Structure and Glass-Forming Ability of Al-Based Amorphous Alloys

doi:10.11900/0412.1961.2021.00561

Acta Metall Sin

2022, Vol. 58

Issue (4): 457-472 DOI: 10.11900/0412.1961.2021.00561

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Structure and Glass-Forming Ability of Al-Based Amorphous Alloys

LI Jinfu¹^,²(

), LI Wei¹

^1.State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
^2.Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

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LI Jinfu, LI Wei. Structure and Glass-Forming Ability of Al-Based Amorphous Alloys. Acta Metall Sin, 2022, 58(4): 457-472.

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Abstract

Although Al-based amorphous alloys have excellent mechanical properties and good corrosion resistance, their poor glass-forming ability makes large-scale samples difficult to obtain, limiting their engineering applications. Owing to the close relationship between the glass-forming ability of alloys and their structure, the development of Al-based amorphous alloys is first briefly reviewed to gain a thorough understanding of their component composition. On this basis, the microstructure, composition design theory, relationship between glass-forming ability and composition, and selection of primary phase during crystallization in Al-based amorphous alloys are discussed. Finally, the future study directions for Al-based amorphous alloys are prospected.

Key words: Al-based amorphous alloy microstructure glass-forming ability crystallization behavior

Received: 14 December 2021

ZTFLH:

TG146.21

Fund: National Natural Science Foundation of China(51620105012);National Natural Science Foundation of China(51771116);National Natural Science Foundation of China(51821001)

About author: LI Jinfu, professor, Tel: (021)54748530, E-mail: jfli@sjtu.edu.cn

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Table 1 Glass formation in Al₇₀LTM₂₀ETM₁₀ (LTM = Fe, Co, Ni, Cu; ETM = Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W) alloys solidified by melt spinning^[15]

N	$R N *$	N	$R N *$
3	0.155	14	1.047
4	0.225	15	1.116
5	0.362	16	1.183
6	0.414	17	1.248
7	0.518	18	1.311
8	0.617	19	1.373
9	0.710	20	1.433
10	0.799	21	1.491
11	0.884	22	1.548
12	0.902	23	1.604
13	0.976	24	1.659

Table 2 The coordination number (N) in the atomic cluster and the corresponding radius ratio between the central atom and the first neighbor coordination atom (

R N *

)^[36]

Fig.1 Differential intensity profile of amorphous Al₉₀Y₁₀ (top) determined from the intensity profiles (bottom) measured at incident energies of 17.0126 and 16.7380 keV, which correspond to the energies of 25 and 300 eV below the Y K-absorption edge. The arrow indicates the prepeak (Q is the wave number in inerted space)^[41]

Fig.2 Random close packing of quasi-equivalent, solute-centered atomic clusters to form Al-based amorphous alloys, as shown in ab initio molecular dynamics (MD) simulations^[67]
(a) the ternary Al₈₉Ni₅La₆ system (b) the quaternary Al₈₅Ni₅Y₈Co₂ system

Fig.3 Distribution of the coordination number (CN) of Ni and La in the Al₈₉Ni₅La₆ amorphous alloy. The bottom panel shows the topologies of dominant Ni-centered, and La-centered clusters with different sizes and CN numbers (listed in the parentheses) as frequently found in the amorphous alloy^[67]

Fig.4 The concentration (atomic fraction) as a function of atomic radius of Al-based amorphous alloys (a) and bulk amorphous alloys (b)^[35]

Fig.5 Bright-field TEM images of as-quenched (a) and annealed (220^oC for 1 min) (b) samples of Al₈₈Ni₄Gd₆La₂ amorphous alloy^[118]

Table 3 Primary crystallization product of Al₈₇Ni₆RE₇ and Al₈₅Ni₆RE₉ (RE = La, Ce, Nd, Y) amorphous alloys^[145]

Fig.6 Al-isoconcentration contours as a function of the selected concentration (as marked) in as-quenched Al₈₆Ni₉La₅ (a-d) and (Al₈₆Ni₉La₅)₉₈Si₂ (e-h) ribbons^[147]

