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Acta Metall Sin  2021, Vol. 57 Issue (4): 425-438    DOI: 10.11900/0412.1961.2020.00431
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Structural Rejuvenation of Metallic Glasses and Its Effect on Mechanical Behaviors
JIANG Minqiang1,2(), GAO Yang1,2
1.State Key Laboratory of Nonlinear Mechanics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China
2.School of Engineering Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
Cite this article: 

JIANG Minqiang, GAO Yang. Structural Rejuvenation of Metallic Glasses and Its Effect on Mechanical Behaviors. Acta Metall Sin, 2021, 57(4): 425-438.

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Abstract  

Metallic glasses (MGs) are formed by the deep undercooling of high-temperature melt up to the glass transition temperature, and this process avoids the crystallization of the melt into ordered configurations of atoms. The atomic packing of MGs lacks a long-range periodicity. MGs reside at metastable energy states far away from the equilibrium of thermodynamics, but they are jammed in dynamics. These features provide MGs with remarkable mechanical, physical, and chemical properties, such as very high strength that is close to the ideal limit. However, the plastic deformation of MGs at room temperature is easily localized to form nanoscale shear bands, thereby resulting in limited macroscopic plasticity. Moreover, physical ageing spontaneously reduces their energies toward an equilibrium state, thereby further weakening the plastic deformation ability of MGs, which is known as ageing-induced brittleness. Recent studies have shown that MGs can be rejuvenated with external energy injection into more disordered high-energy states in structure. This process, which is the inverse of physical ageing, can effectively improve the global plasticity of MGs and is expected to solve the problems of shear banding and physical ageing that restrict the applications of such materials. Therefore, the relevant aspects of the rejuvenation of MGs have attracted increasing interest. This article first introduces methods for the rejuvenation of MGs starting from the concepts of ageing and rejuvenation of glasses, and then summarizes the influencing factors of rejuvenation and the effects of rejuvenation on plasticity and other mechanical behaviors of MGs. Furthemore, the physical mechanism of rejuvenation is discussed briefly. Finally, several conclusions are drawn in this field, and some important problems that deserve further investigation are proposed.

Key words:  metallic glass      structural relaxation      rejuvenation      shear band      mechanical behavior     
Received:  30 October 2020     
ZTFLH:  TG139  
Fund: National Natural Science Foundation of China (NSFC)(11972345);NSFC Basic Science Center for “Multiscale Problems in Nonlinear Mechanics”(11988102)
About author:  JIANG Minqiang, professor, Tel: (010)82544089, E-mail: mqjiang@imech.ac.cn

URL: 

https://www.ams.org.cn/EN/10.11900/0412.1961.2020.00431     OR     https://www.ams.org.cn/EN/Y2021/V57/I4/425

Fig.1  Schematic diagram of thermodynamic enthalpy or entropy evolution of alloy melts during crystallization (route 1), supercooling-glass transition (route 2), physical ageing (route 3) and rejuvenation (route 4) (Tg—glass transition temperature, Tm—melting point, TK—Kauzmann temperature, high-T—high temperature)
Fig.2  Schematic diagram of specific heat capacity curves of the initial and relaxed samples
Fig.3  Ultrafast rejuvenation of metallic glasses via a double-target plate impact technique (a) and the stress wave design (b) (PMMA—poly(methyl methacrylate), PVD—physical vapour deposition, C1—a forward compressive wave, C2—a backward compressive wave, R1—a release wave that is the reflection of C1 at the free surface of the back target, R2—the release (unloading) wave that is the reflection of C2 at the free surface of the flyer, Δt—the duration, σp—the stress amplitude)[99]
Fig.4  The effect of load amplitude on structural rejuvenation of a Zr-based metallic glass under shock compression (ΔHrel—excess relaxation enthalpy, HEL—Hugoniot elastic limit)[99]
Fig.5  Influence of loading time on rejuvenation of two Cu-Zr metallic glasses under elastostatic compression[62]
Fig.6  Plasticity modification of metallic glasses based on rejuvenation methods
Fig.7  Effects of the rejuvenation on relative elastic modulus (Y / Y0) (a)[126], hardness (b)[99], initial yield pressure (c)[125], and plastic deformation (d)[105] of metallic glasses
Fig.8  Boson peaks of the as-cast and rejuvenated Zr-based metallic glasses (a)[99], and the correlation between Boson peak height (HBP) and structural enthalpy (b) and fictive temperature (c) (BP—Boson peak, cp—specific heat capacity, γ—Sommerfeld coefficient, T—temperature, Tf—fictive temperature)[74]
Fig.9  Relaxation dynamical behaviors of structural rejuvenation of metallic glasses (E''—the loss modulus, Eα—the loss modulus of α-peak, Γ—relaxation rate)
Fig.10  Structural characterization of the rejuvenated structures of a Zr-based metallic glass, including HRTEM observations and SAED patterns (insets) (a-d) and radial distribution functions G(r) (r—radius) (e)[99]
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