定向凝固Al－12%Ni过共晶合金组织演化

doi:10.3724/SP.J.1037.2012.00549

金属学报

2013, Vol. 49

Issue (3): 311-319 DOI: 10.3724/SP.J.1037.2012.00549

论文

本期目录 | 过刊浏览

定向凝固Al－12%Ni过共晶合金组织演化

彭鹏，李新中，刘冬梅，苏彦庆，郭景杰，傅恒志

哈尔滨工业大学材料科学与工程学院, 哈尔滨 150001

MICROSTRUCTURE EVOLUTION OF DIRECTIONALLY SOLIDIFIED Al－12%Ni HYPEREUTECTIC ALLOY

PENG Peng, LI Xinzhong, LIU Dongmei, SU Yanqing, GUO Jingjie, FU Hengzhi

School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001

引用本文:

彭鹏，李新中，刘冬梅，苏彦庆，郭景杰，傅恒志. 定向凝固Al－12%Ni过共晶合金组织演化[J]. 金属学报, 2013, 49(3): 311-319.
PENG Peng, LI Xinzhong, LIU Dongmei, SU Yanqing, GUO Jingjie, FU Hengzhi. MICROSTRUCTURE EVOLUTION OF DIRECTIONALLY SOLIDIFIED Al－12%Ni HYPEREUTECTIC ALLOY[J]. Acta Metall Sin, 2013, 49(3): 311-319.

全文: PDF(1251 KB)

摘要:

通过Bridgman定向凝固技术对Al－12%Ni(质量分数)过共晶合金在1－100 μm/s的生长速率范围内进行恒速定向凝固以及不同初始生长条件和变速比下的跃迁加速定向凝固实验, 获得耦合共晶组织的条件. 研究发现, 生长速率为1 μm/s时, 经过一定距离生长后, 组织中无单独生长的初生相, 获得耦合共晶组织; 而当生长速率为2－100 μm/s时, 初生Al₃Ni相领先生长且呈现典型小平面生长特性. 跃迁加速实验表明, 跃迁加速前的初始组织对最终组织有决定性影响, 只有当跃迁前的组织中无单独生长的初生相时, 跃迁后才可在较高生长速率下获得耦合共晶组织. 同时定向凝固可以有效提高Al－12%Ni合金的强度和塑性, 跃迁加速获得的耦合共晶组织延伸率也得到进一步提高.

关键词 ：共晶合金, 定向凝固, 组织演化, 凝固机制

Abstract：

The Al－12%Ni (mass fraction) hypereutectic alloy from pure Ni and Al (99.9%) was induction melted and directionally solidified at constant growth rates ranging from 1 μm/s to 100 μm/s and abrupt change of growth rate were carried out in a Bridgman－type furnace. After solidification, the samples were quickly quenched into liquid Ga－In－Sn alloy to preserve the microstructure. The microstructures of the samples were observed using OM and SEM. It was indicated that at a growth rate of 1 μm/s, after experiencing a certain growth distance, the primary Al₃Ni phase disappeared and the coupled growth of eutectic could be obtained. The morphology of Al₃Ni phase was faceted when it was the leading phase at growth rates from 2 μm/s to 100 μm/s. The result of experiments with abrupt change of growth rate indicate that the initial microstructure before abrupt change of growth rate determine the microstructure after abrupt change of growth rate. Only if there existed no coarse primary Al₃Ni phase before abrupt change of growth rate could entirely coupled eutectic structure be obtained at relatively higher growth rates. After abrupt change of growth rate, the growth of primary Al₃Ni phase was suppressed and the coupled eutectic could grow continuously without any coarse primary phases. The strength and plasticity could be improved effectively through directional solidification.Besides, the elongation of Al－12%Ni alloy could be greatly improved by the abrupt change of growth rate during directional solidification.

Key words： eutectic alloy directional solidification microstructure evolution solidification mechanism

收稿日期: 2012-09-14

基金资助:

国家自然科学基金项目51071062, 51274077 和51271068, 国家重点基础研究发展计划项目2011CB610406, 中央高校基本科研业务费项目HIT.NSRIF.2013002及华中科技大学模具技术国家重点实验室开放基金项目2011－P03资助

作者简介: 彭鹏, 男, 1985年生, 博士生

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https://www.ams.org.cn/CN/10.3724/SP.J.1037.2012.00549 或 https://www.ams.org.cn/CN/Y2013/V49/I3/311

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