1	Greer A L. Metallic glasses [J]. Science, 1995, 267: 1947
2	Zeng Q S, Yin Z L, Lou H B. Polyamorphic transitions in metallic glasses [J]. Acta Metall. Sin., 2021, 57: 492
	曾桥石, 尹梓梁, 楼鸿波. 金属玻璃中的非晶多形态转变 [J]. 金属学报, 2021, 57: 492
3	Wang W H, Dong C, Shek C H. Bulk metallic glasses [J]. Mater. Sci. Eng., 2004, R44: 45
4	Qiao J C, Wang Q, Pelletier J M, et al. Structural heterogeneities and mechanical behavior of amorphous alloys [J]. Prog. Mater. Sci., 2019, 104: 250
5	Predecki P, Giessen B C, Grant N J. New metastable alloy phases of gold, silver, and aluminum [J]. Trans. Metall. Soc. AIME, 1965, 233: 1438
6	Ramachandrarao P, Laridjani M, Cahn R W. Diamond as a splat-cooling substrate [J]. Int. J. Mater. Res., 1972, 63: 43
7	Davies H A, Hull J B. A non-crystalline phase in splat-quenched germanium [J]. Scr. Metall., 1973, 7: 637
8	Grant N J, Giessen B C. Proceedings of the Second International Conference on Rapidly Quenched Metals [M]. Cambridge, MA: MIT Press, 1975: 1
9	Sastry G V S, Suryanarayana C, Srivastava O N. Crystallization of an amorphous aluminum-palladium alloy [J]. Trans. Indian Inst. Met., 1978, 31: 292
10	Furrer P, Warlimont H. Crystalline and amorphous structures of rapidly solidified Al-Cr alloys [J]. Mater. Sci. Eng., 1977, 28: 127
11	Inoue A, Kitamura A, Masumoto T. The effect of aluminium on mechanical properties and thermal stability of (Fe, Co, Ni)-Al-B ternary amorphous alloys [J]. J. Mater. Sci., 1981, 16: 1895
12	Suzuki R O, Komatsu Y, Kobayashi K F, et al. Formation and crystallization of Al-Fe-Si amorphous alloys [J]. J. Mater. Sci., 1983, 18: 1195
13	Inoue A, Bizen Y, Kimura H M, et al. Development of compositional short-range ordering in an Al₅₀Ge₄₀Mn₁₀ amorphous alloy upon annealing [J]. J. Mater. Sci. Lett., 1987, 6: 811
14	Inoue A, Yamamoto M, Kimura H M, et al. Ductile aluminium-base amorphous alloys with two separate phases [J]. J. Mater. Sci. Lett., 1987, 6: 194
15	Tsai A P, Inoue A, Masumoto T. Formation of metal-metal type aluminum-based amorphous alloys [J]. Metall. Trans., 1988, 19A: 1369
16	Tsai A P, Inoue A, Masumoto T. Ductile Al-Ni-Zr amorphous alloys with high mechanical strength [J]. J. Mater. Sci. Lett., 1988, 7: 805
17	Inoue A, Ohtera K, Masumoto T. New amorphous Al-Y, Al-La and Al-Ce alloys prepared by melt spinning [J]. Jpn. J. Appl. Phys., 1988, 27: L736
18	Inoue A, Zhang T, Kita K, et al. Mechanical strengths, thermal stability and electrical resistivity of aluminum-rare earth metal binary amorphous alloys [J]. Mater. Trans., JIM, 1989, 30: 870
19	Inoue A, Ohtera K, Zhang T, et al. New amorphous Al-Ln (Ln = Pr, Nd, Sm or Gd) alloys prepared by melt spinning [J]. Jpn. J. Appl. Phys., 1988, 27: L1583
20	Inoue A, Ohtera K, Tsai A P, et al. New amorphous alloys with good ductility in Al-Y-M and Al-La-M (M = Fe, Co, Ni or Cu) systems [J]. Jpn. J. Appl. Phys., 1988, 27: L280
21	Inoue A, Ohtera K, Kita K, et al. New amorphous alloys with good ductility in Al-Ce-M (M = Nb, Fe, Co, Ni or Cu) systems [J]. Jpn. J. Appl. Phys., 1988, 27: L1796
22	Wang S H, Yang C C, Bian X F. Developing aluminum-based amorphous alloys [J]. Mater. Rev., 2012, 26(1): 88
	王胜海, 杨春成, 边秀房. 铝基非晶合金的研究进展 [J]. 材料导报, 2012, 26(1): 88
23	Yang B J, Yao J H, Zhang J, et al. Al-rich bulk metallic glasses with plasticity and ultrahigh specific strength [J]. Scr. Mater., 2009, 61: 423
