INFLUENCE OF Re ON MICROSTRUCTURESOF A DIRECTIONALLY SOLIDIFIEDNi-BASED SUPERALLOY

doi:10.11900/0412.1961.2015.00600

Acta Metall Sin

2016, Vol. 52

Issue (7): 851-858 DOI: 10.11900/0412.1961.2015.00600

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INFLUENCE OF Re ON MICROSTRUCTURESOF A DIRECTIONALLY SOLIDIFIEDNi-BASED SUPERALLOY

Siqian ZHANG¹,Dong WANG²(

),Di WANG²,Jianqiang PENG³

1 School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China.
2 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China.
3 Harbin Turbine Co. Ltd., Harbin 150046, China.

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Siqian ZHANG,Dong WANG,Di WANG,Jianqiang PENG. INFLUENCE OF Re ON MICROSTRUCTURESOF A DIRECTIONALLY SOLIDIFIEDNi-BASED SUPERALLOY. Acta Metall Sin, 2016, 52(7): 851-858.

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Abstract

Up to now, considerable effort has been expended in attempts to investigate the influences of Re on Ni-based single crystal superalloys. However, few study had elucidated the influences of Re on carbide, boride and grain boundary. Therefore, the influence of a 2%Re (mass fraction) addition on the as-cast and heat-treated microstructures of a Ni-based directionally solidified superalloy was investigated by comparison with Re-free alloy using SEM, EPMA and TEM. The results show that Re accelerates the precipitation of μ phase in the periphery of eutectic and at grain boundary for as-cast microstructure. After heat treatment, Re also accelerates the precipitation of phase in the vicinity of primary MC carbide and at grain boundary. For 0Re alloy, there are small number of M₆C carbide in the vicinity of primary MC carbide and M₂₃(C, B)₆ boro-carbide at grain boundary. For 2Re alloy, a large amount of blocky μ phase enveloped by thick γ′-film is found in the vicinity of primary MC carbide and at grain boundary. Enrichment of B along the grain boundary is observed in 0Re alloy. On the contrary, relatively uniform distribution of B is found in 2Re alloy. The precipitation mechanism of μ phase during the process of heat treatment is also analyzed.

Key words: Ni-based superalloy directional solidification Re μ phase grain boundary carbide

Received: 19 November 2015

Fund: Supported by National Natural Science Foundation of China (Nos.51101160 and 51501117), National Key Foundation for Exploring Scientific Instrument (No.2012YQ22023304) and Liaoning Provincial Department of Education Project (No.L2014050)

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https://www.ams.org.cn/EN/10.11900/0412.1961.2015.00600 OR https://www.ams.org.cn/EN/Y2016/V52/I7/851

Table 1 Nominal compositions of 0Re and 2Re columnar grain superalloys

Fig.1 Precipitates at periphery region of eutectic(a) SEM image of 0Re alloy (b) SEM image of 2Re alloy (c) TEM image and corresponding SAED pattern (inset) of 0Re alloy (d) TEM image and corresponding SAED patterns (insets) of 2Re alloy

Fig.2 Microstructures of grain boundary (GB) in as-cast alloy(a) SEM image of 0Re alloy (b) SEM image of 2Re alloy (c) TEM image of 0Re alloy (d) TEM image and corresponding SAED pattern (inset) of 2Re alloy

Fig.3 Microstructures of interdendritic region(a) SEM image of as-cast 0Re alloy (b) SEM image of as-cast 2Re alloy (c) SEM image of heat-treated 0Re alloy (d) SEM image of heat-treated 2Re alloy(e) TEM image and corresponding SAED pattern (inset) of heat-treated 0Re alloy(f) TEM image and corresponding SAED pattern (inset) of heat-treated 2Re alloy

Fig.4 Microstructures of heat-treated GBs(a) SEM image of 0Re alloy (b) SEM image of 2Re alloy(c) TEM image and corresponding SAED pattern (inset) of 0Re alloy(d) TEM image and corresponding SAED pattern (inset) of 2Re alloy

Fig.5 EPMA maps of B in 0Re (a) and 2Re (b) alloys after heat treatment (Insets show that SEM images at GBs of 0Re and 2Re alloys, and arrows show the location of GB)

Table 2 Chemical compositions of phases in 0Re and 2Re alloys by EPMA

Fig.6 SEM images of interdendritic region near the blocky MC carbide of 2Re alloy aging at 1110 ℃ for different times after solution treatment (a) 0 min (b) 5 min (c) 10 min (d) 20 min

Fig.7 SEM images of grain boundary region of 2Re alloy aging at 1110 ℃ for different times after solution treatment (a) 0 min (b) 5 min (c) 10 min (d) 20 min

Fig.8 Formation of the stacking fault in the vicinity of the MC carbide of 2Re alloy after solution treatment

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