多晶<strong>Ni-Mn-<i>X</i></strong>相变合金的织构化与功能行为

doi:10.11900/0412.1961.2021.00276

金属学报

2021, Vol. 57

Issue (11): 1396-1415 DOI: 10.11900/0412.1961.2021.00276

综述

本期目录 | 过刊浏览

多晶Ni-Mn-X相变合金的织构化与功能行为

左良(

), 李宗宾(

), 闫海乐, 杨波, 赵骧

东北大学材料科学与工程学院材料各向异性与织构(教育部)重点实验室沈阳 110819

Texturation and Functional Behaviors of Polycrystalline Ni-Mn-X Phase Transformation Alloys

ZUO Liang(

), LI Zongbin(

), YAN Haile, YANG Bo, ZHAO Xiang

Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China

引用本文:

左良, 李宗宾, 闫海乐, 杨波, 赵骧. 多晶Ni-Mn-X相变合金的织构化与功能行为[J]. 金属学报, 2021, 57(11): 1396-1415.
Liang ZUO, Zongbin LI, Haile YAN, Bo YANG, Xiang ZHAO. Texturation and Functional Behaviors of Polycrystalline Ni-Mn-X Phase Transformation Alloys[J]. Acta Metall Sin, 2021, 57(11): 1396-1415.

全文: PDF(3892 KB) HTML

摘要:

具备一级马氏体相变特征的Ni-Mn-X (X = Ga、In、Sn、Sb等)系列合金具有多种显著的功能特性(如磁驱动形状记忆效应、磁热效应、弹热效应等)，在新型智能驱动传感及固态制冷等领域有广阔的应用前景。本课题组近年来以多晶Ni-Mn-X合金的织构化与微观组织调控为出发点，针对多晶Ni-Mn-X系列合金的晶体结构与微观组织特征、马氏体相变晶体学以及相关功能行为等方面开展了一系列的探索；本文综述了本课题组近年来所取得的一些研究进展。

关键词 ：形状记忆合金, 马氏体相变, 晶体学织构, 磁致形状记忆效应, 磁热效应, 弹热效应

Abstract：

Ni-Mn-X (X = Ga, In, Sn, and Sb) alloys undergoing the first-order martensitic transformation have received attention owing to their various functional behaviors (e.g., magnetic shape-memory, magnetocaloric, and elastocaloric effects), which can be developed as materials for application in novel-intelligent sensing and solid-state refrigeration. Recently, along the line of texturation and microstructure control for the polycrystalline alloys, our group has conducted a series of explorations on the crystal structure and microstructural features, martensitic transformation crystallography, and related functional behavior of polycrystalline Ni-Mn-X alloys. In this paper, the recent progress of our group's study has been summarized.

Key words： shape memory alloys martensitic transformation crystallographic texture magnetic shape memory effect magnetocaloric effect elastocaloric effect

收稿日期: 2021-07-06

ZTFLH:

TG139.6

基金资助:国家自然科学基金项目(51431005);中央高校基本科研业务费项目(N2102006);辽宁省兴辽英才计划项目(XLYC1907082)

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图1 磁驱动形状记忆效应机制的晶格变形示意图

图2 Ni50Mn36In14合金调制结构马氏体的高能X射线粉末衍射谱及基于超空间理论的全谱拟合谱[47]

图3 Ni50Mn36In14合金6M马氏体的超结构模型[50]

图4 多晶Ni50Mn30Ga20合金一个7M马氏体变体团内部的EBSD取向成像图[53]

表1 多晶Ni50Mn30Ga20合金7M马氏体变体间的取向差角(ω)及正交归一参考坐标系下的旋转轴(d)[53]

表2 Ni50Mn30Ga20合金7M马氏体的3种类型孪晶的孪生元素[53]

图5 奥氏体内包含4个7M变体的EBSD取向成像图[66]

图6 奥氏体与7M马氏体之间惯习面的TEM高分辨像(电子束沿<1 1 1>A晶带轴)[66]

表3 表述在[1 0 1]A-[1 0 1]A-[0 1 0]A坐标系下(1 0 1)A变体团中4个7M马氏体变体的变形梯度矩阵[66]

图7 共存于同一个奥氏体晶粒内的奥氏体、7M及NM马氏体的EBSD相标定成像图及取向成像图[67]

图8 7M马氏体与NM马氏体共存的TEM明场像及相应的选区电子衍射花样[68]

图9 定向凝固Ni50Mn30Ga20合金相变过程中施加50 MPa压应力后的局部EBSD取向成像图[76]

图10 定向凝固Ni50Mn30Ga20合金的压缩应力-应变曲线及变形过程中的中子衍射图谱[77]

图11 不同压缩变形量下定向凝固Ni50Mn30Ga20合金7M马氏体的EBSD取向成像图[77]

图12 压缩载荷下变体A和D中I型、II型和复合型去孪生系统Schmid因子极射赤面投影分布图[79]

图13 多晶Ni50Mn36In14合金6M马氏体沿不同压缩方向加载前后的EBSD取向成像图[79]

图14 定向凝固Ni50Mn28.5Ga21.5合金纵截面的宏观形貌及横截面的{0 0 10}M和{0 4 0}M极图[80]

图15 机械训练后定向凝固Ni50Mn28.5Ga21.5合金样品的磁感生应变曲线[80]

图16 定向凝固Ni45.3Co5.1Mn36.1In13.5合金的M(T)曲线及1.5 T磁场下的ΔTad随温度变化[91]

图17 Ni46Co3Mn35Cu2In14合金2次测量获得的ΔSM及ΔTad随温度变化[95]

图18 定向凝固Ni55Mn18Ga27合金压应力下的超弹性应力-应变曲线及绝热温变[99]

图19 定向凝固Ni50Mn35In15合金320 K加载和卸载过程中的绝热温变及转变熵变随温度变化[105]

图20 定向凝固Ni44Mn46Sn10合金的超弹性应力-应变曲线与绝热温变曲线[106]

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