Please wait a minute...
金属学报  2010, Vol. 46 Issue (6): 755-760    DOI: 10.3724/SP.J.1037.2009.00597
  论文 本期目录 | 过刊浏览 |
25钢在海水中的微生物单因素腐蚀
吴进怡1; 3; 柴柯1; 肖伟龙1;杨雨辉2; 韩恩厚3
1. 海南大学材料与化工学院海南优势资源化工材料应用技术教育部重点实验室; 海口 570228
2. 海南大学农学院; 海口 570228
3. 中国科学院金属研究所金属腐蚀与防护国家重点实验室; 沈阳 110016
THE SINGLE EFFECT OF MICROBE ON THE CORROSION BEHAVIORS OF 25 STEEL IN SEAWATER
WU Jinyi 1; 3; CHAI Ke 1; XIAO Weilong 1; YANG Yuhui 2; Han Enhou 3
1. Key Laboratory of Ministry of Education for Application Technology of Chemical Materials in Hainan Superior Resources; Material and Chemical Engineering College; Hainan University; Haikou 570228
2. Agricultural College; Hainan University; Haikou 570228
3. State Key Laboratory for Corrosion and Protection of Metals; Institute of Metal Research; Chinese Academy of Sciences; Shenyang 110016
引用本文:

吴进怡 柴柯 肖伟龙 杨雨辉 韩恩厚. 25钢在海水中的微生物单因素腐蚀[J]. 金属学报, 2010, 46(6): 755-760.
, , , , . THE SINGLE EFFECT OF MICROBE ON THE CORROSION BEHAVIORS OF 25 STEEL IN SEAWATER[J]. Acta Metall Sin, 2010, 46(6): 755-760.

全文: PDF(1155 KB)  
摘要: 

通过对比25钢在自然海水和无菌海水中的腐蚀行为, 研究了微生物单因素对25钢腐蚀行为的影响. 结果表明, 微生物对25钢的腐蚀有显著影响, 微生物对25钢平均腐蚀速率的影响与微生物种类和含量密切相关. 锈层中的微生物主要由假单胞菌、弧菌、铁细菌、硫杆菌和硫酸盐还原菌组成, 浸泡365 d时还出现大量的黄杆菌. 其中好氧菌、兼性厌氧菌和厌氧菌的含量均随浸泡时间规律性变化, 这也导致在不同浸泡时间下微生物的作用及其作用机理的不同.

关键词 25钢 海水 微生物 腐蚀    
Abstract

Biological elements have a significant impact on lifetime prediction of marine carbon steel facilities. Microbe can produce pitting, crevice corrosion, selective dealloying and stress–oriented hydrogen–induced cracking, which accelerate both localized and average corrosion rates of carbon steel.
The formation of microbe films can also reduce the corrosion rate of 25 steel through inhibition of oxygen diffusion and depletion of oxygen in the electrolyte and metal/solution interface. The research on the single effect of microbe on the corrosion behaviors of metal is insufficient up to now. In this work, the single effect of microbe on the corrosion behaviors of 25 steel was studied by comparing the corrosion behaviors of the carbon steel in natural seawater and in serile seawater. The results show that in most of mmerging periods, the bacterial activity at the interface accelerated the average corrosion rate of 25 steel. When the corrosion time was 365 d, the average corrosion rate of 25 steel immersed in natural seawater was 2.6 times that in sterile seawater. However, when the corrosion time was 28 d, the biofilms inhibited the corrosion of 25 steel. The species and contents of microbes significantly influenced the corrosion behavior of 25 steel. The microbes in the corrosion product mainly consisted of pseudomonas, vibrio, crenothrixandleptothrix, thiobacillus and sulfate–reducing bacteria. When the corrosion time was 365 d, flavobacterium also existed in the corrosion product. The contents of aerobe, facultative anaerobe and anaerobe reached the maximum vale when the corrosion time was 28, 91 and 184 d, respectively. The regular change of the contents of microbes with the immerging time led to the different microbe corrosion mechanisms of 25 steel.

Key words25 steel    seawater    mcrobe    corrosion
收稿日期: 2009-09-09     
基金资助:

