第二取向对第三代单晶高温合金热疲劳过程中冷却孔孔周氧化行为的影响研究

doi:10.11900/0412.1961.2019.00109

金属学报

2019, Vol. 55

Issue (11): 1417-1426 DOI: 10.11900/0412.1961.2019.00109

研究论文

本期目录 | 过刊浏览

第二取向对第三代单晶高温合金热疲劳过程中冷却孔孔周氧化行为的影响研究

王莉¹(

),何禹锋^1,²,申健¹,郑伟¹,楼琅洪¹,张健¹

1. 中国科学院金属研究所沈阳 110016
2. 中国科技大学材料科学与工程学院沈阳 110016

Effect of Secondary Orientation on Oxidation Anisotropy Around the Holes of Single Crystal Superalloy During Thermal Fatigue Tests

WANG Li¹(

),HE Yufeng^1,²,SHEN Jian¹,ZHENG Wei¹,LOU Langhong¹,ZHANG Jian¹

1. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
2. School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China

引用本文:

王莉,何禹锋,申健,郑伟,楼琅洪,张健. 第二取向对第三代单晶高温合金热疲劳过程中冷却孔孔周氧化行为的影响研究[J]. 金属学报, 2019, 55(11): 1417-1426.
Li WANG, Yufeng HE, Jian SHEN, Wei ZHENG, Langhong LOU, Jian ZHANG. Effect of Secondary Orientation on Oxidation Anisotropy Around the Holes of Single Crystal Superalloy During Thermal Fatigue Tests[J]. Acta Metall Sin, 2019, 55(11): 1417-1426.

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摘要:

选用第三代镍基单晶高温合金DD33，采用OM、SEM、EDS等分析手段，研究了室温~1100 ℃的热疲劳过程中不同第二取向板式试样圆孔孔周的氧化各向异性行为。结果表明，不同第二取向的第三代单晶高温合金含孔样品经560 cyc热疲劳实验后，冷却孔周围仍未产生裂纹，但其孔周氧化存在明显各向异性特征。并且，相同第二取向试样，孔周不同取向位置氧化层厚度差异明显；不同第二取向试样，孔周不同位置氧化层的厚度分布也不同。造成此差异的本质原因是由于第二取向不同引起样品宏观热应力的差别，导致孔的形状变化趋势与孔周不同位置热应力的差别，与孔周不同位置微观组织差异共同作用的结果。

关键词 ：单晶高温合金, 第二取向, 热疲劳, 氧化, 各向异性

Abstract：

With the increase of inlet temperatures of the aeroengines, high generation single crystal superalloys were used widely, and more and more complicated structures were employed. Thermal fatigue cracks around the cooling holes were reported to be one of the most important failure mechanisms. In this work, the thermal fatigue behaviors of a third generation single crystal superalloy with different secondary orientations were studied and the effect of secondary orientation on oxidation behaviors around the cooling holes during thermal fatigue tests of samples was investigated by OM, SEM and EDS. The results showed that no cracks was found around the holes even after 560 cyc thermal fatigue tests for both (100) and (110) specimens. But the oxidation behaviors around the holes were different for samples with different secondary orientations, and oxidation layers with different thicknesses were observed around each hole. After 1 cyc thermal fatigue test, the average thickness of oxidation layer around the (110) specimens was almost the same as that of the (100) specimens. After 20 cyc thermal fatigue test, thicker oxidation layers were detected in (110) specimens than that in (100) specimens. Larger difference was observed with the ongoing of the thermal fatigue tests. After 560 cyc, the average oxidation thickness is round 137 μm for (110) specimens, while it is only 88 μm for (100) specimens. Furthermore, the oxidation layer shows different thickness at the different positions of a hole. For (100) specimens, the thickness of oxidation layer decreases in the sequences of [010], [011] and [001] direction, while for (110) specimens it decreases in the sequences of [110], [112] and [001] direction. It was discussed based on the combined effect of thermal stress anisotropy of the sample and local thermal stress anisotropy around the holes, which were caused by crystal anisotropy of single crystals, and the different microstructures around the holes.

