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金属学报  2010, Vol. 46 Issue (8): 941-945    DOI: 10.3724/SP.J.1037.2010.00143
  论文 本期目录 | 过刊浏览 |
时效析出相对铸造2507超级双相不锈钢力学及耐蚀性能的影响
向红亮,刘东,阮方如,何福善,黄利光
福州大学机械工程及自动化学院, 福州 350108
EFFECTS OF PRECIPITATION FOR AGING ONMECHANICAL AND CORROSION RESISTANCE PROPERTIES OF CAST 2507 SUPER DUPLEX STAINLESS STEEL
XIANG Hongliang, LIU Dong, RUAN Fangru, HE Fushan, HUANG Liguang
School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou 350108
引用本文:

向红亮 刘东 阮方如 何福善 黄利光. 时效析出相对铸造2507超级双相不锈钢力学及耐蚀性能的影响[J]. 金属学报, 2010, 46(8): 941-945.
, , , , . EFFECTS OF PRECIPITATION FOR AGING ONMECHANICAL AND CORROSION RESISTANCE PROPERTIES OF CAST 2507 SUPER DUPLEX STAINLESS STEEL[J]. Acta Metall Sin, 2010, 46(8): 941-945.

全文: PDF(7008 KB)  
摘要: 

通过OM, SEM以及拉伸实验与电化学测试等手段, 研究了高温时效析出金属间相对铸造2507超级双相不锈钢力学及耐蚀性能的影响. 实验结果表明: 材料固溶后经650-950 ℃时效处理, 析出弥散颗粒χ相有提高抗拉强度的作用,σ相却使抗拉强度急剧下降; 二者均使塑性急剧恶化, 拉伸断口均表现为脆性断裂. 在人工海水中, σ相对材料的耐蚀性影响要比$\chi$相弱,其数量越多, 材料耐蚀性越差.

关键词 铸造2507超级双相不锈钢 金属间相 力学性能 耐蚀性    
Abstract

Duplex stainless steel (DSS) has been used widely due to its very excellent combination of mechanical and corrosion resistance properties. However, the use of DSS is limited by their susceptibility to the formation of dangerous intermetallic phases, such as χ phase and phase, resulting in the detrimental effects on mechanical properties and corrosion resistance. With the application of the super duplex stainless steel (SDSS) with a pitting resistance equivalent number more than 40. The harmful effects of intermetallic phases easily precipitated in DSS on mechanical properties and corrosion resistance are a research focus. This paper, based on prior study, investigates the effects of intermetallic phases formed during aging on the mechanical properties and corrosion resistance of cast 2507 super duplestainless steel by means of optical microscope (OM), scanning electron microscope (SEM), tensile test and electrochemical test. The results indicate that for the solution annealing cast 2507 super duplex stainless steel aged in the temperature range 650—950 ℃, small and depressive distribution χ phase precipitatd from ferrite can increase its tensile strength, but σ phase causes the opposing effect on its plasticity owing to precipitated along grain boundaries. Both of them can rapidly deteriorate its plasticity, and cause brittle failure. The effect of σ phase on corrosion resistance of 2507 SDSS is weaker than phase. The more the σ phase is, the worse the corrosion resistant could be.

Key wordscast 2507 super duplex stainless steel    intermetallic phase    mechanical roperty    corrosion resistance
收稿日期: 2010-03-25     
基金资助:

科技部科技人员服务企业项目2009GJC40018, 福建省青年人才创新基金项目2008F3061和福州大学科技发展基金项目2008--XQ--16资助

作者简介: 向红亮, 男, 1972年生, 副教授
[1] Wu J. Corrosion & Protection in Petrochem Industry, 1996; 13: 6 (吴玖.石油化工腐蚀与防护. 1996; 13: 6) [2] Graham G. 2th Int Conf on Duplex Stainless Steel. Beijing: Stainless steel council China Special steel Enterprises association, 2006:218 [3] Benson M, Snis M. 2th Int Conf on Duplex Stainless Steel. Beijing: Stainless steel council China Special steel Enterprises association, 2006:17 [4] Erich F, translated by Su Z X. Welding metallurgy of stainless steel, Beijing: Chemical Industry Press, 2004: 74 (Erich F著, 栗卓新译. 不锈钢焊接冶金. 北京: 化学工业出版社, 2004: 74) [5] Henrik S, Rolf S. Mater Sci Eng, 2007, 444A: 271 [6] Elmer J W, Palmer T A. Mater Sci Eng, 2007, 459 A: 151 [7] Russell S W, Lundin C D. Final Report for the Development of Energy: the Development of Qualification Standards for Cast Duplex Stainless Steel the University of Tennessee Knoxville, 2005,2:8 [8] Ezuber H M,. El-Houd A,. El-Shawesh F. Desalination. 2007, 207: 268 [9]Huang C, Shih C. Mater Sci Eng, 2005,A402: 66 [10] Chen J Y, Yang Z Y, Yang W, Su J, Luo F H. J Iron Steel Res, 2006; 18:2 (陈嘉砚, 杨卓越, 杨武, 苏杰, 罗丰华. 钢铁研究学报. 2006, 18: 1) [11] Long J M, Fan A M. Phys Test, 1997; 15(1):1 (龙晋明, 樊爱民. 物理测试. 1997; 15(1):1) [12] Otarola T, Hollner S, Bonnefois B. Eng Fail Anal, 2005; 12: 930 [13] Marcelo M, Leonardo R F. Mater Char. 2007; doi:10.1016/j.matchar.2007.02.010. [14] Pohl M, Storz O, Glogowski T. Mater Sci Eng, 2007, 58: 66. [15].Redja A,. Proult A,. Donnadieu P,. Morniroli J. J Mater Sci, 2004; 39: 2386. [16] Takuyo Y, Satoshi O, Hisashi K. J Nuclear Mater. 2006, 350: 47 [17] Xiang H L, He F S, Liu D. Acta Metall Sin, 2009; 45:1456 (向红亮, 何福善, 刘东. 金属学报, 2009; 45: 1456 [18] Jang Y, Kim S, Lee J. Metall Mater Trans, 2005; 36A: 1229 [19] Chiu P K, Wang S.H, Yang J R, Weng K L, Jason F. Mater Chem Phys, 2006; 98: 103 [20] Zhong Q P. Zhao Z H. Fractography. Beijing: High Education Press, 2006: 202 (钟群鹏, 赵子华. 断口学. 北京: 高等教育出版社, 2006:202) [21] Tavares S S, Terra V. F, Neto P, Lima, D E. Matos. Microchimica Acta. 2005, 40: 4025 [22] Xiang H L, Huang W L, Liu D, He F S. Acta Metall Sin. 2010, 46:304 (向红亮, 黄伟林, 刘东, 何福善. 金属学报. 2010, 46: 304)
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