涂层<strong>/</strong>高温合金界面行为及调控研究进展

doi:10.11900/0412.1961.2023.00257

金属学报

2023, Vol. 59

Issue (9): 1097-1108 DOI: 10.11900/0412.1961.2023.00257

综述

本期目录 | 过刊浏览

涂层/高温合金界面行为及调控研究进展

宫声凯¹^,²(

), 刘原³, 耿粒伦⁴, 茹毅¹^,², 赵文月¹, 裴延玲¹, 李树索³

¹北京航空航天大学前沿科学技术创新研究院北京 100191
²天目山实验室杭州 311115
³北京航空航天大学航空发动机学院北京 100191
⁴北京航空航天大学材料科学与工程学院北京 100191

Advances in the Regulation and Interfacial Behavior of Coatings/Superalloys

GONG Shengkai¹^,²(

), LIU Yuan³, GENG Lilun⁴, RU Yi¹^,², ZHAO Wenyue¹, PEI Yanling¹, LI Shusuo³

¹Frontier Research Institute of Innovative Science and Technology, Beihang University, Beijing 100191, China
²Tianmu Mountain Laboratory, Hangzhou 311115, China
³Research Institute of Aero-Engine, Beihang University, Beijing 100191, China
⁴School of Materials Science and Engineering, Beihang University, Beijing 100191, China

引用本文:

宫声凯, 刘原, 耿粒伦, 茹毅, 赵文月, 裴延玲, 李树索. 涂层/高温合金界面行为及调控研究进展[J]. 金属学报, 2023, 59(9): 1097-1108.
Shengkai GONG, Yuan LIU, Lilun GENG, Yi RU, Wenyue ZHAO, Yanling PEI, Shusuo LI. Advances in the Regulation and Interfacial Behavior of Coatings/Superalloys[J]. Acta Metall Sin, 2023, 59(9): 1097-1108.

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摘要:

防护涂层技术对于提高涡轮叶片材料抗氧化腐蚀性能、保证涡轮叶片安全服役具有至关重要的作用，然而，防护涂层与高温合金间有本征的物理、化学性能不匹配性，其界面反应会导致界面组织退化，合金与涂层性能下降，成为制约涂层应用的关键因素。本文概述了典型涂层/高温合金界面组织演变与扩散行为及其影响因素，讨论了界面行为对含涂层高温合金组织稳定性和力学性能的影响，从涂层组织成分优化、界面阻扩散层设计和新型界面稳定涂层研发3个方面介绍了涂层/合金界面的调控方法。总结了涂层/高温合金界面相容性的关键特征，并提出未来应在界面对涂层/合金性能的影响规律与机制、调控界面的多手段联用、计算辅助涂层设计等方面开展系统性研究。

关键词 ：高温合金, 防护涂层, 界面扩散, 组织演变, 力学性能

Abstract：

With the continuous increase of turbine inlet temperature of advanced aero-engine, the protective coating technology plays a vital role in improving the oxidation and corrosion resistance of turbine blade materials to ensure the safe performance of turbine blades. However, an intrinsic physical and chemical property mismatch exists between protective coating and superalloy. Interfacial reaction leads to the degradation of interfacial microstructure and mechanical properties. It is the key factor to restrict the application of coating. In this paper, the evolution and diffusion behavior of typical coating/superalloy interface microstructure and its influencing factors are summarized. The influence of interfacial behavior on microstructural stability and mechanical properties of superalloys with coatings is also discussed. The control methods of coating/alloy interface are introduced from three aspects, including the optimization of microstructure composition, design of interfacial diffusion-resistant layer, and development of a new type of interfacial stabilizing coating. Furthermore, the key characteristics of the compatibility of the coating/superalloy interface are summarized, which will promote systematic studies on the effect of the interface on the coating/alloy properties, the combination of multiple methods to control the interface, and the computer-aided coating design.

Key words： superalloy protective coating interfacial diffusion microstructure evolution mechanical property

收稿日期: 2023-06-13

ZTFLH:

TG111.6

基金资助:国家自然科学基金项目(52101117)

作者简介: 宫声凯，男，1956年生，教授，博士

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链接本文:

https://www.ams.org.cn/CN/10.11900/0412.1961.2023.00257 或 https://www.ams.org.cn/CN/Y2023/V59/I9/1097

图1 保温不同时间含涂层合金等效承载面位置示意图

图2 梯度MCrAlY涂层截面形貌

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