24	He Y, Poon S J, Shiflet G J. Synthesis and properties of metallic glasses that contain aluminum [J]. Science, 1988, 241: 1640
25	Inoue A. Amorphous, nanoquasicrystalline and nanocrystalline alloys in Al-based systems [J]. Prog. Mater. Sci., 1998, 43: 365
26	Kim Y H, Inoue A, Masumoto T. Ultrahigh tensile strengths of Al₈₈Y₂Ni₉ M₁ (M = Mn or Fe) amorphous alloys containing finely dispersed FCC-Al particles [J]. Mater. Trans., JIM, 1990, 31: 747
27	Inoue A, Kimura H. Fabrications and mechanical properties of bulk amorphous, nanocrystalline, nanoquasicrystalline alloys in aluminum-based system [J]. J. Light Met., 2001, 1: 31
28	Debenedetti P G, Stillinger F H. Supercooled liquids and the glass transition [J]. Nature, 2001, 410: 259
29	Bernal J D. A geometrical approach to the structure of liquids [J]. Nature, 1959, 183: 141
30	Bernal J D. Geometry of the structure of monatomic liquids [J]. Nature, 1960, 185: 68
31	Gaskell P H. New structural model for transition metal-metalloid glasses [J]. Nature, 1978, 276: 484
32	Gaskell P H. New structural model for amorphous transition metal silicides, borides, phosphides and carbides [J]. J. Non-Cryst. Solids, 1979, 32: 207
33	Nelson D R, Spaepen F. Polytetrahedral order in condensed matter [J]. Solid State Phys., 1989, 42: 1
34	Nelson D R. Order, frustration, and defects in liquids and glasses [J]. Phys. Rev., 1983, 28B: 5515
35	Senkov O N, Miracle D B. Effect of the atomic size distribution on glass forming ability of amorphous metallic alloys [J]. Mater. Res. Bull., 2001, 36: 2183
36	Miracle D B, Sanders W S, Senkov O N. The influence of efficient atomic packing on the constitution of metallic glasses [J]. Philos. Mag., 2003, 83: 2409
37	Miracle D B, Senkov O N. A geometric model for atomic configurations in amorphous Al alloys [J]. J. Non-Cryst. Solids, 2003, 319: 174
38	Miracle D B. A structural model for metallic glasses [J]. Nat. Mater., 2004, 3: 697
39	Miracle D B. The efficient cluster packing model—An atomic structural model for metallic glasses [J]. Acta Mater., 2006, 54: 4317
40	Yi J J. Glass forming ability and crystallization behavior of Al-Ni-Re alloys [D]. Shanghai: Shanghai Jiao Tong University, 2016
	乙姣姣. Al-Ni-RE合金的非晶形成能力与晶化行为 [D]. 上海: 上海交通大学, 2016
41	Matsubara E, Waseda Y, Inoue A, et al. Anomalous X-ray scattering on amorphous Al₈₇Y₈Ni₅ and Al₉₀Y₁₀ alloys [J]. Z. Naturforsch., 1989, 44A: 814
42	Hsieh H Y, Egami T, He Y, et al. Short range ordering in amorphous Al₉₀Fe _x Ce_{10 -} _x [J]. J. Non-Cryst. Solids, 1991, 135: 248
43	Hsieh H Y, Toby B H, Egami T, et al. Atomic structure of amorphous Al₉₀Fe _x Ce_{10 -} _x [J]. J. Mater. Res., 1990, 5: 2807
44	Zhang L, Wu Y S, Bian X F, et al. Origin of the prepeak in the structure factors of liquid and amorphous Al-Fe-Ce alloys [J]. J. Phys. Condens. Matter, 1999, 11: 7959
45	Zhang L, Wu Y S, Bian X F, et al. Short-range and medium-range order in liquid and amorphous Al₉₀Fe₅Ce₅ alloys [J]. J. Non-Cryst. Solids, 2000, 262: 169
46	Mansour A N, Wong C P, Brizzolara R A. Atomic structure of amorphous Al_{100 - 2} _x Co _x Ce _x (x = 8, 9, and 10) and Al₈₀Fe₁₀Ce₁₀ alloys: An XAFS study [J]. Phys. Rev., 1994, 50B: 12401
