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CHARACTERISTIC TEMPERATURE AND PERFOR-MANCE OF THE Ge30Se70 CHALCOGENIDE GLASS |
Tingting JIA,Zengyun JIAN,Junfeng XU,Man ZHU,Fang'e CHANG |
School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China |
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Cite this article:
Tingting JIA,Zengyun JIAN,Junfeng XU,Man ZHU,Fang'e CHANG. CHARACTERISTIC TEMPERATURE AND PERFOR-MANCE OF THE Ge30Se70 CHALCOGENIDE GLASS. Acta Metall Sin, 2016, 52(6): 755-760.
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Abstract Chalcogenide glass is an ideal infrared wave-transparent material, and it has the advantages of low cost, high production efficiency, high glass transition temperature and good mechanical properties, etc.. It is a candidate material for thermal imaging system. The block sample of Ge30Se70 chalcogenide glass was prepared by the method of the melt-quenched. In this work, XRD was used to determine whether the sample was amorphous material. With the DSC thermal analysis method, the glass transition temperature Tg and the initial crystallization temperature Tx of the sample were measured. The dynamics ideal glass transition temperature T0 of the specimen was fitted by VFT equation. The method of segmented step heating is used to analyze the calorific value for the glass and congruent crystal of Ge30Se70 sample in setting temperature range. Then from the calculated calorific values of the glass and crystalline samples, the specific heat capacity relationships were obtained, i.e., cp,l=0.0002T+0.3337 and cp,c=0.00006T+0.4594. The results show that Tg and T0 of Ge30Se70 sample is 590 and 581 K, respectively. And Tg will increase with the increasing of the heating rate R. The average value of the specific heat capacity of the Ge30Se70 glass sample is about 11.8 J/(molK) below the glass transition temperature. The infrared transmittance is about 60% indicating that the infrared performance is good. The glass reduced temperature Trg of Ge30Se70 sample is between 0.5~0.667, and the nucleation rate is very low, which indicates that the glass forming ability of Ge30Se70 glass is good.
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Received: 25 September 2015
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Fund: Supported by National Basic Research Program of China (No.2013CB632904), National Natural Science Foundation of China (Nos.51371133, 51171136, 51301125 and 51401156), Natural Science Foundation of Shaanxi Province (Nos.2012JM6010 and 2014- JM6225) and Key Laboratory Research Project of Shaanxi Provincial Education Department (No.13JS041) |
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