Key words： single crystal superalloy secondary orientation thermal fatigue oxidation anisotropy

收稿日期: 2019-04-10

ZTFLH:

TG146.1

基金资助:国家自然科学基金项目Nos(51671196);国家自然科学基金项目Nos(51871210);国家自然科学基金项目Nos(51631008);国家自然科学基金项目Nos(91860201)

作者简介: 王莉，女，1977年生，研究员，博士

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https://www.ams.org.cn/CN/10.11900/0412.1961.2019.00109 或 https://www.ams.org.cn/CN/Y2019/V55/I11/1417

图1 不同第二取向热疲劳样品示意图

图2 热疲劳实验前不同第二取向样品横截面组织

图3 (100)样品电火花打孔后孔周显微组织形貌

图4 不同第二取向样品热疲劳实验过程中圆孔周围组织演变

图5 热疲劳实验220 cyc后(110)样品孔周典型氧化层组织

图6 560 cyc热疲劳实验后(100)样品孔周形貌及氧化层成分分析

图7 不同第二取向样品热疲劳循环过程中氧化绝对深度及氧化层厚度变化曲线

图8 不同第二取向样品冷热循环不同周次后孔周不同位置氧化示意图

[1]	HeG, LiJ G, MaoX M, et al. Development of materials and processes for turbine blades [J]. Mater. Rev., 1994, (1): 12
[1]	何国, 李建国, 毛协民等. 涡轮叶片材料及制造工艺的研究进展 [J]. 材料导报, 1994, (1): 12
[2]	MaD X. Development of single crystal solidification technology for production of superalloy turbine blades [J]. Acta Metall. Sin., 2015, 51: 1179
[2]	马德新. 高温合金叶片单晶凝固技术的新发展 [J]. 金属学报, 2015, 51: 1179
[3]	ZhangJ, LouL H. Basic research in development and application of cast superalloy [J]. Acta Metall. Sin., 2018, 54: 1637
[3]	张健, 楼琅洪. 铸造高温合金研发中的应用基础研究 [J]. 金属学报, 2018, 54: 1637
[4]	OnyszkoA, KubiakK, SieniawskiJ. Turbine blades of the single crystal nickel based CMSX-6 superalloy [J]. J. Achiev. Mater. Manuf. Eng., 2009, 32: 66
[5]	ReedR C, TaoT, WarnkenN. Alloys-by-design: Application to nickel-based single crystal superalloys [J]. Acta Mater., 2009, 57: 5898
[6]	McNallyC A, FolkesJ, PashbyI R. Laser drilling of cooling holes in aeroengines: State of the art and future challenges [J]. Mater. Sci. Technol., 2004, 20: 805
[7]	HouN X, WenZ X, DuZ X, et al. Crystallographic failure analysis of film near cooling hole under temperature gradient of nickel-based single crystal superalloys [J]. Theor. Appl. Fract. Mech., 2007, 47: 164
[8]	SunE, HeffernanT, HelminkR. Stress rupture and fatigue in thin wall single crystal superalloys with cooling holes [A]. Superalloys 2012 [C]. Hoboken, NJ: Wiley, 2012: 353
[9]	LiL, AoL B, XieG N, et al. Influences of holes arrangement on creep characteristic of nickel-base single crystal alloy blade cooling holes [J]. Adv. Mater. Sci. Eng., 2013, 2013: 930156
[10]	WangJ L, ChenM H, YangL L, et al. Comparative study of oxidation and interdiffusion behavior of AIP NiCrAlY and sputtered nanocrystalline coatings on a nickel-based single-crystal superalloy [J]. Corros. Sci., 2015, 98: 530
[11]	AlamnM Z, SatyanarayanaD V V, ChatterjeeD, et al. Creep behavior of Pt-aluminide (PtAl) coated directionally solidified Ni-based superalloy CM-247LC after thermal exposure [J]. Mater. Sci. Eng., 2015, A641: 84