47	Mansour A N, Marcelli A, Cibin G, et al. Amorphous Al₉₀Fe _x Ce_{10 -} _x alloys: X-ray absorption analysis of the Al, Fe and Ce local atomic and electronic structures [J]. Phys. Rev., 2002, 65B: 134207
48	Yang H, Wang J Q, Li Y. Influence of TM and RE elements on glass formation of the ternary Al-TM-RE systems [J]. J. Non-Cryst. Solids, 2008, 354: 3473
49	Saksl K, Jóvári P, Franz H, et al. Atomic structure of Al₈₈Y₇Fe₅ metallic glass [J]. J. Appl. Phys., 2005, 97: 113507
50	Saksl K, Jóvári P, Franz H, et al. Atomic structure of Al₈₉La₆Ni₅ metallic glass [J]. J. Phys.: Condens. Matter, 2006, 18: 7579
51	Bacewicz R, Antonowicz J. XAFS study of amorphous Al-RE alloys [J]. Scr. Mater., 2006, 54: 1187
52	Zalewski W, Antonowicz J, Bacewicz R, et al. Local atomic order in Al-based metallic glasses studied using XAFS method [J]. J. Alloys Compd., 2009, 468: 40
53	Takeuchi A, Inoue A. Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element [J]. Mater. Trans., 2005, 46: 2817
54	Egami T. The atomic structure of aluminum based metallic glasses and universal criterion for glass formation [J]. J. Non-Cryst. Solids, 1996, 205-207: 575
55	Xiong X Z, Yi J J, Kong L T, et al. The atomic packing structure of Al-(TM)-Y metallic glasses [J]. Intermetallics, 2019, 111: 106505
56	Xiong X Z. Glass forming ability and atomic packing structure of Al-based amorphous alloys [D]. Shanghai: Shanghai Jiao Tong University, 2019
	熊贤仲. Al基非晶合金的玻璃形成能力与原子堆垛结构 [D]. 上海: 上海交通大学, 2019
57	Waseda Y. The Structure of Non-Crystalline Materials [M]. New York: McGraw-Hill, 1980: 1
58	Zhang F, Sun Y, Ye Z, et al. Solute-solute correlations responsible for the prepeak in structure factors of undercooled Al-rich liquids: A molecular dynamics study [J]. J. Phys. Condens. Matter, 2015, 27: 205701
59	Tang L, Yang Z J, Wen T Q, et al. Short- and medium-range orders in Al₉₀Tb₁₀ glass and their relation to the structures of competing crystalline phases [J]. Acta Mater., 2021, 204: 116513
60	Ahn K, Louca D, Poon S J, et al. Topological and chemical ordering induced by Ni and Nd in Al₈₇Ni₇Nd₆metallic glass [J]. Phys. Rev., 2004, 70B: 224103
61	Cheng Y Q, Ma E. Atomic-level structure and structure-property relationship in metallic glasses [J]. Prog. Mater. Sci., 2011, 56: 379
62	Jakse N, Lebacq O, Pasturel A. Ab initio molecular-dynamics simulations of short-range order in liquid Al₈₀Mn₂₀ and Al₈₀Ni₂₀ alloys [J]. Phys. Rev. Lett., 2004, 93: 207801
63	Yu C Y, Hui X D, Chen X H, et al. Ab initio molecular dynamics simulation of the atom packing and density of Al-Ni amorphous alloys [J]. Sci. China Technol. Sci., 2010, 53: 3175
64	Wang F R, Zhang H P, Li M Z. Correlation between structure and glass-forming ability in Al₈₆Ni_{14 -} _x La _x (x = 3, 5, 9) alloys: An ab initio molecular dynamics study [J]. J. Alloys Compd., 2018, 763: 392
65	Cheng Y Q, Ma E, Sheng H W. Atomic level structure in multicomponent bulk metallic glass [J]. Phys. Rev. Lett., 2009, 102: 245501
66	Sun Y, Zhang Y, Zhang F, et al. Cooling rate dependence of structural order in Al₉₀Sm₁₀ metallic glass [J]. J. Appl. Phys., 2016, 120: 015901
67	Sheng H W, Cheng Y Q, Lee P L, et al. Atomic packing in multicomponent aluminum-based metallic glasses [J]. Acta Mater., 2008, 56: 6264
68	Turnbull D. Under what conditions can a glass be formed? [J]. Contemp. Phys., 1969, 10: 473
