|
|
Discharge Characteristics of Novel Dual-Pulse HiPIMS and Deposition of CrN Films with High Deposition Rate |
Houpu WU,Xiubo TIAN(),Xinyu ZHANG,Chunzhi GONG |
State Key Laboratory of Advanced Welding Production and Technology, Harbin Institute of Technology, Harbin 150001, China |
|
Cite this article:
Houpu WU,Xiubo TIAN,Xinyu ZHANG,Chunzhi GONG. Discharge Characteristics of Novel Dual-Pulse HiPIMS and Deposition of CrN Films with High Deposition Rate. Acta Metall Sin, 2019, 55(3): 299-307.
|
Abstract High power impulse magnetron sputtering (HiPIMS) is of great significance for improving the quality of sputtered films because of its high ionization degree of sputtered particles and high ion fluxes. Therefore, it has been widely studied by researchers. However, the conventional HiPIMS shows a significantly low deposition rate, which greatly limits the industrial applications of HiPIMS. In this work, a novel high power impulse magnetron sputtering is proposed to enhance the low deposition rate encountered in conventional HiPIMS. The novel technology is based on dual pulses discharge mode, in which a pulsed high voltage with short duration is utilized to high-current discharge and produce initial high density plasma and a subsequent work-pulse of low voltage with long duration is employed to sustain the high-current discharge. Consequently the re-adsorption effect by magnetron target may be weakened. The influence of ignition pulse voltage discharge characteristics of Cr target and microstructure of CrN films were investigated. The discharge characteristics of Cr target and the structure characteristics of CrN coatings were characterized by digital oscilloscope, spectrometer, focused ion beam/electron beam dual-beam microscope and X-ray diffraction. The results show that the discharge of Cr target is ignited rapidly and the discharge current is substantially large with the ignition voltage applied to the target. In contrast, the pulse current gradually rises for the conventional HiPIMS meaning a weak discharge. Compared with the conventional HiPIMS, the dual-pulse HiPIMS produce a higher substrate current integral value and more amount of Ar+ and Cr0 with the same input power. With ignition pulse voltage of 590 V, the deposition rate at unit power for CrN coating is 2.52 μm/(h·kW) for dual-pulse HiPIMS, which is nearly three times higher than that of conventional HiPIMS. With the increase of the ignition pulse voltage, the CrN films prepared by dual-pulse HiPIMS possess denser structure with smaller grain size.
|
Received: 23 March 2018
|
|
Fund: National Natural Science Foundation of China(11675047);National Natural Science Foundation of China(11875119);National Natural Science Foundation of China(51811530059) |
[1] | Li J X, Zhang H Q, Fan A L, et al. Tribological properties characterization of Ti/Cu/N thin films prepared by DC magnetron sputtering on titanium alloy [J]. Surf. Coat. Technol., 2016, 294: 30 | [2] | Liu G, Yang Y Q, Jin N, et al. The structural characterizations of Ti-17 alloy films prepared by magnetron sputtering [J]. Appl. Surf. Sci., 2018, 427: 774 | [3] | Chen L, Chang K K, Du Y, et al. A comparative research on magnetron sputtering and arc evaporation deposition of Ti-Al-N coatings [J]. Thin Solid Films, 2011, 519: 3762 | [4] | Sarakinos K, Alami J, Konstantinidis S. High power pulsed magnetron sputtering: A review on scientific and engineering state of the art [J]. Surf. Coat. Technol., 