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X-RAY DIFFRACTION STUDY ON CRYSTALLIZATION OF AMORPHOUS Fe (76.5)Cu_1Si_(13.5)B_9 ALLOY |
YANG Huisheng; XIONG Xiaotao; XU Zuxiong; MA Ruzhang (University of Science and Technology Beijing); TU Guochao; ZHANG Jiaji (Institute of Metallurgy; Shoudu Iron and Steel Company) |
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Cite this article:
YANG Huisheng; XIONG Xiaotao; XU Zuxiong; MA Ruzhang (University of Science and Technology Beijing); TU Guochao; ZHANG Jiaji (Institute of Metallurgy; Shoudu Iron and Steel Company). X-RAY DIFFRACTION STUDY ON CRYSTALLIZATION OF AMORPHOUS Fe (76.5)Cu_1Si_(13.5)B_9 ALLOY. Acta Metall Sin, 1992, 28(11): 75-80.
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Abstract X-ray diffraction peak for α-Fe solid solution (α-phase) precipitates during crystallization of Fe_(76.5)Cu_1Si_(13.5)B_9 amorphous alloy was asymmetrical and dependent on annealing temperature. The fitting results for (200)_α peak indicated that Cu atoms may promote the nucleation of α-phase and dissolve in it so the crystallization has no relation with the as-quenched α phase. The bond energy between atoms in alloy shows that Cu atoms interact slightly with others, as a result, it decreases the removal energy barrier and the crystallization initiates in the Cu-rich region, and results in the decrease of crystallization temperature.
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Received: 18 November 1992
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