69	Inoue A. High strength bulk amorphous alloys with low critical cooling rates (Overview) [J]. Mater. Trans., JIM, 1995, 36: 866
70	Lu Z P, Liu C T. Glass formation criterion for various glass-forming systems [J]. Phys. Rev. Lett., 2003, 91: 115505
71	Lu Z P, Liu C T. A new glass-forming ability criterion for bulk metallic glasses [J]. Acta Mater., 2002, 50: 3501
72	Ma C S, Zhang J, Hou W L, et al. Efficient atomic packing clusters and glass formation in ternary Al-based metallic glasses [J]. Philos. Mag. Lett., 2008, 88: 599
73	Yang B J, Yao J H, Chao Y S, et al. Developing aluminum-based bulk metallic glasses [J]. Philos. Mag., 2010, 90: 3215
74	Zhang Z, Xiong X Z, Zhou W, et al. Glass forming ability and crystallization behavior of Al-Ni-RE metallic glasses [J]. Intermetallics, 2013, 42: 23
75	Egami T, Waseda Y. Atomic size effect on the formability of metallic glasses [J]. J. Non-Cryst. Solids, 1984, 64: 113
76	Lisboa R D S, Bolfarini C, Botta F W J, et al. Topological instability as a criterion for design and selection of aluminum-based glass-former alloys [J]. Appl. Phys. Lett., 2005, 86: 211904
77	Ueno S, Waseda Y. Evaluation of the optimum solute concentration for good glass formability in multi-component alloys [J]. J. Mater. Eng., 1987, 9: 199
78	Waseda Y, Chen H S, Thomas Jacob K, et al. On the glass forming ability of liquid alloys [J]. Sci. Technol. Adv. Mater., 2008, 9: 023003
79	Zhang Z, Xiong X Z, Yi J J, et al. Crystallization behavior and thermal stability of Al-Ni-RE metallic glasses [J]. Acta Phys. Sin., 2013, 62: 136401
	张章, 熊贤仲, 乙姣姣等. Al-Ni-RE非晶合金的晶化行为和热稳定性 [J]. 物理学报, 2013, 62: 136401
80	Nagel S R, Tauc J. Nearly-free-electron approach to the theory of metallic glass alloys [J]. Phys. Rev. Lett., 1975, 35: 380
81	Wu N C, Lian J B, Wang R, et al. Effect of element types on the glass forming ability of Al-TM-RE ternary metallic glasses using electron structure guiding [J]. J. Alloys Compd., 2017, 723: 123
82	Shen Y, Perepezko J H. Al-based amorphous alloys: Glass-forming ability, crystallization behavior and effects of minor alloying additions [J]. J. Alloys Compd., 2017, 707: 3
83	Wu R I, Wilde G, Perepezko J H. Glass formation and primary nanocrystallization in Al-base metallic glasses [J]. Mater. Sci. Eng., 2001, A301: 12
84	Zhang Z. Glass forming ability and crystallization behavior of Al-Ni-Re metallic glasses [D]. Shanghai: Shanghai Jiao Tong University, 2013
	张章. Al-Ni-RE非晶合金的非晶形成能力与晶化行为 [D]. 上海: 上海交通大学, 2013
85	Li F, Liu X J, Hou H Y, et al. Structural origin underlying poor glass forming ability of Al metallic glass [J]. J. Appl. Phys., 2011, 110: 013519
86	Ashkenazy Y, Averback R S. Kinetic stages in the crystallization of deeply undercooled body-centered-cubic and face-centered-cubic metals [J]. Acta Mater., 2010, 58: 524
87	Yan Z Z, Sheng H, Ma E, et al. Intermediate structural evolution preceding growing BCC crystal interface in deeply undercooled monatomic metallic liquids [J]. Acta Mater., 2021, 202: 387
88	Louzguine-Luzgin D V, Miracle D B, Inoue A. Intrinsic and extrinsic factors influencing the glass-forming ability of alloys [J]. Adv. Eng. Mater., 2008, 10: 1008
89	Huang Z H. Formation and crystallization behaviors of Al-TM-RE based amorphous alloys [D]. Shanghai: Shanghai Jiao Tong University, 2008
