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金属学报  2026, Vol. 62 Issue (6): 1091-1104    DOI: 10.11900/0412.1961.2025.00368
  研究论文 本期目录 | 过刊浏览 |
直接退火与冷轧+退火处理Cu-Ni-Si/1010钢双金属复合材料的组织演变及强化机制
王明飞1, 陶美悦1, 宫臣1, 彭博1, 李廷举1,2, 接金川1,2()
1 大连理工大学 材料科学与工程学院 大连 116024
2 大连理工大学 宁波研究院 宁波 315000
Microstructural Evolution and Strengthening Mechanisms of Cu-Ni-Si/1010 Steel Bimetallic Composites via Direct Annealing and Cold Rolling + Annealing
WANG Mingfei1, TAO Meiyue1, GONG Chen1, PENG Bo1, LI Tingju1,2, JIE Jinchuan1,2()
1 School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
2 Ningbo Research Institute of Dalian University of Technology, Ningbo 315000, China
引用本文:

王明飞, 陶美悦, 宫臣, 彭博, 李廷举, 接金川. 直接退火与冷轧+退火处理Cu-Ni-Si/1010钢双金属复合材料的组织演变及强化机制[J]. 金属学报, 2026, 62(6): 1091-1104.
Mingfei WANG, Meiyue TAO, Chen GONG, Bo PENG, Tingju LI, Jinchuan JIE. Microstructural Evolution and Strengthening Mechanisms of Cu-Ni-Si/1010 Steel Bimetallic Composites via Direct Annealing and Cold Rolling + Annealing[J]. Acta Metall Sin, 2026, 62(6): 1091-1104.

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摘要: 

针对铸态Cu-Ni-Si/1010钢双金属复合材料微观组织粗大及力学性能不足的问题,本工作旨在通过后处理工艺实现其组织调控和性能优化。本工作对比研究了直接退火与冷轧+退火复合工艺对铸态Cu-Ni-Si/1010钢双金属复合材料显微组织和力学行为的影响。结果表明,铸态Cu-Ni-Si合金微观组织呈现粗大柱状晶和少量β-Ni3Si相,直接退火诱导α-Cu基体析出纳米级δ-Ni2Si强化相;冷轧+退火工艺通过引入高密度位错并抑制部分晶粒再结晶,使组织呈现细化的纤维状特征。力学测试结果表明,冷轧+退火样品的抗拉强度由铸态的379 MPa显著提高至613 MPa,这归因于析出强化、加工硬化及异质变形诱导强化的协同效应。此外,得益于1010钢的回复作用,冷轧+退火样品在保持高强度的同时,延伸率仍达18.4%。

