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Acta Metall Sin  1993, Vol. 29 Issue (10): 87-91    DOI:
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ON OF TEXTURAL YBa_2Cu_3O_(7-x) WITH NOMINAL COMPOSITION (123+211) BY LIQUID PHASE SINTERING
FAN Yongnian;TANG Baozhen;QIAO Guiwen International Centre of Materials Physics; Institute of Metal Research; Academia Sinica; Shenyang Institute of Metal Research; Academia Sinica; Shenyang
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FAN Yongnian;TANG Baozhen;QIAO Guiwen International Centre of Materials Physics; Institute of Metal Research; Academia Sinica; Shenyang Institute of Metal Research; Academia Sinica; Shenyang. ON OF TEXTURAL YBa_2Cu_3O_(7-x) WITH NOMINAL COMPOSITION (123+211) BY LIQUID PHASE SINTERING. Acta Metall Sin, 1993, 29(10): 87-91.

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Abstract  To eliminate the deposition along BaCuO_2 grain boundaries, the 211(Y_2Ba_2CuO_5) powder was properly doped to the 123 (YBa_2Cu_3O_(7-x) compounds. Sufficienttime for mass transfer along a-b plane was allowed by lowering the cooling rate nearby thetemperature of peritectic transformation. Since the plane a-b is the fastest growing one, thelength of grains is controlled by the rate of mass transfer. XRD, SEM and EDXA analysesrevealed that the grains are strip-shaped, their orientation is perpendicular to c-axis and par-allel to surface a-b plane. Thus, the compound 123 (YBa_2Cu_3O_(7-x) has a strong texturalstructure.
Key words:  liquid phase sintering      texture      peritectic transformation      YBa_2Cu_3O_(7-x)      Y_2Ba_2CuO_5      directional solidification     
Received:  18 October 1993     
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