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Acta Metall Sin  1995, Vol. 31 Issue (20): 353-359    DOI:
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FORMATION MECHANISM FOR NANOCRYSTALLINE FROM AMORPHOUS Fe_(85)Zr_9B_6 AND Fe_(84)Zr_9B_6Cu_1 ALLOYS
LING Gang; JI Yu; HU Xiao jun; WU Qiulin; CHU Wei; YANG Guobin; WANG Run (University of Science & Technology Beijing; Beijing 100083) (Shougang Metallurgical Research Institute; Beijing 100085) (Manuscript received 1994-11-25; in revised form 1995-04-03)
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LING Gang; JI Yu; HU Xiao jun; WU Qiulin; CHU Wei; YANG Guobin; WANG Run (University of Science & Technology Beijing; Beijing 100083) (Shougang Metallurgical Research Institute; Beijing 100085) (Manuscript received 1994-11-25; in revised form 1995-04-03). FORMATION MECHANISM FOR NANOCRYSTALLINE FROM AMORPHOUS Fe_(85)Zr_9B_6 AND Fe_(84)Zr_9B_6Cu_1 ALLOYS. Acta Metall Sin, 1995, 31(20): 353-359.

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Abstract  The microstructure changes in the nanocrystalline soft magnetic material of FeZrB(Cu) alloys with different temperatures of heat treatment and dynamic heating-up processes have been investigated by using TEM and EDAX. It has been found that there appears appreciable phase separation before crystallization. In amorphous phase there are Zr-rich and Fe-rich regions. The Zr-rich phase has a very important effect on precipitation and stability of bcc Fe phase, and the obvious precipitation of α-Zr phase indictates the beginning of instable growth for bcc Fe phase. It has been confirmed that the phase separation of FeZrB(Cu) alloys is a spinodal decomposition process. Correspondent. LING Gang, postdoctor, Box 61, Beijing Agricultural Engineering University, Beijing 100083
Key words:  nanocrystal      amorphous phase      crystallization     
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