[12]	Segers?llM, LeidermarkD, MoverareJ J. Influence of crystal orientation on the thermomechanical fatigue behaviour in a single-crystal superalloy [J]. Mater. Sci. Eng., 2015, A623: 68
[13]	YueZ F, YinZ Y, YangZ G. Effect of crystal orientation on the structural strength and the creep rupture life of single crystal blades in aeroengines [J]. Aeroengine, 1997, (4): 32
[13]	岳珠峰, 尹泽勇, 杨治国. 晶体取向对航空发动机单晶叶片结构强度和蠕变寿命的影响 [J]. 航空发动机, 1997, (4): 32
[14]	SabnisP A, MazièreM, ForestS, et al. Effect of secondary orientation on notch-tip plasticity in superalloy single crystals [J]. Int. J. Plast., 2012, 28: 102
[15]	JinZ X. Influence of specimen notch shape on thermal fatigue properties and crack morphology [J]. Central Iron Steel Res. Inst. Tech. Bull., 1985, 5: 205
[15]	金哲学. 试样缺口形状对冷热疲劳性能与裂纹形貌影响的研究 [J]. 钢铁研究总院学报, 1985, 5: 205
[16]	RatnaV, SarmaD S. Influence of thermal fatigue on the microstructure of a Ni-base superalloy [J]. Scr. Metall. Mater., 1993, 29: 467
[17]	LiY L, YuanC, GuoJ T. Thermal fatigue behavior of cast nickel base superalloy K445 [J]. Acta Metall. Sin., 2006, 42: 1056
[17]	李友林, 袁超, 郭建亭. 铸造镍基高温合金K445的热疲劳行为 [J]. 金属学报, 2006, 42: 1056
[18]	ObrtlíkK, PetrenecM, ManJ, et al. Isothermal fatigue behavior of cast superalloy Inconel 792-5A at 23 and 900 ℃ [J]. J. Mater. Sci., 2009, 44: 3305
[19]	XiaoX, XuH, QinX Z, et al. Thermal fatigue behaviors of three cast nickel base superalloys [J]. Acta Metall. Sin., 2011, 47: 1129
[19]	肖璇, 许辉, 秦学智等. 3种铸造镍基高温合金热疲劳行为研究 [J]. 金属学报, 2011, 47: 1129
[20]	JiangW H, YaoX D, GuanH R, et al. Studies of high-temperature notch fatigue property and fracture of a directional solidified Co-base superalloy [J]. Rare Met. Mater. Eng., 1998, 27: 340
[20]	姜文辉, 姚向东, 管恒荣等. 定向凝固钴基合金DZ40M高温缺口疲劳性能及其断口研究 [J]. 稀有金属材料与工程, 1998, 27: 340
[21]	XiaP C, YuJ J, SunX F, et al. Thermal fatigue property of DZ951 alloy [J]. Rare Met. Mater. Eng., 2008, 37: 50
[21]	夏鹏成, 于金江, 孙晓峰等. DZ951合金的热疲劳性能 [J]. 稀有金属材料与工程, 2008, 37: 50
[22]	XiaP C, YuJ J, SunX F, et al. Influence of holding time and notched radius on thermal fatigue property of DZ951 alloy [J]. Trans. Mater. Heat Treat., 2010, 31(2): 40
[22]	夏鹏成, 于金江, 孙晓峰等. 保温时间和缺口半径对DZ951合金热疲劳性能的影响 [J]. 材料热处理学报, 2010, 31(2): 40
[23]	TotemeierT C, KingJ E. Isothermal fatigue of an aluminide-coated single-crystal superalloy: Part I [J]. Metall. Mater. Trans., 1996, 27A: 353
[24]	LiuY, YuJ J, XuY, et al. Thermal fatigue behavior of single-crystal superalloy [J]. Rare Met. Mater. Eng., 2009, 38: 59
[24]	刘源, 于金江, 徐岩等. 单晶高温合金的冷热疲劳裂纹生长行为研究 [J]. 稀有金属材料与工程, 2009, 38: 59
[25]	Meyer-OlberslebenF, GoldschmidtD, Rézai-AriaF. Investigation of the thermal fatigue behaviour of single-crystal nickel-based superalloys SRR 99 and CMSX-4 [A]. Superalloys 1992 [C]. Warrendale, PA: TMS, 1992: 785
