PRODUCTION OF MgAlON BY CARBOTHERMAL REDUCTION AND NITRIDATION

doi:10.3724/SP.J.1037.2011.00296

Acta Metall Sin

2011, Vol. 47

Issue (11): 1440-1444 DOI: 10.3724/SP.J.1037.2011.00296

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PRODUCTION OF MgAlON BY CARBOTHERMAL REDUCTION AND NITRIDATION

DAI Wenbin, WANG Xinli, YU Jingkun, ZOU Zongshu

School of Materials and Metallurgy, Northeastern University, Shenyang 110819

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DAI Wenbin WANG Xinli YU Jingkun ZOU Zongshu. PRODUCTION OF MgAlON BY CARBOTHERMAL REDUCTION AND NITRIDATION. Acta Metall Sin, 2011, 47(11): 1440-1444.

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Abstract Gravimeter, pycnometer, SEM, XRD, carbon analyzer, XFS and oxygen-nitrogen analyzer were utilized to study the production of magnesium aluminium oxynitride (MgAlON) by carbothermal reduction and nitridation (CRN) under different temperatures and its formation mechanism was also discussed in the present paper. The results show that all of the raw MgO are completely consumed to form MgAl₂O_4ss at 1100℃. At sintered temperatures higher than 1300℃, the CRN reaction is taken place, and MgAlON is formed by solid solving N into MgAl₂O_4ss. The consumption of Al₂O₃ during CRN reaction causes the particle size of Al₂O₃ in the sample heated at 1600℃ to be smaller than that heated at 1500℃. Finally, the monophase MgAlON is obtained at 1650℃ when all the graphite and Al₂O₃ have been consumed. Moreover, because of the solid solution of N into MgAl₂O_4ss, the amount of defects in the lattice of MgAlON is raised leading to the solubility of Al in MgAlON being higher than that in MgAl₂O_4ss. Lots of closed pores are remained in grains even if the heating temperature has been raised to 1800℃ due to higher volatile Mg partial pressure and the gas phase product of CRN reaction at high temperature.

Key words: MgAlON carbothermal reduction and nitridation (CRN) microstructure

Received: 09 May 2011

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TB321

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Supported by Specialized Research Fund for the doctoral Program of Higher Education (No.20090042120009)

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https://www.ams.org.cn/EN/10.3724/SP.J.1037.2011.00296 OR https://www.ams.org.cn/EN/Y2011/V47/I11/1440

[1] Lofaj F, Doˇc´akov´a F, HoffmannM. J Mater Sci, 2005; 40: 47

[2] Zhang T. Refractories, 2002; 36: 26

(张涛. 耐火材料, 2002; 36: 246)

[3] Luo X Y, Sun J L, Wang J X, Hong Y R. Refractories, 2000; 34: 147

(罗星源, 孙加林, 王金相, 洪彦若. 耐火材料, 2000; 34: 147)

[4] Deng C J, Hong Y R, Zhong X C, Sun J L. Refractories, 2001; 35: 135

(邓承继, 洪彦若, 钟香崇, 孙加林. 耐火材料, 2001; 35: 135)

[5] Granon A, Goeuriot P, Thevenot F, Guyader J, L’Jaridon P, Laurent Y. J Euro Ceram Soc, 1994; 14: 365

[6] Bandyopadhyay S, Rixecker G, Aldinger F, Maiti S. J Am Ceram Soc, 2004; 87: 480

[7] Zhang H X, Huang Y, Li H F, Wang Z J. Ceram Sin, 2005; 26: 13

(张厚兴, 黄勇, 李海峰, 万之坚. 陶瓷学报, 2005; 26: 13)

[8] Dai W B, Yamaguchi A, Lin W, Ommyoji J, Yu J K, Zou Z S. J Ceram Soc Jpn, 2007; 115: 515

[9] Wang X T, Wang H Z, Zhang W J, Sun J L, Hong Y R. Key Eng Mater, 2002; 224–226: 373

[10] Dai W B, Lin W, Yamaguchi A, Ommyoji J, Yu J K, Zou Z S. J Ceram Soc Jpn, 2007; 114: 42

[11] American Ceramic Society. ACers–NIST Phase Equilbria Database–ver. 3.0.1. Westerville, OH: American Ceramic Society, 2004

[12] Morey O, Goeuriot P. J Euro Ceramic Soc, 2005; 25: 501

[13] Mackenzie K J D, Temuujin J, Jadambaa T, Smithi M E, Angerer P. J Mater Sci, 2000; 35: 5529

[14] Dai W B, Wang X L, Zhao P, Zhao L, Yu J K. J Ceram Soc Jpn, 2011; 119: 31

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