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金属学报  2026, Vol. 62 Issue (8): 1376-1384    DOI: 10.11900/0412.1961.2024.00158
  研究论文 本期目录 | 过刊浏览 |
超声功率对W90/Sn/Mg接头微观组织和力学性能的影响
张旭东1,2, 付伟1,2(), 宋晓国1,2, 宋娜3, 孙浩2, 胡胜鹏1,2
1 哈尔滨工业大学 材料科学与工程学院 哈尔滨 150001
2 哈尔滨工业大学(威海) 材料科学与工程学院 威海 264209
3 中国航发西安动力控制科技有限公司 西安 710000
Effect of Ultrasonic Power on the Microstructure and Mechanical Property of W90/Sn/Mg Joint
ZHANG Xudong1,2, FU Wei1,2(), SONG Xiaoguo1,2, SONG Na3, SUN Hao2, HU Shengpeng1,2
1 School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
2 School of Materials Science and Engineering, Harbin Institute of Technology (Weihai), Weihai 264209, China
3 Aero-China Xi'an Power Control Technology Co. Ltd. , Xi'an 710000, China
引用本文:

张旭东, 付伟, 宋晓国, 宋娜, 孙浩, 胡胜鹏. 超声功率对W90/Sn/Mg接头微观组织和力学性能的影响[J]. 金属学报, 2026, 62(8): 1376-1384.
Xudong ZHANG, Wei FU, Xiaoguo SONG, Na SONG, Hao SUN, Shengpeng HU. Effect of Ultrasonic Power on the Microstructure and Mechanical Property of W90/Sn/Mg Joint[J]. Acta Metall Sin, 2026, 62(8): 1376-1384.

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摘要: 

为了实现W90钨合金与AZ31B镁合金的低温钎焊,本工作采用纯Sn作为钎料,通过SEM及EDS对不同超声功率下钎焊接头的界面微观组织进行了表征和分析,并对钎焊接头的抗剪强度进行测试,探究了超声功率对接头界面组织及力学性能的影响。结果表明,W90/Sn界面结合良好,焊缝中包含基体相β-Sn和Mg2Sn化合物,Mg/Sn界面生成一层Mg2Sn化合物。随着超声功率增加,焊缝宽度减小,Mg2Sn层厚度增加,接头抗剪强度先增大后减小。当超声功率为100和150 W时,接头的抗剪强度达到最大值10.5 MPa。超声辅助钎焊过程液态Sn声压分布的模拟结果表明,在1个超声周期内,液态Sn中的声压周期性地从负值变为正值,再变为负值。空化泡崩溃时产生高温、高压、微射流和冲击波等空化效应。理论计算结果表明,随着超声功率增加,液态Sn的声压幅值增加,产生的空化效应更剧烈。

