INFLUENCE OF DOPING WITH Si AND Y ON STRUCTURE AND PROPERTIES OF (Ti, Al)N COATING

doi:10.3724/SP.J.1037.2011.00292

Acta Metall Sin

2012, Vol. 48

Issue (1): 99-106 DOI: 10.3724/SP.J.1037.2011.00292

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INFLUENCE OF DOPING WITH Si AND Y ON STRUCTURE AND PROPERTIES OF (Ti, Al)N COATING

FAN Yongzhong, ZHANG Shujuan, TU Jinwei, SUN Xia, LIU Fang, LI Mingsheng

Jiangxi Key Laboratory of Surface Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013

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FAN Yongzhong ZHANG Shujuan TU Jinwei SUN Xia LIU Fang LI Mingsheng. INFLUENCE OF DOPING WITH Si AND Y ON STRUCTURE AND PROPERTIES OF (Ti, Al)N COATING. Acta Metall Sin, 2012, 48(1): 99-106.

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Abstract Composite metastable Ti_0.3Al_0.7N and Ti_0.39Al_0.55Si_0.05Y_0.01NN hard coatings were deposited on a wrought martensite steel 1Cr11Ni2W2MoV for aero-engine compressor blades by the magnetron sputtering system with the bias voltage of 0 and -100 V respectively. Detailed microstructure, chemical composition, crystal structure, hardness and adhesion were examined by means of FESEM, EDS, XRD, Micro hardness tester and scratch tester. The influence of doping with Si and Y and bias on structure, oxidation-resistance and mechanical properties of (Ti, Al)N coatings were investigated. Pulsed bias and the doping with Si and Y gave rise to the change of phase structure and improvement of density. Doping with small amounts of Si and Y into (Ti, Al)N significantly improved the oxidation resistance at 950 ℃. The oxidation-resistance of (Ti, Al, Si, Y)N is based on the formation of dense protective Al₂O₃ layer. The application of negative pulse led to decreased hardness for (Ti, Al)N while remarkable decrease of hardness for (Ti, Al, Si, Y)N. For (Ti, Al, Si, Y)N prepared under -100 V\linebreak bias, annealing 10 h at 950 ℃ slightly decreased it's hardness because of the formation of B4 structure. And for which deposited at 0 V bias, heat-treatment of 950 ℃ for 10 h improved the hardness from 26 GPa to 35 GPa. The hardness change of the coating may be ascribed the transition of B1 phase structure. Scratch tests show that the continuous spall is not occurred for all the coatings under the critical load of 50 N.

Key words: magnetron sputtering (Ti, Al)N doping with Si and Y oxidation-resistance hardness adhesion

Received: 09 May 2011

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Supported by Scientific Research Fund of Jiangxi Provincial Education Department (No.GJJ12586)

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	FAN Yong-Zhong
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https://www.ams.org.cn/EN/10.3724/SP.J.1037.2011.00292 OR https://www.ams.org.cn/EN/Y2012/V48/I1/99

[1] Paldey S, Deevi S C. Mater Sci Eng, 2003; A3: 58

[2] Mayrhofer P H, Mitterer C, Hultman L, Clemens H. Prog Mater Sci, 2006; 51: 1032

[3] Ma S L, Jie W Q, Xu K W. Chin J Vac Sci Technol, 2002; 22: 438

(马胜利, 介万奇, 徐可为. 真空科学与技术学报, 2002; 22: 438)

[4] Inoue S, Uchida H, Yoshinaga Y, Koterazawa K. Thin Solid Films, 1997; 300: 171

[5] Li M S, Wang F H, Wang T G, Gong J, Sun C, Wen L S. Acta Metall Sin, 2003; 39: 55

(李明升, 王福会, 王铁钢, 宫俊, 孙超, 闻立时. 金属学报, 2003; 39: 55)

[6] Makino Y. Surf Coat Technol, 2005; 193: 185

[7] Pilloud D, Pierson J F, Marco de Lucas M C, Cavaleiro A. Surf Coat Technol, 2008; 202: 2413

[8] Veprek S, Reiprich S, Shizi L. Appl Phys Lett, 1995; 66: 2640

[9] Vaz F, Rebouta L, Andritschky M, Silva M, Soares J C. Surf Coat Technol, 1998; 98: 912

[10] Pfeiler M, Zechner J, Penoy M, Michotte C, Mitterer C, Kathrein M. Surf Coat Technol, 2009; 203: 3104

[11] Lembke M I, Lewis D B, M¨unz W D, Titchmarsh J M. Surf Eng, 2001; 17: 153

[12] Li M S, Feng C J, Wang F H. Funct Mater (suppl), 2007; (38): 2615

(李明升, 冯长杰, 王福会. 功能材料(增刊), 2007; (38): 2615)

[13] Mao Y F, Tang W G, Liu J L, Han P G. Tool Eng, 2006; 40: 20

(毛延发, 唐为国, 刘金良, 韩培刚. 工具技术, 2006; 40: 20)

[14] Jung H G, Kim K Y. Oxid Met, 1998; 49: 403

[15] Flink A, Andersson J M, Alling B, Daniel R, Sjolen J, Karlsson L, Hultman L. Thin Solid Films, 2008; 517: 714

[16] Carvalho S, Rebouta L, Ribeiro E, Vaz F, Tavares C J, Alves E, Barradas N P, Riviere J P. Vacuum, 2009; 83: 1206

[17] Vennemann A, Stock H R, Kohlscheen J, Rambadt S, Erkens G. Surf Coat Technol, 2003; 174–175: 408

[18] Wang F Z, Ma W C. Vapor Deposition Applications Technology. Beijing: China Machine Press, 2006: 291

(王福贞, 马文存. 气相沉积应用技术. 北京: 机械工业出版社, 2006: 291)

[19] Makino Y. Mater Sci Eng, 1995; 2: 67

[20] Vaz F, Rebouta L, Andritschky M, Silva M, Soares J C. J Eur Ceram Soc, 1997; 17: 1971

[21] Banakh O, Schmid P E, Sanjines R, Levy F. Surf Coat Technol, 2003; 163: 57

[22] Chang Y Y, Hsiao C Y. Surf Coat Technol, 2009; 204: 992

[23] M¨unz W D. Werkst Korros, 1990; 41: 753

[24] Veprek S, Sarott F A, Iqbal Z. Phys Rev, 1987; B36: 3344

[25] Veprek S, Maritza G J, Veprek H, Karvankova P, Prochazka J. Thin Solid Films, 2005; 476: 1

[26] Raveh A, Zukerman I, Shneck R, Avni R, Fried I. Surf Coat Technol, 2007; 201: 6136

[27] Tanaka Y, Ichimiya N, Onishi Y, Yamada Y. Surf Coat Technol, 2001; 146–147: 215

[28] Carvalho S, Rebouta L, Cavaleiro A, Rocha L A, Gomes J, Alves E. Thin Solid Films, 2001; 398–399: 391

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