焊接热循环及时效处理对一种Ni-Fe基高温合金的组织和力学性能的影响<sup>*</sup>

doi:10.3724/SP.J.1037.2013.00355

金属学报

2014, Vol. 50

Issue (3): 313-322 DOI: 10.3724/SP.J.1037.2013.00355

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焊接热循环及时效处理对一种Ni-Fe基高温合金的组织和力学性能的影响^*

吴栋¹, 王鑫^1,², 董文超¹, 陆善平¹(

)

1 中国科学院金属研究所沈阳材料科学国家(联合)实验室, 沈阳110016
2 中国工程物理研究院, 绵阳621900

EFFECTS OF WELDING THERMAL CYCLE AND AGING TREATMENT ON THE MICROSTRUCTURE AND MECHANICAL PROPERTY OF A Ni-Fe BASE SUPERALLOY

WU Dong¹, WANG Xin^1,², DONG Wenchao¹, LU Shanping¹(

)

1 Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
2 China Academy of Engineering Physics, Mianyang 621900

引用本文:

吴栋, 王鑫, 董文超, 陆善平. 焊接热循环及时效处理对一种Ni-Fe基高温合金的组织和力学性能的影响^*[J]. 金属学报, 2014, 50(3): 313-322.
Dong WU, Xin WANG, Wenchao DONG, Shanping LU. EFFECTS OF WELDING THERMAL CYCLE AND AGING TREATMENT ON THE MICROSTRUCTURE AND MECHANICAL PROPERTY OF A Ni-Fe BASE SUPERALLOY[J]. Acta Metall Sin, 2014, 50(3): 313-322.

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摘要:

采用焊接热模拟实验, 研究了焊接热循环对一种700 ℃超超临界火电机组高温部件候选材料—Ni-Fe基高温合金组织和力学性能的影响. 结果表明, 固溶态Ni-Fe基高温合金在经过峰值温度为1249 ℃的焊接热循环后, 25和700 ℃屈服强度和抗拉强度都降低, 延伸率升高. 对经过焊接热循环后的合金再进行时效处理发现, 在25 ℃时, 焊接热循环后再时效样品的屈服强度和抗拉强度与母材时效态相当; 在700 ℃时, 焊接热循环后再时效样品的强度高于母材时效态的强度. Ni-Fe基高温合金在高温焊接热循环过程中, 强化相γ'以及难溶相MC发生溶解, 导致强度下降. 经过时效处理后, 强化相γ'再次大量析出, 同时晶界析出了M₂₃C₆. M₂₃C₆存在于晶界, 并没有造成拉伸性能的弱化. 高温焊接热循环使MC发生部分溶解, 为M₂₃C₆的时效析出提供了C元素.

关键词 ： Ni-Fe基高温合金, 焊接热循环, 时效, γ', 碳化物, 力学性能

Abstract：

Increasing the steam temperature and pressure of boilers in super-ultracritical power plant is an important approach to increase the plant efficiency. The steam temperature of the most efficient coal power plant is now around 620 ℃, representing an increase of about 80 ℃ in the past 40 years, which owes to the high temperature properties improvement of boiler components, such as the superheater and the reheater. Nickel base superalloy, for example Inconel 740 and Inconel 617, is being developed by some countries for the material requirement of 700 ℃ super-ultracritical power plants. Meanwhile, weldability investigation is necessary for the developing materials since welding plays a key role on the construction of coal power plant boilers. In this work, the weldability of a kind of Ni-Fe base superalloy, one of the candidate materials for the high temperature components of 700 ℃ ultra-supercritical coal plant is studied. By welding thermal simulator (Gleeble 1500) experiments, the variation and evolution of mechanical properties and microstructure were analyzed for this Ni-Fe base superalloy, under welding thermal cycle treatment condition and aging treatment condition after welding thermal cycle. After the welding thermal cycle with a peak temperature of 1249 ℃, both the yield strength and tensile strength for solutioned Ni-Fe base superalloy at 25 and 700 ℃ were decreased, along with the increasing of ductility. After aging treatment to the Ni-Fe base superalloy experienced a welding thermal cycle, the yield strength and tensile strength at 25 ℃ were similar with those of the aged base metal. At 700 ℃, the strength of the heat affected zone (HAZ) after aging treatment is higher than that of the aged Ni-Fe base superalloy. Microstructure analysis showed that the γ' phase and MC carbide in Ni-Fe base superalloy dissolved during the high temperature welding thermal simulation experimental process. The solution of carbides in the grain boundaries caused a loss of a pinning effect on the migration of grain boundary and a decreasing of the strength. After the aging treatment to the Ni-Fe base superalloy experienced a high temperature welding thermal cycle, γ' and M₂₃C₆ carbide were precipitated. The precipitation of M₂₃C₆ at the grain boundaries during aging treatment was mainly due to the supply of the carbon from the MC which had been dissolved partially during former welding thermal cycle.