国家自然科学基金项目50761004、海南省自然科学基金项目807011和80630及海南大学2005和2009科研项目Kyjj0536和hd09xm77资助

作者简介: 吴进怡, 女, 1976年生, 副教授

[1] Little B, Wagner P. Mater Performance, 1997; 36(6): 40
[2] Little B, Wagner P. J Adhes, 1986; 20: 187
[3] Li X B, Wang W, Wang J, Liu W Y. Corros Sci Prot Technol, 2002; 14: 218
(李相波, 王伟, 王佳, 刘五一. 腐蚀科学与防护技术, 2002; 14: 218)
[4] Jung H G, Yoo J Y, Woo J S. ISIJ Int, 2003; 43: 1603
[5] Mathiyarasu J, Palaniswamy N, Muralidharan V S. Corros Rev, 2000; 18: 65
[6] Walsh D, Pope D, Danford M, Huff T. JOM, 1993; 45(9): 22
[7] Liu D Y, Wei K J, Li W J, Cao F Y. J Chin Soc Corros Prot, 2003; 23: 211
(刘大扬, 魏开金, 李文军, 曹付炎. 中国腐蚀与防护学报, 2003; 23: 211)
[8] Busalmen J P, V´azquez M, de S´anchez S R. Electrochim Acta, 2002; 47: 1857
[9] de Damborenea J J, Crist´obal A B, Arenas M A, L´opez V, Conde A. Mater Lett, 2007; 61: 821
[10] Crist´obal A B, Arenas M A, Conde A, de Damborenea J. Electrochim Acta, 2006; 52: 546
[11] Sand W. Int Biodeterior Biodegrad, 1997; 40: 183
[12] Mansfeld F, Little B. Corros Sci, 1991; 32: 247
[13] Buchanan R E, Gibbons N E, Bergey’s. Manual of Determinative Bacteriology. 8th Ed., Baltimore, Maryland: The Williams and Wilkins Company, 1974: 7
[14] Sreekumari K R, Nandakumar K, Takao K, Kikuchi Y. ISIJ Int, 2003; 43: 1799
[15] Little B, Wagner P, Mansfeld F. Electrochim Acta, 1992; 37: 2185
[16] Ponmariappan S, Maruthamuthu S, Palaniswamy N, Palaniappan R. Corros Rev, 2004; 22: 307

[1] 司永礼, 薛金涛, 王幸福, 梁驹华, 史子木, 韩福生. Cr添加对孪生诱发塑性钢腐蚀行为的影响[J]. 金属学报, 2023, 59(7): 905-914.
[2] 张奇亮, 王玉超, 李光达, 李先军, 黄一, 徐云泽. EH36钢在不同粒径沙砾冲击下的冲刷腐蚀耦合损伤行为[J]. 金属学报, 2023, 59(7): 893-904.
[3] 陈润农, 李昭东, 曹燕光, 张启富, 李晓刚. 9%Cr合金钢在含Cl环境中的初期腐蚀行为及局部腐蚀起源[J]. 金属学报, 2023, 59(7): 926-938.
[4] 王宗谱, 王卫国, Rohrer Gregory S, 陈松, 洪丽华, 林燕, 冯小铮, 任帅, 周邦新. 不同温度轧制Al-Zn-Mg-Cu合金再结晶后的{111}/{111}近奇异晶界[J]. 金属学报, 2023, 59(7): 947-960.
[5] 李小涵, 曹公望, 郭明晓, 彭云超, 马凯军, 王振尧. 低碳钢Q235、管线钢L415和压力容器钢16MnNi在湛江高湿高辐照海洋工业大气环境下的初期腐蚀行为[J]. 金属学报, 2023, 59(7): 884-892.
[6] 赵平平, 宋影伟, 董凯辉, 韩恩厚. 不同离子对TC4钛合金电化学腐蚀行为的协同作用机制[J]. 金属学报, 2023, 59(7): 939-946.
[7] 王京阳, 孙鲁超, 罗颐秀, 田志林, 任孝旻, 张洁. 以抗CMAS腐蚀为目标的稀土硅酸盐环境障涂层高熵化设计与性能提升[J]. 金属学报, 2023, 59(4): 523-536.
[8] 吴欣强, 戎利建, 谭季波, 陈胜虎, 胡小锋, 张洋鹏, 张兹瑜. Pb-Bi腐蚀Si增强型铁素体/马氏体钢和奥氏体不锈钢的研究进展[J]. 金属学报, 2023, 59(4): 502-512.
[9] 韩恩厚, 王俭秋. 表面状态对核电关键材料腐蚀和应力腐蚀的影响[J]. 金属学报, 2023, 59(4): 513-522.
[10] 常立涛. 压水堆主回路高温水中奥氏体不锈钢加工表面的腐蚀与应力腐蚀裂纹萌生:研究进展及展望[J]. 金属学报, 2023, 59(2): 191-204.
[11] 夏大海, 计元元, 毛英畅, 邓成满, 祝钰, 胡文彬. 2024铝合金在模拟动态海水/大气界面环境中的局部腐蚀机制[J]. 金属学报, 2023, 59(2): 297-308.
[12] 廖京京, 张伟, 张君松, 吴军, 杨忠波, 彭倩, 邱绍宇. Zr-Sn-Nb-Fe-V合金在过热蒸汽中的周期性钝化-转折行为[J]. 金属学报, 2023, 59(2): 289-296.
[13] 胡文滨, 张晓雯, 宋龙飞, 廖伯凯, 万闪, 康磊, 郭兴蓬. 共晶高熵合金AlCoCrFeNi2.1H2SO4 溶液中的腐蚀行为[J]. 金属学报, 2023, 59(12): 1644-1654.
[14] 宋嘉良, 江紫雪, 易盼, 陈俊航, 李曌亮, 骆鸿, 董超芳, 肖葵. 高铁转向架用钢G390NH在模拟海洋和工业大气环境下的腐蚀行为及产物演化规律[J]. 金属学报, 2023, 59(11): 1487-1498.
[15] 马志民, 邓运来, 刘佳, 刘胜胆, 刘洪雷. 淬火速率对7136铝合金应力腐蚀开裂敏感性的影响[J]. 金属学报, 2022, 58(9): 1118-1128.