	黄正华. Al-TM-RE系非晶合金形成及其晶化行为的研究 [D]. 上海: 上海交通大学, 2008
90	Sanders W S, Warner J S, Miracle D B. Stability of Al-rich glasses in the Al-La-Ni system [J]. Intermetallics, 2006, 14: 348
91	Zhang Z, Xiong X Z, Yi J J, et al. Effects of substitution of La by other rare-earth elements on the glass forming ability of Al₈₆Ni₉La₅ alloy [J]. J. Non-Cryst. Solids, 2013, 369: 1
92	Wu N C, Zuo L, Wang J Q, et al. Designing aluminum-rich bulk metallic glasses via electronic-structure-guided microalloying [J]. Acta Mater., 2016, 108: 143
93	Yang B J, Lu W Y, Zhang J L, et al. Melt fluxing to elevate the forming ability of Al-based bulk metallic glasses [J]. Sci. Rep., 2017, 7: 11053
94	Liu Y, Wang J, Qin J Y, et al. Influence of Ag substitution on the local structure and glass-forming ability of Al₈₆Ni_{(8 -} _x₎Y₆Ag _x (x = 0, 1, 2) liquids [J]. Phys. Chem. Liq., 2016, 54: 98
95	Audebert F, Galano M, Saporiti F. The use of Nb in rapid solidified Al alloys and composites [J]. J. Alloys Compd., 2014, 615 (): S621
96	Jun J H, Kim J M, Kim K T, et al. Glass formability and thermal stability of Al-Ni-Y-Be amorphous alloys [J]. J. Alloys Compd., 2007, 434-435: 190
97	Chen S F, Chen J K, Lin S L, et al. Effects of B upon glass forming ability of Al₈₇Y₈Ni₅ amorphous alloy [J]. J. Alloys Compd., 2013, 565: 29
98	Wang J Q, Liu Y H, Imhoff S, et al. Enhance the thermal stability and glass forming ability of Al-based metallic glass by Ca minor-alloying [J]. Intermetallics, 2012, 29: 35
99	Sha P F, Qi Z, Zhang Z H. Effect of Ag or Pd additions on the microstructure, crystallization and thermal stability of Al-Ni-Ce amorphous alloys [J]. Intermetallics, 2010, 18: 1699
100	Yi J J, Xiong X Z, Inoue A, et al. Glass forming ability of Al-Ni-La alloys with Si addition [J]. J. Alloys Compd., 2015, 650: 578
101	Zhong Z C, Jiang X Y, Greer A L. Micro structure and hardening of Al-based nanophase composites [J]. Mater. Sci. Eng., 1997, A226-228: 531
102	Holland-Moritz D. Short-range order and solid-liquid interfaces in undercooled metallic melts [J]. Mater. Sci. Eng., 2001, A304-306: 108
103	Güntherodt H J, Beck H. Glassy Metals I: Ionic Structure, Electronic Transport, and Crystallization [M]. New York: Springer-Verlag, 1981: 1
104	Allen D R, Foley J C, Perepezko J H. Nanocrystal development during primary crystallization of amorphous alloys [J]. Acta Mater., 1998, 46: 431
105	Blank-Bewersdorff M. Crystallization behaviour of Al₈₆Ni₁₀Zr₄ and Al₈₆Fe₁₀Zr₄ metallic glasses [J]. J. Mater. Sci. Lett., 1991, 10: 1225
106	Nakazato K, Kawamura Y, Tsai A P, et al. On the growth of nanocrystalline grains in an aluminum-based amorphous alloy [J]. Appl. Phys. Lett., 1993, 63: 2644
107	Inoue A, Nakazato K, Kawamura Y, et al. Effect of Cu or Ag on the formation of coexistent nanoscale Al particles in Al-Ni-M-Ce (M = Cu or Ag) amorphous alloys [J]. Mater. Trans., JIM, 1994, 35: 95
108	Foley J C, Allen D R, Perepezko J H. Analysis of nanocrystal development in Al-Y-Fe and Al-Sm glasses [J]. Scr. Mater., 1996, 35: 655
109	Tsai A P, Kamiyama T, Kawamura Y, et al. Formation and precipitation mechanism of nanoscale Al particles in Al-Ni base amorphous alloys [J]. Acta Mater., 1997, 45: 1477
110	Wilde G, Sieber H, Perepezko J H. Glass formation versus nanocrystallization in an Al₉₂Sm₈ alloy [J]. Scr. Mater., 1999, 40: 779