Key words： Ni-Fe base superalloy welding thermal cycle aging γ' carbide mechanical property

收稿日期: 2013-06-26

ZTFLH:

TG113.26

基金资助:* 国家高技术研究发展计划资助项目2012AA03A501

作者简介: null

吴栋, 男, 1988年生, 硕士生

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https://www.ams.org.cn/CN/10.3724/SP.J.1037.2013.00355 或 https://www.ams.org.cn/CN/Y2014/V50/I3/313

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表1 固溶态和焊接热循环态下的晶粒尺寸

表2 Ni-Fe基高温合金在25和700 ℃下的拉伸性能

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表3 在25和700 ℃下Ni-Fe基高温合金(含HAZ)时效态的拉伸性能

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[1]	Zhang H J, Zhou R C, Hou S F, Guo Y. Proc CSEE, 2011; 31: 108
[1]	(张红军, 周荣灿, 侯淑芳, 郭岩. 中国电机工程学报, 2011; 31: 108)
[2]	Bugge J, Kaer S, Blum R. Energy, 2006; 31: 1437
[3]	Wang J, Dong J X, Zhang M C, Xie X S. World Iron Steel, 2011; 11(2): 26
[3]	(王珏, 董建新, 张麦仓, 谢锡善. 世界钢铁, 2011; 11(2): 26)
[4]	Hu P. Electric Power Construction, 2005; 26(6): 26
[4]	(胡平. 电力建设, 2005; 26(6): 26)
[5]	Guo Y, Zhou R C, Hou S F, Zhang H J. Proc CSEE, 2010; 30: 86
[5]	(郭岩, 周荣灿, 侯淑芳, 张红军. 中国电机工程学报, 2010; 30: 86)
[6]	Zhao S Q, Xie X S, Smith G D, Patel S J. Mater Des, 2006; 27: 1120
[7]	Cowen C J, Danielson P E, Jablonski P D. J Mater Eng Perform, 2011; 20: 1078
[8]	Evans N D, Maziasz P J, Swindeman R W, Smith G D. Scr Mater, 2004; 51: 503
[9]	Park Y S, Ham H S, Cho S M, Bae D H. In: Guagliano M, Vergani L eds., Proc 11th Int Conf on the Mechanical Behavior of Materials (ICM11), Amsterdam: Elsevier Science BV, 2011: 2645
[10]	Mankins W L, Hosier J C, Bassford T H. Metall Mater Trans, 1974; 5B: 2579
[11]	Guo J T, Du X K. Acta Metall Sin, 2006; 41: 1221
[11]	(郭建亭, 杜秀魁. 金属学报, 2006; 41: 1221)
[12]	Masuyama F. ISIJ Int, 2001; 41: 612
[13]	Viswanathan R, Bakker W. J Mater Eng Perform, 2001; 10: 81
[14]	Shi X. Electr Weld Mach, 2010; 40(2): 4
[14]	(史轩. 电焊机, 2010; 40(2): 4)
[15]	Zhong W L,Wang W,Liang Y C,Lin J D,Lin Q R,Liu H W,Yu Y R. High Temperature Steam Oxidation of Supercritical Plant Metal. Beijing: China Electric Power Press, 2010: 30
[15]	(钟万里,王伟,梁永纯,林介东,林清如,刘洪文,虞月荣. 超临界机组金属高温蒸汽氧化. 北京: 中国电力出版社, 2010: 30)
[16]	Ramirez J E. Weld J, 2012; 91: 122
[17]	Mo W L, Lu S P, Li D Z, Li Y Y. J Mater Sci Technol, 2013; 29: 458
[18]	Mo W L, Lu S P, Li D Z, Li Y Y. Mater Sci Eng, 2013; A582: 326
[19]	Xu S, Dickson J I, Koul A K. Metall Mater Trans, 1998; 29A: 2687
[20]	Shulga A V. J Alloys Compd, 2007; 436: 155
[21]	Li Y Q,Liu J Y. Interstitial Phase of Superalloy. Beijing: Metallurgical Industry Press, 1990: 276
[21]	(李玉清,刘锦岩. 高温合金间隙相. 北京: 冶金工业出版社, 1990: 276)
[22]	Richards N L, Chaturvedi M C. Int Mater Rev, 2000; 45: 109
[23]	Hu R, Bai G H, Li J S, Zhang J Q, Zhang T B, Fu H Z. Mater Sci Eng, 2012; A548: 83
[24]	Jena A K, Chaturvedi M C. J Mater Sci, 1984; 19: 3121
[25]	Garosshen T J, Mccarthy G P. Metall Trans, 1985; 16A: 1213

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