共晶高熵合金十年发展回顾<strong>(2014</strong>—<strong>2024)</strong>：设计、制备与应用

doi:10.11900/0412.1961.2024.00250

金属学报

2025, Vol. 61

Issue (1): 1-11 DOI: 10.11900/0412.1961.2024.00250

综述

本期目录 | 过刊浏览

共晶高熵合金十年发展回顾(2014—2024)：设计、制备与应用

王志军¹(

), 白晓昱¹, 王健斌¹, 姜慧², 焦文娜³, 李天昕⁴, 卢一平³^,⁵(

)

1 西北工业大学凝固技术国家重点实验室西安 710072
2 山东科技大学机械电子工程学院青岛 266590
3 大连理工大学材料科学与工程学院大连 116024
4 贵州大学材料与冶金学院贵阳 550025
5 大连理工大学辽宁省高熵合金材料工程研究中心大连 116024

Revisiting the Development of Eutectic High-Entropy Alloys over the Past Decade (2014-2024): Design, Manufacturing, and Applications

WANG Zhijun¹(

), BAI Xiaoyu¹, WANG Jianbin¹, JIANG Hui², JIAO Wenna³, LI Tianxin⁴, LU Yiping³^,⁵(

)

1 State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072, China
2 School of Mechanical and Electronic Engineering, Shandong University of Science and Technology, Qingdao 266590, China
3 School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
4 College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China
5 Liaoning Engineering Research Center of High-Entropy Alloy Materials, Dalian University of Technology, Dalian 116024, China

引用本文:

王志军, 白晓昱, 王健斌, 姜慧, 焦文娜, 李天昕, 卢一平. 共晶高熵合金十年发展回顾(2014—2024)：设计、制备与应用[J]. 金属学报, 2025, 61(1): 1-11.
Zhijun WANG, Xiaoyu BAI, Jianbin WANG, Hui JIANG, Wenna JIAO, Tianxin LI, Yiping LU. Revisiting the Development of Eutectic High-Entropy Alloys over the Past Decade (2014-2024): Design, Manufacturing, and Applications[J]. Acta Metall Sin, 2025, 61(1): 1-11.

全文: PDF(3081 KB) HTML

摘要:

共晶合金是以凝固过程发生共晶反应命名的一类多相合金，具有悠久的历史，是应用最广的铸造合金。高熵合金是多主元的新型合金，自2004年提出以来取得了迅速发展。共晶高熵合金结合了共晶合金和高熵合金的优点，于2014年首次公开报道。经历十年发展，共晶高熵合金已经快速经历了成分设计、组织/性能调控、大规模制备与应用几个阶段。共晶高熵合金独特的微观组织特征和优异的综合性能使其在多个领域展现出广阔的应用前景，成为近年来备受关注的新型合金材料。本文对过去十年共晶高熵合金的成分设计、制备和应用进展进行了回顾，并对未来发展趋势进行了展望。

关键词 ：共晶高熵合金, 成分设计, 组织调控, 材料制备, 应用

Abstract：

Eutectic alloys are a class of multi-phase materials named for their formation through eutectic reactions during solidification. They have a long history as the most widely used casting alloys. High-entropy alloys (HEAs), on the other hand, are a novel class of multi-principal element alloys that have rapidly developed since their conceptualization in 2004. Combining the advantages of eutectic alloys and HEAs, eutectic high-entropy alloys (EHEAs) were first proposed in 2014. Over a decade, EHEAs have been systematically investigated by focusing on alloy design, microstructure/performance optimization, large-scale fabrication, and potential applications. Their unique microstructures and excellent comprehensive properties have made EHEAs promising materials across various domains, garnering significant attention in recent years. By revisiting the advances in composition design, manufacturing, and applications of EHEAs over the past decade, this review offered insights into future trends and developments in this rapidly evolving field.

Key words： eutectic high-entropy alloy composition design microstructure control material manufacturing application

收稿日期: 2024-07-23

ZTFLH:

TG139

通讯作者: 王志军，zhjwang@nwpu.edu.cn，主要从事高熵合金设计与强韧化的研究;
卢一平，luyiping@dlut.edu.cn，主要从事高熵合金的成分设计理论以及制备技术的研究

Corresponding author: WANG Zhijun, professor, Tel: 13484671484, E-mail: zhjwang@nwpu.edu.cn;
LU Yiping, professor, Tel: (0411)84709400, E-mail: luyiping@dlut.edu.cn

作者简介: 王志军，男，1984年生，教授

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https://www.ams.org.cn/CN/10.11900/0412.1961.2024.00250 或 https://www.ams.org.cn/CN/Y2025/V61/I1/1

图1 共晶高熵合金的成分设计方法[22,23,25,26]

图2 机器学习辅助的共晶高熵合金成分设计方法[27]

图3 典型共晶高熵合金凝固组织[34,38,39]

图4 多种工艺调控下的共晶高熵合金微观组织[48,50~54]

图5 具有不同微观组织的共晶高熵合金的力学性能[48,50~54]

图6 共晶高熵合金工业化制备示例

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