[26]	GetsovL, DobinaN, RybnikovA. Thermal fatigue of a Ni-based superalloy single crystal [J]. Mater. Technol., 2007, 41: 67
[27]	WangL, ZhouZ J, JiangW G, et al. Effect of secondary orientation on thermal fatigue behavior of a nickel-base single crystal superalloy DD33 [J]. Chin. J. Mater. Res., 2014, 28: 663
[27]	王莉, 周忠娇, 姜卫国等. 第二取向对镍基单晶高温合金DD33热疲劳性能的影响 [J]. 材料研究学报, 2014, 28: 663
[28]	WangL, ZhouZ J, ZhangS H, et al. Crack initiation and propagation around holes of Ni-based single crystal superalloy during thermal fatigue cycle [J]. Acta Metall. Sin., 2015, 51: 1273
[28]	王莉, 周忠娇, 张少华等. 镍基单晶高温合金冷热循环过程中圆孔周围裂纹萌生与扩展行为 [J]. 金属学报, 2015, 51: 1273
[29]	KakehiK, LatiefF H, SatoT. Influence of primary and secondary orientations on creep rupture behavior of aluminized single crystal Ni-based superalloy [J]. Mater. Sci. Eng., 2014, A604: 148
[30]	ZhangY Y, QiuW H, ShiH J, et al. Effects of secondary orientations on long fatigue crack growth in a single crystal superalloy [J]. Eng. Fract. Mech., 2015, 136: 172
[31]	QiuW H, HeZ W, FanY N, et al. Effects of secondary orientation on crack closure behavior of nickel-based single crystal superalloys [J]. Int. J. Fatigue, 2016, 83: 335
[32]	ZhouZ J, WangL, WangD, et al. Effect of secondary orientation on room temperature tensile behaviors of Ni-base single crystal superalloys [J]. Mater. Sci. Eng., 2016, A659: 130
[33]	QinL, PeiY L, LiS S, et al. Influence of stress and secondary orientation on the oxidation-induced dynamic recrystallization behavior of a Ni-based single crystal superalloy [J]. J. Alloys Compd., 2017, 706: 455
[34]	SuzukiS, SakaguchiM, InoueH. Temperature dependent fatigue crack propagation in a single crystal Ni-base superalloy affected by primary and secondary orientations [J]. Mater. Sci. Eng., 2018, A724: 559
[35]	WangL, LiuX G, ZhangJ, et al. High temperature oxidation of a single crystal nickel-base superalloy [J]. J. Iron Steel Res., 2011, 23(suppl.2: 353
[35]	王莉, 刘心刚, 张健等. 第三代单晶高温合金DD33的高温氧化行为 [J]. 钢铁研究学报, 2011, 23(增刊2): 353
[36]	HuG X, CaiX, RongY H. Fundamental of Materials Science [M]. 2nd Ed., Shanghai: Shanghai Jiaotong University Press, 2006: 150
[36]	胡赓祥, 蔡珣, 戎咏华. 材料科学基础 [M]. 第2版. 上海: 上海交通大学出版社, 2006: 150
[37]	HerchlR, KhoiN N, HommaT, et al. Short-circuit diffusion in the growth of nickel oxide scales on nickel crystal faces [J]. Oxid. Met., 1972, 4: 35
[38]	YuanF H, HanE H, JoC Y, et al. The effect of crystallographic orientation on the oxidation behavior of a single-crystal nickel-base superalloy [J]. Oxid. Met., 2003, 60: 211
[39]	LatiefF H, AlrasheediN H. Anisotropic oxidation resistance in a Ni-base single crystal superalloy [J]. Int. J. Electrochem. Sci., 2015, 10: 2183

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