2010, 204: 1661 | [5] | Odivanova A N, Podkovyrov V G, Sochugov N S, et al. Study of the plasma parameters in a high-current pulsed magnetron sputtering system [J]. Plasma Phys. Rep., 2011, 37: 239 | [6] | Stranak V, Cada M, Hubicka Z, et al. Time-resolved investigation of dual high power impulse magnetron sputtering with closed magnetic field during deposition of Ti-Cu thin films [J]. J. Appl. Phys., 2010, 108: 043305 | [7] | Kouznetsov V, Macák K, Schneider J M, et al. A novel pulsed magnetron sputter technique utilizing very high target power densities [J]. Surf. Coat. Technol., 1999, 122: 290 | [8] | Lin J L, Moore J J, Sproul W D, et al. The structure and properties of chromium nitride coatings deposited using dc, pulsed dc and modulated pulse power magnetron sputtering [J]. Surf. Coat. Technol., 2010, 204: 2230 | [9] | Aiempanakit M, Kubart T, Larsson P, et al. Hysteresis and process stability in reactive high power impulse magnetron sputtering of metal oxides [J]. Thin Solid Films, 2011, 519: 7779 | [10] | Li C W, Tian X B. Novel high power impulse magnetron sputtering enhanced by an auxiliary electrical field [J]. Rev. Sci. Instrum., 2016, 87: 083507 | [11] | Anders A. Deposition rates of high power impulse magnetron sputtering: Physics and economics [J].J. Vac. Sci. Technol., 2010, 28A: 783 | [12] | Brenning N, Huo C, Lundin D, et al. Understanding deposition rate loss in high power impulse magnetron sputtering: I. Ionization-driven electric fields [J]. Plasma Sources Sci. Technol., 2012, 21: 025005 | [13] | Paulitsch J, Schenkel M, Schintlmeister A, et al. Low friction CrN/TiN multilayer coatings prepared by a hybrid high power impulse magnetron sputtering/DC magnetron sputtering deposition technique [J]. Thin Solid Films, 2010, 518: 5553 | [14] | Luo Q, Yang S, Cooke K E. Hybrid HIPIMS and DC magnetron sputtering deposition of TiN coatings: Deposition rate, structure and tribological properties [J]. Surf. Coat. Technol., 2013, 236: 13 | [15] | Stranak V, Drache S, Bogdanowicz R, et al. Effect of mid-frequency discharge assistance on dual-high power impulse magnetron sputtering [J]. Surf. Coat. Technol., 2012, 206: 2801 | [16] | Lu C Y, Diyatmika W, Lou B S, et al. Influences of target poisoning on the mechanical properties of TiCrBN thin films grown by a superimposed high power impulse and medium-frequency magnetron sputtering [J]. Surf. Coat. Technol., 2017, 332: 86 | [17] | Wu Z Z, Tian X B, Pan F, et al. High power pulsed magnetron sputtering discharge behavior of various target materials [J]. Acta Metall. Sin., 2014, 50: 1279 | [17] | 吴忠振, 田修波, 潘 锋等. 不同靶材料的高功率脉冲磁控溅射放电行为 [J]. 金属学报, 2014, 50: 1279 | [18] | Anders A, Andersson J, Ehiasarian A. High power impulse magnetron sputtering: Current-voltage-time characteristics indicate the onset of sustained self-sputtering [J]. J. Appl. Phys., 2007, 102: 113303 | [19] | Wu Z Z, Tian X B, Li C W, et al. Phasic discharge characteristics in high power pulsed magnetron sputtering [J]. Acta Phys. Sin., 2014, 63: 175201 | [19] | 吴忠振, 田修波, 李春伟等. 高功率脉冲磁控溅射的阶段性放电特征 [J]. 物理学报, 2014, 63: 175201 | [20] | Li X C, Ke P L, Liu X C, et al. Discharge characteristics of Ti and film preparation using hybrid high power impulse magnetron sputtering [J]. Acta Metall. Sin., 2014, 50: 879 | [20] | 李小婵, 柯培玲, 刘新才等. 复合高功率脉冲磁控溅射Ti的放电特性及薄膜制备 [J]. 