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金属学报  2024, Vol. 60 Issue (1): 1-15    DOI: 10.11900/0412.1961.2022.00582
  综述 本期目录 | 过刊浏览 |
增材制造TiAl合金的研究进展
陈玉勇1,2(), 时国浩1,2, 杜之明2, 张宇1,2, 常帅1
1 哈尔滨工业大学 先进焊接与连接国家重点实验室 哈尔滨 150001
2 哈尔滨工业大学 金属精密热加工国家级重点实验室 哈尔滨 150001
Research Progress on Additive Manufacturing TiAl Alloy
CHEN Yuyong1,2(), SHI Guohao1,2, DU Zhiming2, ZHANG Yu1,2, CHANG Shuai1
1 State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001, China
2 National Key Laboratory for Precision Hot Processing of Metals, Harbin Institute of Technology, Harbin 150001, China
引用本文:

陈玉勇, 时国浩, 杜之明, 张宇, 常帅. 增材制造TiAl合金的研究进展[J]. 金属学报, 2024, 60(1): 1-15.
Yuyong CHEN, Guohao SHI, Zhiming DU, Yu ZHANG, Shuai CHANG. Research Progress on Additive Manufacturing TiAl Alloy[J]. Acta Metall Sin, 2024, 60(1): 1-15.

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摘要: 

轻质耐热的TiAl合金是航空航天和民用工业等领域最具潜力的高温结构材料之一。然而,由于其低的延展性和断裂韧性,制造TiAl零部件具有挑战性。目前,增材制造工艺被认为是制造TiAl零件具有前途的技术之一。本文在介绍增材制造技术原理和特点的基础上,综述了激光金属沉积(LMD)、选区激光熔化(SLM)和电子束熔化(EBM)制备TiAl合金的工艺-组织-性能关系,并对该技术未来的发展趋势进行了展望。

关键词 TiAl合金激光金属沉积选区激光熔化电子束熔化    
Abstract

One of the most promising high-temperature structural materials in aerospace and civil industries is the lightweight and heat-resistant TiAl alloys. However, owing to their low ductility and fracture toughness, manufacturing TiAl parts is challenging. At present, additive manufacturing process is considered one of the most promising technologies for manufacturing TiAl parts. Based on the principles and characteristics of additive manufacturing technology, this paper summarizes the process-structure-property relation of laser metal deposition (LMD), selective laser melting (SLM), and electron beam melting (EBM) in the preparation of TiAl alloy. Furthermore, this paper discusses the future development trends of additive manufacturing technology.

Key wordsTiAl alloy    laser metal deposition    selective laser melting    electron beam melting
收稿日期: 2022-11-10     
ZTFLH:  TG146.23  
基金资助:国家重点研发计划项目(2017YFE0123500)
通讯作者: 陈玉勇,yychen@hit.edu.cn,主要从事高温钛合金及TiAl合金研究
Corresponding author: CHEN Yuyong, professor, Tel: (0451)86418802, E-mail: yychen@hit.edu.cn
作者简介: 陈玉勇,男,1956年生,教授,博士
图1  增材制造工作原理示意图[8,11]

Method

Energy source

Power

W

Beam size

mm

Layer thickness

μm

Powder preheating

oC

Residual stress

Build speed

cm3·h-1

Dimensional accuracy

mm

Ra

μm

Max. build size

mm

Machines

company

LMDLaser100-100002-4500-1000Room temperatureHighHigh, ~10000.5-1.0

20-50

(Coarse)

4000 × 2000 × 1000Optomec (USA)

SLM

Laser

50-500

0.1-0.5

50-100

≤ 200

High

Low, ~150

0.04-0.2

9-12

(Excellent)

800 × 400 × 500

Concept Laser and SLM Solutions (Germany)
EBMElectronbeam30000.2-1.050-200600-1150MinimalLow, ~150± 0.2

25-35

(Moderate)

ϕ350 × 380Arcam (Sweden)
表1  增材制造技术的对比[8~11]
ProcessPowder feed rate / (g·min-1)Optimum energy density / (J·mm-2)
10.560-150
21.025-60
32.210-20
表2  激光金属沉积(LMD)制造Ti-47Al-2Cr-2Nb合金的最佳工艺条件[14]
图2  激光沉积Ti-48Al-2Cr-2Nb合金的SEM-BSE像[22]
图3  Ti-47Al-2Cr-2Nb合金热处理前后的SEM像[14]
λ / (°)UTS / MPaδ / %
07060.51
453580.49
902730.16
表3  Ti-47Al-2Cr-2Nb合金在不同加载方向下的室温拉伸性能[31]
图4  不同扫描速率下选区激光熔化(SLM)加工Ti-40Al-9V-0.5Y合金的裂纹密度和孔隙率[51]
图5  SLM制造的TNM-B1样品的SEM像[52,53]
图6  在不同体积能量水平下生产的TNB-V4样品微观组织的SEM像[47]
图7  电子束熔化(EBM)制备Ti-48Al-2Cr-2Nb合金的OM像[73]
图8  热处理EBM Ti-48Al-2Cr-2Nb合金的拉伸性能[82]
Specimen condition

Kq

MPa·m1/2

R

ΔKth

MPa·m1/2

Kmax

MPa·m1/2

As-built24.1 ± 6.50.38-913.2-13.9
HIP27.8 ± 0.40.11318.2
As-cast24-250.38-918.3-20.4
表4  EBM Ti-48Al-2Cr-2Nb合金的缺口韧性和疲劳裂纹扩展结果汇总[67]
图9  EBM制造的TiAl涡轮叶片[90]
图10  EBM Ti-48Al-2Cr-2Nb合金的蜂窝结构[4]
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