新型耐磨耐高温氧化<strong>NiCrAlSiC</strong>复合涂层的制备及性能研究

doi:10.11900/0412.1961.2019.00034

金属学报

2019, Vol. 55

Issue (7): 902-910 DOI: 10.11900/0412.1961.2019.00034

本期目录 | 过刊浏览

新型耐磨耐高温氧化NiCrAlSiC复合涂层的制备及性能研究

赵明雨¹,甄会娟^2,³(

),董志宏²,杨秀英¹(

),彭晓⁴

1. 沈阳工学院抚顺 113122
2. 中国科学院金属研究所沈阳 110016
3. 中国科学技术大学材料科学与工程学院沈阳 110016
4. 南昌航空大学材料科学与工程学院南昌 330063

Preparation and Performance of a Novel Wear-Resistant and High Temperature Oxidation-Resistant NiCrAlSiC Composite Coating

Mingyu ZHAO¹,Huijuan ZHEN^2,³(

),Zhihong DONG²,Xiuying YANG¹(

),Xiao PENG⁴

1. Shenyang Institute of Technology, Fushun 113122, China
2. Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3. School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
4. School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China

引用本文:

赵明雨,甄会娟,董志宏,杨秀英,彭晓. 新型耐磨耐高温氧化NiCrAlSiC复合涂层的制备及性能研究[J]. 金属学报, 2019, 55(7): 902-910.
Mingyu ZHAO, Huijuan ZHEN, Zhihong DONG, Xiuying YANG, Xiao PENG. Preparation and Performance of a Novel Wear-Resistant and High Temperature Oxidation-Resistant NiCrAlSiC Composite Coating[J]. Acta Metall Sin, 2019, 55(7): 902-910.

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摘要:

采用“电泳+电沉积”两步法在金属基体上先预沉积CrAlSiC电泳层，再电沉积Ni，制备了NiCrAlSiC复合涂层，并制备不含SiC的NiCrAl涂层为对比样品。采用XRD、SEM、EPMA和TEM对复合涂层进行形貌、结构和成分表征，并研究其高温氧化性能和摩擦磨损性能。结果表明：复合涂层致密并与基体结合良好，涂层内颗粒分散均匀。与不含SiC的NiCrAl复合涂层相比，NiCrAlSiC复合涂层的氧化膜由NiO、NiAl₂O₄和Al₂O₃三层结构转变为NiAl₂O₄和Al₂O₃两层结构，且氧化膜更薄；同时，涂层硬度提高26%，磨损速率下降52%，磨损机制由磨粒磨损转变为黏着磨损。SiC颗粒的加入同时提高了NiCrAl涂层的抗高温氧化性能和耐磨性能。

关键词 ： NiCrAl复合涂层, 高温氧化, 摩擦磨损, 电泳, 电沉积

Abstract：

MCrAl (M=Ni, Co, or their combinations) coatings have been widely used as high temperature oxidation protection coatings on turbine blades, as they can thermally grow stable, dense and well adherent Al₂O₃ protective scales. Due to the particulate nature of the exhaust, MCrAl coatings often fail owing to severe high-temperature wear. To improve the anti-wear resistance of the MCrAl coatings, NiCrAlSiC composite coatings were designed and fabricated by the combination of electrophoretic deposition (EPD) and electrodeposition (ED). The compositions, morphologies and structures of the as-deposited composite coatings were characterized by XRD, SEM, EPMA and TEM. A Ni7.4Cr6.2Al14.3SiC (mass fraction, %) coating, as well as a contrast SiC-free Ni7.2Cr6.2Al coating, was prepared. No cracks or micro pores were found either at the coating/substrate interface or in the coating, and elements distributed uniformly in the coating. Compared to the SiC-free coating, oxide scale on the NiCrAlSiC coating transformed from a three-layered structure (NiO, NiAl₂O₄ and Al₂O₃) to a thinner two-layered structure (NiAl₂O₄ and Al₂O₃), showing better high temperature oxidation resistance. And microhardness of the NiCrAlSiC coating increased 26%, together with the wear rate reduced 52%. Wear mechanism of the NiCrAl coating was abrasive wear, while that of the NiCrAlSiC coating switched to adhesive wear. These results indicate that the addition of SiC improves both high temperature oxidation resistance and wear resistance of the NiCrAl composite coating obviously.

Key words： NiCrAl composite coating high temperature oxidation friction and wear electrophoretic deposition electrodeposition

收稿日期: 2019-02-02

ZTFLH:

TG174.4

基金资助:辽宁省自然科学基金项目No.20170540666

作者简介: 赵明雨，女，1987年生，副教授，硕士

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https://www.ams.org.cn/CN/10.11900/0412.1961.2019.00034 或 https://www.ams.org.cn/CN/Y2019/V55/I7/902

图1 “电泳+电沉积”(EPD+ED)制备NiCrAlSiC复合涂层示意图

图2 NiCrAl和NiCrAlSiC复合涂层的XRD谱

图3 EPD+ED制备涂层的表面形貌

图4 EPD+ED制备涂层的纵截面形貌

图5 NiCrAlSiC涂层横截面EPMA分析结果

图6 NiCrAl/Ni基体界面附近TEM明场像

图7 涂层在空气中900 ℃氧化20 h氧化膜的表面形貌

图8 涂层在空气中900 ℃氧化20 h氧化膜的截面形貌

表1 图8中NiCrAl和NiCrAlSiC涂层氧化膜的成分

图9 涂层摩擦系数随时间变化曲线

图10 NiCrAl和NiCrAlSiC涂层的磨痕表面形貌

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