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金属学报  2023, Vol. 59 Issue (9): 1109-1124    DOI: 10.11900/0412.1961.2023.00140
  综述 本期目录 | 过刊浏览 |
镍基单晶高温合金的研发进展
张健1(), 王莉1, 谢光1, 王栋1, 申健1, 卢玉章1, 黄亚奇1, 李亚微1,2
1中国科学院金属研究所 沈阳 110016
2中国科学技术大学 材料科学与工程学院 沈阳 110016
Recent Progress in Research and Development of Nickel-Based Single Crystal Superalloys
ZHANG Jian1(), WANG Li1, XIE Guang1, WANG Dong1, SHEN Jian1, LU Yuzhang1, HUANG Yaqi1, LI Yawei1,2
1Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
2School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
引用本文:

张健, 王莉, 谢光, 王栋, 申健, 卢玉章, 黄亚奇, 李亚微. 镍基单晶高温合金的研发进展[J]. 金属学报, 2023, 59(9): 1109-1124.
Jian ZHANG, Li WANG, Guang XIE, Dong WANG, Jian SHEN, Yuzhang LU, Yaqi HUANG, Yawei LI. Recent Progress in Research and Development of Nickel-Based Single Crystal Superalloys[J]. Acta Metall Sin, 2023, 59(9): 1109-1124.

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摘要: 

单晶高温合金是先进航空发动机、燃气轮机的核心热端材料,单晶叶片要求高、制造工艺复杂、容错空间小,在高温、复杂应力、氧化和热腐蚀等苛刻环境下工作。本文概述了近几年镍基单晶高温合金在合金研制、组织性能演化和表征、近服役环境下力学行为评价以及叶片制造工艺等方面的研发进展,并简单介绍了难熔高熵合金等“下一代”新型高温结构材料的研发情况。

关键词 单晶高温合金合金设计力学性能定向凝固    
Abstract

Single crystal Ni-based superalloys are key materials used in the hot section of aeroengines and industrial gas turbines. In service, single crystal blades face harsh environments, including high temperatures, complex stresses, oxidation and hot corrosion. Therefore, they must meet strict technical specifications, such as impurity, defects and dimensional control. Single crystal components should be manufactured using complex technologies within a highly narrow processing window. The present paper reviews recent progress in the research and development of alloy design, microstructure and property evolution and characterization, evaluation in near-service conditions, and single crystal manufacture. Further, the development of “next generation” high-temperature structural materials, such as refractory high-entropy alloys, is briefly discussed.

Key wordssingle crystal superalloy    alloy design    mechanical property    directional solidification
收稿日期: 2023-04-03     
ZTFLH:  TG132.3  
基金资助:国家重点研发计划项目(2021YFB3702900);国家自然科学基金项目(5227-1042);国家自然科学基金项目(52071219);国家自然科学基金项目(52201151);国家自然科学基金项目(U2141206);国家自然科学基金项目(U2241283);国家科技重大专项项目(P2022-C-IV-001-001);国家科技重大专项项目(P2021-AB-IV-001-002);国家科技重大专项项目(J2019-IV-0006-0074);国家科技重大专项项目(J2019-VI-0010-0124);中国科学院依托中国散裂中子源的定向性建制化科研平台项目,中国科学院国际伙伴计划项目(172GJHZ2022095FN);哈尔滨工业大学金属精密热加工国家级重点实验室项目(JCKYS2022603C008)
作者简介: 张 健,男,1972年生,研究员,博士
图1  各代次单晶高温合金持久性能对比[3~10]
图2  单晶高温合金蠕变变形机制示意图
DS processAlloyPDAS / μmVolume fraction of porosity / %Average porosity size / μm2
HRSCMSX-4333-3840.072-0.10218.9
FBCCMSX-4248-2750.022-0.0458.8
LMCDD331800.026.8
表1  不同定向凝固工艺制备的单晶铸件组织对比
图3  液态金属冷却(LMC)工艺过程的数值模拟
图4  不同温度下高熵合金和高温合金的高温压缩、拉伸屈服强度对比[176~193]
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