金属学报, 2014, 50: 879 | [21] | Lin J L, Moore J J, Sproul W D, et al. Modulated pulse power sputtered chromium coatings [J]. Thin Solid Films, 2009, 518: 1566 | [22] | Konstantinidis S, Dauchot J P, Ganciu M, et al. Transport of ionized metal atoms in high-power pulsed magnetron discharges assisted by inductively coupled plasma [J]. Appl. Phys. Lett., 2006, 88: 021501 | [23] | Tiron V, Velicu I L, Mih?il? I, et al. Deposition rate enhancement in HiPIMS through the control of magnetic field and pulse configuration [J]. Surf. Coat. Technol., 2018, 337: 484 | [24] | Konstantinidis S, Dauchot J P, Ganciu M, et al. Influence of pulse duration on the plasma characteristics in high-power pulsed magnetron discharges [J]. J. Appl. Phys., 2006, 99: 013307 | [25] | Li C W, Tian X B, Gong C Z, et al. The improvement of high power impulse magnetron sputtering performance by an external unbalanced magnetic field [J]. Vacuum, 2016, 133: 98 | [26] | Oliveira J C, Fernandes F, Serra R, et al. On the role of the energetic species in TiN thin film growth by reactive deep oscillation magnetron sputtering in Ar/N2 [J]. Thin Solid Films, 2018, 645: 253 | [27] | Guimaraes M C R, de Castilho B C N M, de Souza Nossa T, et al. On the effect of substrate oscillation on CrN coatings deposited by HiPIMS and dcMS [J]. Surf. Coat. Technol., 2018, 340: 112 | [28] | Wang Z Y, Xu S, Zhang D, et al. Influence of N2 flow rate on structures and mechanical properties of TiSiN coatings prepared by HIPIMS method [J]. Acta Metall. Sin., 2014, 50: 540 | [28] | 王振玉, 徐 胜, 张 栋等. N2流量对HIPIMS制备TiSiN涂层结构和力学性能的影响 [J]. 金属学报, 2014, 50: 540 | [29] | Ferreira F, Serra R, Cavaleiro A, et al. Additional control of bombardment by deep oscillation magnetron sputtering: Effect on the microstructure and topography of Cr thin films [J]. Thin Solid Films, 2016, 619: 250 | [30] | Lin J, Sproul W D, Moore J J, et al. Effect of negative substrate bias voltage on the structure and properties of CrN films deposited by modulated pulsed power (MPP) magnetron sputtering [J]. J. Phys., 2011, 44D: 425305 | [31] | Yang C, Jiang B L, Feng L, et al. Effect of discharge characteristics of target on ionization and deposition of deposited particles [J]. Acta Metall. Sin., 2015, 51: 1523 | [31] | 杨 超, 蒋百灵, 冯 林等. 靶面放电特性对沉积粒子离化率及沉积行为的影响 [J]. 金属学报, 2015, 51: 1523 | [32] | Kong Y, Ma Y H, Li Y J, et al. Microstructure and surface properties of TiCN films using cathodic arc deposition enhanced by additional electric field [J]. Rare Met. Mater. Eng., 2017, 46: 1026 | [32] | 孔 营, 马英鹤, 李永健等. 电场增强的阴极弧放电TiCN薄膜结构及性能研究 [J]. 稀有金属材料与工程, 2017, 46: 1026 | [33] | Burton A W, Ong K, Rea T, et al. On the estimation of average crystallite size of zeolites from the Scherrer equation: A critical evaluation of its application to zeolites with one-dimensional pore systems [J]. Microporous Mesoporous Mater., 2009, 117: 75 | [34] | Ibrahim K, Rahman M M, Zhao X L, et al. Annealing effects on microstructural, optical, and mechanical properties of sputtered CrN thin film coatings: Experimental studies and finite element modeling [J]. J. Alloys Compd., 2018, 750: 451 | [35] | Elmkhah H, Zhang T F, Abdollah-Zadeh A, et al. Surface characteristics for the Ti-Al-N coatings deposited by high power impulse magnetron sputtering technique at the different bias voltages [J]. J. Alloys Compd., 2016, 688: 820 | [36] | Ganesan R, Akhavan B, Dong X, et al. External magnetic field increases both plasma generation and deposition rate in HiPIMS [J]. Surf. Coat. Technol., 2018, 352: 671 |
|
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|