Effects of Direct Current on Microstructure and Properties of Ti-48Al-2Cr-2Nb Alloy
Zhanxing CHEN,Hongsheng DING,Shiqiu LIU,Ruirun CHEN,Jingjie GUO,Hengzhi FU
National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Cite this article:
Zhanxing CHEN,Hongsheng DING,Shiqiu LIU,Ruirun CHEN,Jingjie GUO,Hengzhi FU. Effects of Direct Current on Microstructure and Properties of Ti-48Al-2Cr-2Nb Alloy. Acta Metall Sin, 2017, 53(5): 583-591.
TiAl based alloys have been widely used as promising aerospace structural materials, which benefit from their unique combination of mechanical properties. However, they yield poor plasticity and low process ability, thus restricting the wide application. In this work, an efficient way was proposed by which direct current (DC) was imposed on the solidification process of TiAl-based alloy. Influences of DC on the microstructure and properties of directionally solidified Ti-48Al-2Cr-2Nb alloy using water cold crucible directional solidification equipment has been investigated. The changes of solidification microstructure, phase structure and composition of the alloy and γ/α2 interlamellar structures were characterized by OM, XRD, SEM and TEM. The effect of DC on the size of eutectoid colony, interlamellar spacing and relative content of α2 phase had been studied by Image Pro Plus. Furthermore, the mechanical properties of the directionally solidified Ti-48Al-2Cr-2Nb alloy at 800 ℃ were performed. The results revealed that the DC can evidently promote the homogeneity of the solidification component and refiner the structure, and the segregation in lamellar colonies can be efficiently reduced or eliminated to a certain extent. With the increasing of the current density, the grain size and lamellar spacing decreased first and then increased, however, the α2 phase content showed a totally different trend. Moreover, the microhardness, compression yield strength and the fracture strength of the alloy also revealed a trend of decrease after the first increase too. With the current density increasing, the average grain size and interlamellar spacing declined to the lowest of 0.46 mm and 0.19 μm, respectively, and the content of α2 phase increased from 18.5% to 39.4%. The microhardness of sample reached 542 HV, the compression yield strength and the fracture strength were remarkably improved, and the maximum values reached 1200 and 1365 MPa, respectively. DC can cause a reduction of the supercooling in front of the liquid phase during the solidification process. The results can be seen as the peritectic reaction L→β+L→α+β moving a tiny drift to the direction of the Al-rich side in TiAl binary phase diagram, consequently, the primary β-phase increased, and the content of α2 phase, microstructure under room temperature, increased evidently.
Fig.1 Macrostructures of directionally solidified Ti-48Al-2Cr-2Nb alloy without direct current (DC) (a) and with the DC densities of 32 mA/mm2 (b), 64 mA/mm2 (c) and 96 mA/mm2 (d) (Zone A—original as-cast zone, zone B—heat affected zone, zone C—transition zone, zone D—columnar crystal zone, zone E—equiaxed crystal zone)
Fig.2 OM images of microstructures of Ti-48Al-2Cr-2Nb alloys solidified without DC (a) and with the DC densities of 32 mA/mm2 (b), 64 mA/mm2 (c) and 96 mA/mm2 (d)
Fig.3 SEM images of microstructures of Ti-48Al-2Cr-2Nb alloy solidified without DC (a) and with the DC densities of 32 mA/mm2 (b), 64 mA/mm2 (c) and 96 mA/mm2 (d)
Fig.4 XRD spectra of Ti-48Al-2Cr-2Nb alloy solidified with and without DC
Fig.5 TEM images of lamella structures of Ti-48Al-2Cr-2Nb alloy solidified without DC (a) and with the DC densities of 32 mA/mm2 (b), 64 mA/mm2 (c) and 96 mA/mm2 (d)
Fig.6 Volume fraction of α2 phase in Ti-48Al-2Cr-2Nb alloy solidified with and without DC
Fig.7 Grain size and lamella width of Ti-48Al-2Cr-2Nb alloy with and without DC
Fig.8 Microhardness in various zones of directionally solidified Ti-48Al-2Cr-2Nb alloy with and without DC current
Fig.9 True stress-true strain curves of Ti-48Al-2Cr-2Nb alloy solidified with and without DC
Fig.10 Schematic of equivalent binary phase diagram of TiAl system with direct current
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