111	Perepezko J H, Hebert R J, Tong W S. Amorphization and nanostructure synthesis in Al alloys [J]. Intermetallics, 2002, 10: 1079
112	Perepezko J H, Hebert R J, Tong W S, et al. Nanocrystallization reactions in amorphous aluminum alloys [J]. Mater. Trans., 2003, 44: 1982
113	Perepezko J H, Hebert R J, Wu R I, et al. Primary crystallization in amorphous Al-based alloys [J]. J. Non-Cryst. Solids, 2003, 317: 52
114	Perepezko J H. Nucleation-controlled reactions and metastable structures [J]. Prog. Mater. Sci., 2004, 49: 263
115	Stratton W G, Hamann J, Perepezko J H, et al. Aluminum nanoscale order in amorphous Al₉₂Sm₈ measured by fluctuation electron microscopy [J]. Appl. Phys. Lett., 2005, 86: 141910
116	Lay M D H, Hill A J, Saksida P G, et al. ²⁷Al NMR measurement of fcc Al configurations in as-quenched Al₈₅Ni₁₁Y₄ metallic glass and crystallization kinetics of Al nanocrystals [J]. Acta Mater., 2012, 60: 79
117	Spowart J E, Miracle D B, Mullens H M. The influence of solute distribution on the high nucleation density of Al crystals in amorphous aluminum alloys [J]. J. Non-Cryst. Solids, 2004, 336: 202
118	Gangopadhyay A K, Croat T K, Kelton K F. The effect of phase separation on subsequent crystallization in Al₈₈Gd₆La₂Ni₄ [J]. Acta Mater., 2000, 48: 4035
119	Antonowicz J, Yavari A R, Vaughan G. Nanocrystallization of Al₉₂Sm₈ amorphous alloy studied in situ by real-time X-ray diffraction [J]. Nanotechnology, 2004, 15: 1038
120	Antonowicz J. Phase separation and nanocrystal formation in Al-based metallic glasses [J]. J. Alloys Compd., 2007, 434-435: 126
121	Antonowicz J. Atomic packing and phase separation in Al-rare earth metallic glasses [J]. J. Mater. Sci., 2010, 45: 5040
122	Antonowicz J, Jezierska E, Kêdzierski M, et al. Early stages of phase separation and nanocrystallization in Al-rare earth metallic glasses studied using SAXS/WAXS and HRTEM methods [J]. Rev. Adv. Mater. Sci., 2008, 18: 454
123	Antonowicz J, Yavari A R, Botta W J, et al. Phase separation and nanocrystallization in Al₉₂Sm₈ metallic glass [J]. Philos. Mag., 2006, 86: 4235
124	Antonowicz J, Kędzierski M, Jezierska E, et al. Small-angle X-ray scattering from phase-separating amorphous metallic alloys undergoing nanocrystallization [J]. J. Alloys Compd., 2009, 483: 116
125	Wang Y B, Yang H W, Sun B B, et al. Evidence of phase separation correlated with nanocrystallization in Al₈₅Ni₅Y₆Fe₂Co₂ metallic glass [J]. Scr. Mater., 2006, 55: 469
126	Radiguet B, Blavette D, Wanderka N, et al. Segregation-controlled nanocrystallization in an Al-Ni-La metallic glass [J]. Appl. Phys. Lett., 2008, 92: 103126
127	Sahu K K, Mauro N A, Longstreth-Spoor L, et al. Phase separation mediated devitrification of Al₈₈Y₇Fe₅ glasses [J]. Acta Mater., 2010, 58: 4199
128	Tian N, Ohnuma M, Ohkubo T, et al. Primary crystallization of an Al₈₈Gd₆Er₂Ni₄ metallic glass [J]. Mater. Trans., 2005, 46: 2880
129	Hume-Rothery W, Anderson E. Eutectic compositions and liquid immiscibility in certain binary alloys [J]. Philos. Mag., 1960, 5: 383
130	Sommer F. Association model for the description of thermodynamic functions of liquid alloys: II. Numerical treatment and results [J]. Int. J. Mater. Res., 1982, 73: 77
131	Bokeloh J, Boucharat N, Rösner H, et al. Primary crystallization in Al-rich metallic glasses at unusually low temperatures [J]. Acta Mater., 2010, 58: 3919