关键词 双金属复合材料组织调控析出强化加工硬化异质变形诱导强化    
Abstract

High-performance materials are in strong demand in the electronics and automotive industries. Cu-Ni-Si alloys are widely used owing to their excellent combination of strength and electrical conductivity, whereas 1010 steel provides superior formability, high elastic modulus, and cost-effectiveness. Integrating these materials into laminated bimetallic composites represents a promising strategy for achieving structural-functional integration, thereby overcoming the trade-offs inherent in single-component metals. However, fabrication of such composites remains challenging, primarily due to poor wettability and limited mutual solubility between Cu and Fe, which often result in weak interfacial bonding and coarse as-cast microstructures. Therefore, the development of effective fabrication methods and appropriate post-processing routes to tailor microstructure and optimize mechanical properties is essential for industrial application. In this study, Cu-Ni-Si/1010 steel laminated bimetallic composite was successfully fabricated via continuous solid-liquid bonding method. To investigate the effects of annealing and cold rolling followed by annealing on microstructural evolution and mechanical behavior, the composites were subjected to four conditions: as-cast (sample S1), direct annealing at 450 °C (sample S2), 70% cold rolling followed by annealing at 450 °C (sample S3), and 70% cold rolling (sample S4). Microstructural and mechanical characterization was performed using OM, SEM, TEM, and tensile testing to elucidate the relationships among processing parameters, interfacial characteristics, and strengthening mechanisms. The Cu-Ni-Si layer in sample S1 exhibits coarse columnar grains, with a minor β-Ni3Si phase located at α-Cu grain boundaries. Direct annealing promotes the formation of nanoscale δ-Ni2Si precipitates within the α-Cu matrix, contributing to strengthening. In contrast, the combined cold rolling and annealing treatment induces more pronounced microstructural evolution: severe plastic deformation increases dislocation density and refines the grain structure into the fibrous morphology due to incomplete recrystallization. No brittle intermetallic compounds are observed at the interface under any condition. Samples S3 and S4 exhibit wavy, well-bonded interfaces, indicating enhanced interfacial diffusion and metallurgical bonding. Tensile testing shows that sample S3 achieves the highest ultimate tensile strength (613 MPa), significantly exceeding those of sample S1 (379 MPa) and sample S2 (415 MPa), which is attributed to the synergistic effects of work hardening, precipitation strengthening, and hetero-deformation induced strengthening. Although ductility decreases slightly in sample S3, the elongation remains relatively high at 18.4%, whereas sample S4 exhibits the lowest elongation (12.6%), which is detrimental to subsequent forming. Importantly, all samples fracture within the matrix without interfacial delamination, confirming robust metallurgical bonding. These results indicate that direct annealing enhances both strength and ductility in Cu-Ni-Si/1010 steel laminated bimetallic composites, while cold rolling followed by annealing is an effective strategy for substantially increasing strength while preserving interfacial integrity.

Key wordsbimetallic composites    microstructure control    precipitation strengthening    work hardening    hetero-deformation induced strengthening
收稿日期: 2025-11-14     
ZTFLH:  TG14  
基金资助:国家自然科学基金项目(U23A20611);国家自然科学基金项目(52071050);宁波市科技创新项目(2024Z077);宁波市科技创新项目(2023Z100);中国博士后科学基金项目(2024M750312);中国博士后科学基金项目(GZB20240091);辽宁省博士后科研基金项目(2025-BS-0043)
通讯作者: 接金川,jiejc@dlut.edu.cn,主要从事物理场作用下铜合金凝固组织控制及高品质金属基复合材料制备研究
Corresponding author: JIE Jinchuan, professor, Tel: 15941130325, E-mail: jiejc@dlut.edu.cn
作者简介: 王明飞,男,1995年生,博士生
MaterialCSiMnCrNiCuFe
Cu-Ni-Si-0.50--2.10Bal.-
1010 steel0.090.360.400.10--Bal.
表1  Cu-Ni-Si合金和1010钢的主要化学成分 (mass fraction / %)
图1  固-液复合法制备Cu-Ni-Si/1010钢双金属层状复合材料、不同后处理工艺及力学性能测试所用试样尺寸的示意图
图2  S1~S4样品Cu-Ni-Si侧、界面区域及1010钢侧微观组织的OM像
图3  S1~S4样品界面处的EPMA线扫描结果
图4  S1~S4样品界面附近Cu-Ni-Si合金侧和1010钢侧的反极图及对应的晶粒尺寸分布图
图5  S1~S4样品中Cu-Ni-Si合金的XRD谱
图6  S1~S3样品中Cu-Ni-Si基体和析出相的TEM表征
图7  S1~S4样品从Cu-Ni-Si侧到1010钢侧的硬度分布曲线和平均硬度
图8  S1~S4样品的拉伸性能
图9  S1~S4样品断口表面形貌的SEM像
图10  Cu-Ni-xSi伪二元相图、Cu-Ni-Si相转变曲线、Cu-Ni-Si 450 ℃等温相图及Fe-C二元相图
图11  S1~S4样品Cu-Ni-Si合金侧和1010钢侧的局部取向差(KAM)图及对应的几何必需位错密度分布统计图
图12  S1~S3样品的真应力-应变曲线和异质变形诱导(HDI)应力随应变的演变
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