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INFLUENCE OF Ce IMPLANTATION ON OXIDATION BEHAVIOUR OF Ni20Cr ALLOY |
LI Meishuan; PENG Hiao;MA Hinqing;LI Tiefan(Corrosion Science Laboratory;Institute of Corrosion and Protection of Metals;Chinese Academy of Sciences)(Manuscript received 10 May;1993) |
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Cite this article:
LI Meishuan; PENG Hiao;MA Hinqing;LI Tiefan(Corrosion Science Laboratory;Institute of Corrosion and Protection of Metals;Chinese Academy of Sciences)(Manuscript received 10 May;1993). INFLUENCE OF Ce IMPLANTATION ON OXIDATION BEHAVIOUR OF Ni20Cr ALLOY. Acta Metall Sin, 1994, 30(16): 169-174.
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Abstract Implantation of 2×1016,5×1016,1×1017Ce+/cm2 into Ni20Cr alloy can significantly decrease the oxidation rate at 1000 and 1100℃,and improve the adhesion of oxide scales.The changes of binding energy of alloy in elements in alloy surface after Ce implanting and in oxide scale formed at 1100℃ were measured using ion microperobe mass analyzer.The decrement of binding energy of Cr+on the alloy surface accelerate rapidly the formation of protective Cr2O3,however these of Cr+and Ni+ in the oxide scale increase,the outward diffusion of Cr3+and Ni2+through the scale are delayed.This seems to be the main reason for Ce implantation to decrease the oxidation rate of Ni20Cr at 1100℃.The oxide scales of Ce-implanted Ni20Cr alloy are dense,intact and well adhesive with the alloy.The oxide scales spall partially after 270 time during the cyclic oxidation at 1000℃,but the effect of Ce on the improvement of the oxide scale adherence is still obvious.Correspondent:LI Meishuan,assistant professor,(Institute of Corrosion and Protection of Metals,Chinese Academy of Sciences,Shenyang 110015)
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