132	Huang Z H, Li J F, Rao Q L, et al. Effects of replacing Ni by Co on the crystallization behaviors of Al-Ni-La amorphous alloys [J]. Intermetallics, 2008, 16: 727
133	Huang Z H, Li J F, Rao Q L, et al. Thermal stability and primary phase of Al-Ni(Cu)-La amorphous alloys [J]. J. Alloys Compd., 2008, 463: 328
134	Cuevas F G, Lozano-Perez S, Aranda R M, et al. Crystallisation of amorphous Al-Y-Ni-(Cu) alloys [J]. J. Non-Cryst. Solids, 2019, 512: 15
135	Cuevas F G, Lozano-Perez S, Aranda R M, et al. Crystallisation of amorphous Al-Sm-Ni-(Cu) alloys [J]. Intermetallics, 2019, 112: 106537
136	Mansouri M, Varahram N, Simchi A. Effect of copper on the thermal stability and non-isothermal crystallization behavior of Al₈₆Ni_{10 -} _x Cu _x RE₄ (x = 0.5-2.5) amorphous alloys prepared by melt spinning [J]. J. Non-Cryst. Solids, 2019, 506: 46
137	Cuevas F G, Lozano-Perez S, Aranda R M, et al. Crystallization process and microstructural evolution of melt spun Al-RE-Ni-(Cu) ribbons [J]. Metals, 2020, 10: 443
138	Zhang Y, Warren P J, Cerezo A. Effect of Cu addition on nanocrystallisation of Al-Ni-Sm amorphous alloy [J]. Mater. Sci. Eng., 2002, A327: 109
139	Hong S J, Warren P J, Chun B S. Nanocrystallization behaviour of Al-Y-Ni with Cu additions [J]. Mater. Sci. Eng., 2001, A304-306: 362
140	Inoue A, Ohtera K, Tsai A P, et al. Aluminum-based amorphous alloys with tensile strength above 980 MPa (100 kg/mm²) [J]. Jpn. J. Appl. Phys., 1988, 27: L479
141	Chang I T H, Svec P, Gogebakan M, et al. Rapidly solidified Al₈₅Ni_{15 -} _x Y _x (x = 5, 8, 10) alloys [J]. Mater. Sci. Forum, 1996, 225-227: 335
142	Huang Z H, Li J F, Rao Q L, et al. Dependences of the crystallization behavior of Al-Ni-La amorphous alloys on La and Ni contents [J]. J. Non-Cryst. Solids, 2008, 354: 1671
143	Louzguine D V, Inoue A. Full or partial replacement of Y by rare-earth and some other elements in the Al₈₅Y₈Ni₅Co₂alloy [J]. J. Light Met., 2001, 1: 105
144	Louzguine-Luzgin D V, Inoue A. Structure and transformation behaviour of a rapidly solidified Al-Y-Ni-Co-Pd alloy [J]. J. Alloys Compd., 2005, 399: 78
145	Huang Z H, Li J F, Rao Q L, et al. Primary crystallization of Al-Ni-RE amorphous alloys with different type and content of RE [J]. Mater. Sci. Eng., 2008, A489: 380
146	Yi J J, Xu W Q, Xiong X Z, et al. Glass-forming ability and crystallization behavior of Al₈₆Ni₉La₅ metallic glass with Si addition [J]. Adv. Eng. Mater., 2016, 18: 972
147	Yi J J, Kong L T, Ferry M, et al. Origin of the separated α-Al nanocrystallization with Si added to Al₈₆Ni₉La₅ amorphous alloy [J]. Mater. Charact., 2021, 178: 111199
148	Li W, Yang L, Zhang Y G, et al. Influences of Si addition on the thermal stability and crystallization behavior of Al-Y binary amorphous alloys [J]. J. Alloys Compd., 2021, 873: 159816
149	Li W, Kong L T, Li J F. The alloying effects of Ge and Si on thermal stability and crystallization behavior of Al-Y binary amorphous alloys [J]. J. Non-Cryst. Solids, 2022, 575: 121197
150	Guan P F, Sun S J. Atomic-level study in the structure and its instability of metallic glasses [J]. Acta Metall. Sin., 2021, 57: 501
	管鹏飞, 孙胜君. 金属玻璃结构及其失稳的原子层次研究 [J]. 金属学报, 2021, 57: 501

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