composites[J]. J. Mater. Sci., 1994, 29: 4967
[65]	Eustathopoulos N, Coudurier L. Adsorption and wettability in metal/ceramic system [A]. Capillarity Today [C]. Berlin: Springer, 1991, vol.386: 15
[66]	Saiz E, Tomsia A P.Atomic dynamics and Marangoni films during liquid-metal spreading[J]. Nat. Mater., 2004, 3: 903
[67]	Tanaka S, Kohyama M.Ab initio calculations of 3C-SiC[111]/Ti polar interfaces [A]. 2000 International Semiconducting and Insulating Materials Conference[C]. Canberra, ACT, Australia, Australia: IEEE, 2000: 299
[68]	Zhang L J, Yang D L, Qiu F, et al.Effects of reinforcement surface modification on the microstructures and tensile properties of SiCp/Al2014 composites[J]. Mater. Sci. Eng., 2015, A624: 102
[69]	Shaga A.Fabrication of nacre-inspired Al alloy/SiC lamellar composites and their microstructures and properties [D]. Changchun: Jilin University, 2016(阿拉腾沙嘎. 仿珍珠贝Al合金/SiC层状复合材料的制备、组织与性能 [D]. 长春: 吉林大学, 2016)
[70]	Zhang H, Shen P, Shaga A, et al.Preparation of nacre-like composites by reactive infiltration of a magnesium alloy into porous silicon carbide derived from ice template[J]. Mater. Lett., 2016, 183: 299
[71]	Shen P, Xi J W, Fu Y J, et al.Preparation of high-strength Al-Mg-Si/Al2O3 composites with lamellar structures using freeze casting and pressureless infiltration techniques[J]. Acta Metall. Sin.(Engl. Lett.), 2014, 27: 944
[72]	Shaga A, Shen P, Sun C, et al.Lamellar-interpenetrated Al-Si-Mg/SiC composites fabricated by freeze casting and pressureless infiltration[J]. Mater. Sci. Eng., 2015, A630: 78
[73]	Shaga A, Shen P, Guo R F, et al.Effects of oxide addition on the microstructure and mechanical properties of lamellar SiC scaffolds and Al-Si-Mg/SiC composites prepared by freeze casting and pressureless infiltration[J]. Ceram. Int., 2016, 42: 9653

[1]	马宗义, 肖伯律, 张峻凡, 朱士泽, 王东. 航天装备牵引下的铝基复合材料研究进展与展望[J]. 金属学报, 2023, 59(4): 457-466.
[2]	李谦, 孙璇, 罗群, 刘斌, 吴成章, 潘复生. 镁基材料中储氢相及其界面与储氢性能的调控[J]. 金属学报, 2023, 59(3): 349-370.
[3]	沈莹莹, 张国兴, 贾清, 王玉敏, 崔玉友, 杨锐. SiC_f/TiAl复合材料界面反应及热稳定性[J]. 金属学报, 2022, 58(9): 1150-1158.
[4]	宋庆忠, 潜坤, 舒磊, 陈波, 马颖澈, 刘奎. 镍基高温合金K417G与氧化物耐火材料的界面反应[J]. 金属学报, 2022, 58(7): 868-882.
[5]	聂金凤, 伍玉立, 谢可伟, 刘相法. Al-AlN异构纳米复合材料的组织构型与热稳定性[J]. 金属学报, 2022, 58(11): 1497-1508.
[6]	刘悦, 汤鹏正, 杨昆明, 沈一鸣, 吴中光, 范同祥. 抗辐照损伤金属基纳米结构材料界面设计及其响应行为的研究进展[J]. 金属学报, 2021, 57(2): 150-170.
[7]	毕胜, 李泽琛, 孙海霞, 宋保永, 刘振宇, 肖伯律, 马宗义. 高能球磨结合粉末冶金法制备碳纳米管增强7055Al复合材料的微观组织和力学性能[J]. 金属学报, 2021, 57(1): 71-81.
[8]	王超, 张旭, 王玉敏, 杨青, 杨丽娜, 张国兴, 吴颖, 孔旭, 杨锐. SiC_f/Ti65复合材料界面反应与基体相变机理[J]. 金属学报, 2020, 56(9): 1275-1285.
[9]	张志杰, 黄明亮. 原位研究Cu/Sn-37Pb/Cu微焊点液-固电迁移行为[J]. 金属学报, 2020, 56(10): 1386-1392.
[10]	吕钊钊,祖宇飞,沙建军,鲜玉强,张伟,崔鼎,严从林. 含Cu界面层碳纤维增强铝基复合材料制备工艺及其力学性能研究[J]. 金属学报, 2019, 55(3): 317-324.
[11]	冯业飞,周晓明,邹金文,王超渊,田高峰,宋晓俊,曾维虎. 粉末高温合金中SiO₂夹杂物与基体的界面反应机理及对其变形行为的影响[J]. 金属学报, 2019, 55(11): 1437-1447.
[12]	马凯, 张星星, 王东, 王全兆, 刘振宇, 肖伯律, 马宗义. SiC/2009Al复合材料的变形加工参数的优化仿真研究[J]. 金属学报, 2019, 55(10): 1329-1337.
[13]	王晨, 王贝贝, 薛鹏, 王东, 倪丁瑞, 陈礼清, 肖伯律, 马宗义. SiC_p/6092Al复合材料搅拌摩擦焊接头的疲劳行为研究[J]. 金属学报, 2019, 55(1): 149-159.
[14]	赵乃勤, 刘兴海, 蒲博闻. 多维度碳纳米相增强铝基复合材料研究进展[J]. 金属学报, 2019, 55(1): 1-15.
[15]	范同祥, 刘悦, 杨昆明, 宋健, 张荻. 碳/金属复合材料界面结构优化及界面作用机制的研究进展[J]. 金属学报, 2019, 55(1): 16-32.

Viewed

Full text

Abstract

Cited

Shared

Discussed