MICROSTRUCTURE AND PHASE TRANSFORMATION OF Ni43Co7Mn41Sn9 HIGH TEMPERATURE SHAPE MEMORY ALLOY RIBBON

doi:10.3724/SP.J.1037.2013.00155

Acta Metall Sin

2013, Vol. 49

Issue (8): 976-980 DOI: 10.3724/SP.J.1037.2013.00155

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MICROSTRUCTURE AND PHASE TRANSFORMATION OF Ni₄₃Co₇Mn₄₁Sn₉ HIGH TEMPERATURE SHAPE MEMORY ALLOY RIBBON

CHEN Feng¹⁾, SU Dexi¹⁾, TONG Yunxiang¹⁾, NIU Liqun¹⁾,WANG Haibo²⁾, LI Li¹⁾

1) Center for Biomedical Materials and Engineering, Harbin Engineering University, Harbin 150001
2) College of Physics and Electronic Engineering, Taizhou University, Taizhou 318000

Cite this article:

CHEN Feng, SU Dexi, TONG Yunxiang, NIU Liqun,WANG Haibo, LI Li. MICROSTRUCTURE AND PHASE TRANSFORMATION OF Ni₄₃Co₇Mn₄₁Sn₉ HIGH TEMPERATURE SHAPE MEMORY ALLOY RIBBON. Acta Metall Sin, 2013, 49(8): 976-980.

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Abstract

NiCoMnSn shape memory alloy (SMA) is expected to be a promising high temperature SMA. However, the brittleness has become a big obstacle for its practical application. It is known that, grain refining is effective in improving the ductility of a specific metallic alloy. The aim of this work is to investigate the effect of melt--spinning on grain refinement and martensitic transformation and provide a guideline for the development of NiCoMnSn SMA. Ni₄₃Co₇Mn₄₁Sn₉ high temperature SMA ribbon was prepared by a single-roll melt-spinning method. The microstructure and martensitic transformation were investigated by means of OM, SEM, TEM, XRD and DSC, respectively. The experimental results showed that, the ribbon had a chemical composition close to the master alloy and exhibited a thermoelastic martensitic transformation at about 160℃. The grains in the as-spun ribbon, ranging from 2 μm to 18 μm,were remarkably refined compared with the master alloy. In the as--prepared ribbon,most of the columnar grains grew along the direction vertical to the ribbon plane.At room temperature, non-modulated martensite (tetragonal structure) consisting of twin substructure is determined in the ribbon after relieving the internal stress. Transformation temperatures were lowered by 30℃ after heat treatment at 400℃ for 1 h and then kept nearly constant with the increase of heat treatment temperatures.

Key words: Ni-Co-Mn-Sn high temperature shape memory alloy ribbon rapid solidification martensitic transformation

Received: 02 April 2013

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	CHEN Feng
	SU Dexi
	TONG Yunxiang
	NIU Liqun
	WANG Haibo
	LI Li

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https://www.ams.org.cn/EN/10.3724/SP.J.1037.2013.00155 OR https://www.ams.org.cn/EN/Y2013/V49/I8/976

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