CORRELATION BETWEEN THE GLASS-FORMING ABILITY AND CHARACTERISTIC FREE VOLUMES OF THE IRON BASE BULK METALLIC GLASSES

doi:10.3724/SP.J.1037.2012.00417

Acta Metall Sin

2012, Vol. 48

Issue (11): 1329-1334 DOI: 10.3724/SP.J.1037.2012.00417

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CORRELATION BETWEEN THE GLASS-FORMING ABILITY AND CHARACTERISTIC FREE VOLUMES OF THE IRON BASE BULK METALLIC GLASSES

HU Qiang¹⁾, ZENG Xierong^2,3), QIAN Haixia^2,3), XIE Shenghui^2,3), SHENG Hongchao^2,3)

1) School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072
2) College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060
3) Shenzhen Key Laboratory of Special Functional Materials, Shenzhen 518060

Cite this article:

HU Qiang ZENG Xierong QIAN Haixia XIE Shenghui SHENG Hongchao. CORRELATION BETWEEN THE GLASS-FORMING ABILITY AND CHARACTERISTIC FREE VOLUMES OF THE IRON BASE BULK METALLIC GLASSES. Acta Metall Sin, 2012, 48(11): 1329-1334.

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Abstract

Many researches have demonstrated that the free volume have a great effect on the properties of bulk metallic glasses (BMGs). For different BMGs, however, quantitative measurement of free volumes and analysis of properties of BMGs using the measurement results are still difficult. In this work, the two types of characteristic free volumes, the free volume released in structural relaxation, ΔV_f-sr and the free volume generated in glass transition, ΔV_f-gt are given from the Δ(dV(T)/V₀) curve, where the Δ(dV(T)/V₀) is the thermal expansion difference between amorphous and crystalline samples measured by a cyclic thermal dilation test. In a series of Fe-(Er)-Cr-Mo-C-B BMGs, it is found that the BMG with the largest critical diameter (D_c) has also the largest ΔV_f-gt, and D_cincreases sensitively with the decrease of ΔV_f-sr. More impressively, D_c² or D_c can be fitted with high regression coefficient of 0.998 by a negative exponential function of ΔV_f-sr. Hence, the characteristic free volume has a sensitive and close correlation with the glass forming ability of BMGs.

Key words: bulk metallic glass free volume structural relaxation glass transition glass-forming ability thermal dilation

Received: 11 July 2012

ZTFLH:	TG115.25
	TG111.4
	TG113.22

Fund:

Supported by Science and Technology Foundation of Shenzhen (No.CXB200903090012A) and Two Hundred Plan for Talent Station
of Shenzhen (No.182)

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https://www.ams.org.cn/EN/10.3724/SP.J.1037.2012.00417 OR https://www.ams.org.cn/EN/Y2012/V48/I11/1329

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