金属学报  2004, Vol. 40 Issue (4): 337-341

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马氏体相变的形核问题

孟庆平 戎咏华 徐祖耀

(上海交通大学材料科学与工程学院; 上海 200030)

Nucleation Of Martensitic Transformation[

MENG Qingping; RONG Yonghua; T.Y. Hsu (XU Zuyao)

School of Materials Science and Engineering; Shanghai Jiao Tong University; Shanghai 200030

孟庆平; 戎咏华; 徐祖耀 . 马氏体相变的形核问题[J]. 金属学报, 2004, 40(4): 337-341 .
, , . Nucleation Of Martensitic Transformation[[J]. Acta Metall Sin, 2004, 40(4): 337-341 .

摘要 参考文献 相关文章 Metrics 全文: PDF(187 KB)   摘要: 在对马氏体相变经典形核理论阐述的基础上, 仔细考察了Fisher等以统计物理对形核几率的原始推导, 指出一些学者近年来否定Cohen和Kaufman马氏体相变形核几率计算的错误, 确定形核几率计算中的形核能垒ΔG*应为临界核胚中所有原子的总自由能变化, 而不应为核胚中单个原子的自由能. 对他们佐证均匀形核观点所引用的实验给予了重新解释, 对他们提出的形核模型进行了评论. 最后简要提出研究马氏体相变形核问题的几个可能方向. 关键词 ： 马氏体相变,  形核几率,  形核能垒     Abstract：On the basis of describing the classical nucleation theory of martensitic transformation and considering in detail the original derivation of nucleation probability through statistical physics by Fisher $et~al$, the present work points out the mistakes appearing in the recent works of some authors who negated the calculation of the nucleation probability of martensitic transformation with Cohen and Kaufman. The nucleation barrier ΔG* in calculating the nucleation probability should be the free energy change of total atoms in an embryo, rather than that of an atom. 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