Research Progress in Elastocaloric Cooling Effect Basing on Shape Memory Alloy

doi:10.11900/0412.1961.2020.00270

Acta Metall Sin

2021, Vol. 57

Issue (1): 29-41 DOI: 10.11900/0412.1961.2020.00270

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Research Progress in Elastocaloric Cooling Effect Basing on Shape Memory Alloy

XIAO Fei, CHEN Hong, JIN Xuejun(

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School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

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XIAO Fei, CHEN Hong, JIN Xuejun. Research Progress in Elastocaloric Cooling Effect Basing on Shape Memory Alloy. Acta Metall Sin, 2021, 57(1): 29-41.

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Abstract

Elastocaloric refrigeration is characterized by a high energy efficiency and drastic temperature change, and it requires no refrigerant. It is the best candidate for the non-gas-liquid compression refrigeration technology, which has the advantage of alternate absorption and release of latent heat during solid-solid phase transformation to realize refrigeration. Compared with the magnetocaloric and electrocaloric refrigeration, elastocaloric refrigeration exhibits advantages such as low cost, high cooling rate, and high efficiency. Elastocaloric refrigeration mainly employs shape memory alloys, which have been a research focus in the past decades. This study describes the mechanism and test methods of the elastocaloric effect and summarizes the research progress as well as challenges in the Ti-Ni-based, Cu-based, Fe-based, and Heusler-type shape-memory alloys as elastocaloric materials. Furthermore, a brief perspective on research directions of the elastocaloric effect based on shape memory alloys is presented herein.

Key words: elastocaloric effect shape memory alloy martensitic transformation

Received: 21 July 2020

ZTFLH:

TG139

Fund: National Natural Science Foundation of China(51871151);Natural Science Foundation of Shanghai(20ZR1428800)

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	Fei XIAO
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https://www.ams.org.cn/EN/10.11900/0412.1961.2020.00270 OR https://www.ams.org.cn/EN/Y2021/V57/I1/29

Table 1 Caloric effects, the control parameters used to induce the phase transformation, typical temperature changes, and materials^[12]

Fig.1 Schematic showing the elastocaloric effect in shape memory alloy

Fig.2 Schematic showing of Ti-Ni shape memory alloy elastocaloric temperature change test during tension

Fig.3 Temperature distributions (in ^oC, detected by infrared camera) of Ti-Ni shape memory alloy during the quick loading and unloading processes (Δε—strain amplitude)^[19]

Fig.4 The temperature and strain distributions of the Ti-44Ni-5Cu-1Al alloy during the loading process^[30]

Fig.5 The inverse elastocaloric effect in the Ti-Ni shape memory alloy exhibiting aligned Ti₃Ni₄ precipitates^{drew according to Ref.[46] (σ_ext—external stress)}

Fig.6 Comparisons of the elastocaloric effect between the Ni-Fe-Ga-Co alloy exhibiting typical first-order martensitic transformation (a) and the Fe-Pd alloy exhibiting weak first-order martensitic transformation (b) drew according to Refs.[72,73] (ΔT—sample temperature change, A_f—finish temperature of the reverse martensitic transformation, M_d—highest temperature of the martensitic transformation)

Fig.7 Comparisons of several typical shape memory alloy as elastocaloric materials including isothermal entropy change (ΔS_iso) and adiabatic temperature change (ΔT_adi)

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