关键词 钨合金镁合金超声辅助钎焊Sn空化效应    
Abstract

Tungsten alloy, known for its high hardness, thermal stability, and excellent nuclear radiation shielding performance, is a critical material for radiation shielding applications. It is widely used in aerospace, national defense, and medical fields. However, tungsten alloy has drawbacks such as high density and processing difficulty, which limit its applicability in high-efficiency, miniaturized, and lightweight designs, particularly in nuclear medical treatment and nuclear-powered flight devices. A double-layered W/Mg structure is expected to serve as a next-generation nuclear radiation shielding material. Due to the significant differences in melting temperatures and coefficients of thermal expansion between W and Mg, conventional soldering methods are ineffective for joining them. In this study, a W90 tungsten heavy alloy and AZ31B magnesium alloy were successfully bonded using an ultrasonic-assisted soldering method with pure Sn. The bonding temperature was 250 oC, and the ultrasonic duration was 4 s. The interfacial microstructure of the W90/Sn/Mg joint under varying ultrasonic power levels was analyzed using SEM and EDS. Additionally, the shear strength of the joint was tested to assess the impact of ultrasonic power on interfacial bonding and mechanical performance. The results indicated that effective bonding formed at the W90/Sn interface, with Ni3Sn4 compounds appearing between the (Ni, Fe) matrix and Sn. The seam consisted of a β-Sn matrix phase and Mg2Sn compounds, with an Mg2Sn layer forming on Mg/Sn interface. As ultrasonic power increased, joint width decreased while the Mg2Sn layer thickness increased. The shear strength of the joint initially increased with ultrasonic power but later decreased. At ultrasonic power levels of 100 and 150 W, the joint strength reached a maximum of 10.5 MPa, with failure occurring at the W90/Sn interface. When ultrasonic power increased to 200 W, joint strength declined, and fracture occurred at the Mg2Sn layer. The acoustic pressure distribution of liquid Sn during the ultrasonic-assisted soldering process was simulated. During a single ultrasonic cycle, the acoustic pressure of liquid Sn oscillated periodically from negative to positive and back to negative values. The maximum acoustic pressure was observed at the center of the liquid Sn, gradually decreasing toward the edges. The cavitation effect, driven by collapsing bubbles, generated high temperatures, high pressures, micro-jets, and shock waves, as explained through theoretical calculations. Based on the Keller-Miksis equation, as ultrasonic power increased, the ratio of the cavitation bubble radius to its initial radius increased from 16.3 to 47.7, with collapse velocities ranging from 3262 m/s to 6985 m/s. According to the Noltingk-Neppiras theory, as acoustic pressure increased, cavitation-induced temperatures rose from 14614 K to 24989 K, while pressure increased from 1.08 × 105 MPa to 9.45 × 105 MPa. The generated temperature and pressure were sufficient to break the Mg alloy’s oxide film and promote interfacial reactions.

Key wordstungsten alloy    magnesium alloy    ultrasonic-assisted soldering    Sn    cavitation effect
收稿日期: 2024-05-13     
ZTFLH:  TG456  
基金资助:国家自然科学基金项目(52105330);国家自然科学基金项目(52175307);山东省自然科学基金项目(ZR2023JQ021)
通讯作者: 付 伟,wei.fu@hit.edu.cn,主要从事异种材料钎焊研究
Corresponding author: FU Wei, professor, Tel: (0631)5687454, E-mail: wei.fu@hit.edu.cn
作者简介: 张旭东,男,1994年生,博士
图1  超声辅助钎焊装置示意图
图2  100 W超声功率下W90/Sn/Mg接头横截面微观组织的SEM像及EDS分析(a) typical interface microstructure(b-f) EDS mappings of W (b), Ni (c), Fe (d), Sn (e), and Mg (f)(g, h) EDS line scanning results along lines ab (b) and cd (c) in Fig.2a
PositionSnMgWNiFePhase type
A'0.010.0310.5464.2325.19(Ni, Fe) phase
B'99.820.110.020.030.02β-Sn
C'30.9868.970.010.030.01Mg2Sn
D'29.3070.650.010.030.01Mg2Sn
表1  图2中标记点的化学成分及相种类 (atomic fraction / %)
图3  不同超声功率下W90/Sn/Mg钎焊接头微观组织的SEM像(a) 50 W (b) 150 W (c) 200 W
图4  超声功率对W90/Sn/Mg接头抗剪强度的影响
图5  不同超声功率下接头断口截面和表面的SEM像
图6  9 cyc内液态Sn中声压变化(a) 400 μs (b) 410 μs (c) 415 μs (d) 425 μs(e) 430 μs (f) 435 μs (g) 445 μs (h) 450 μs
图7  0~12 cyc内特征点A与B声压值对比(a) coordinates of points A and B(b) acoustic pressure distribution
图8  空化泡动力学分析(a) Solution R(t) / R0 within two acoustic periods (R(t)—radius of cavitation bubble at time t, R0—initial radius of cavitation bubble)(b) collapse velocities (dR / dt) of the bubble wall(c) variations of temperature (T) with t of bubble collapse(d) variations of pressure (P1) with t of bubble collapse
图9  超声功率对特征点A声压的影响
图10  接头形成机理图(a) heating process (b) applying ultrasound (c) cavitation effect(d) elemental diffusion (e) turning off ultrasound (f) cooling process
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