医用镁合金：成分、组织及腐蚀

doi:10.11900/0412.1961.2018.00032

金属学报

2018, Vol. 54

Issue (9): 1215-1235 DOI: 10.11900/0412.1961.2018.00032

本期目录 | 过刊浏览

医用镁合金：成分、组织及腐蚀

曾荣昌¹(

), 崔蓝月¹, 柯伟²

1 山东科技大学材料科学与工程学院青岛 266590
2 中国科学院金属研究所沈阳 110016

Biomedical Magnesium Alloys: Composition, Microstructure and Corrosion

Rongchang ZENG¹(

), Lanyue CUI¹, Wei KE²

1 College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China
2 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;

引用本文:

曾荣昌, 崔蓝月, 柯伟. 医用镁合金：成分、组织及腐蚀[J]. 金属学报, 2018, 54(9): 1215-1235.
Rongchang ZENG, Lanyue CUI, Wei KE. Biomedical Magnesium Alloys: Composition, Microstructure and Corrosion[J]. Acta Metall Sin, 2018, 54(9): 1215-1235.

全文: PDF(4210 KB) HTML

摘要:

镁合金具有良好的生物相容性和力学相容性,具有发展成为新一代可降解生物材料的前景。本文总结了医用镁合金合金化的原理与进展,分析了合金元素对镁合金材料学以及生物学性能的影响,重点讨论了医用镁合金显微组织(晶粒尺寸、第二相、长周期堆垛有序相(LPSO)、准晶相)、热处理和表面氧化膜对其降解行为的影响和腐蚀形态、机理方面的重要进展,并指出了医用镁合金的发展方向。

关键词 ：镁合金, 合金化, 第二相, 腐蚀, 生物材料

Abstract：

Magnesium alloys, with good biocompatibility and mechanical-compatibility, can be developed as next generation promising biomaterials. This paper summerizes the principle and the cutting-edge advances of alloying of magnesium alloys as degradable biomaterials. The effects of alloy elements on the material and biological properties of magnesium alloys are analyzed. The focus is laid on the influence of microstructure (grain size, secondary phase or intermetallic compound, long-period stacking ordered (LPSO) phase and quasi-crystal phase), heat treatment and surface oxide film on degradation and their critical progress on corrosion morphology and mechanism. Several outlooks on bio-magnesium alloys are proposed.

Key words： magnesium alloy alloying second phase corrosion biomaterial

收稿日期: 2018-01-22

ZTFLH:

TG406

基金资助:国家自然科学基金项目No.51571134和山东科技大学校级科研创新团队支持计划经费项目No.2014TDJH104

作者简介:

作者简介曾荣昌,男,1964年生,教授

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https://www.ams.org.cn/CN/10.11900/0412.1961.2018.00032 或 https://www.ams.org.cn/CN/Y2018/V54/I9/1215

图1 挤压镁合金ZK60腐蚀电流密度与晶粒尺寸的关系

图2 晶粒尺寸和孪晶对轧制AZ31合金自腐蚀电流密度的影响

图3 Mg-Al-Gd合金腐蚀机制示意图[102]

图4 铸态双相Mg-Li合金腐蚀示意图[115]

图5 在双相Mg-Li-Ca合金表面氧化膜的形成机理模拟示意图[35]

图6 双相Mg-Li-Ca合金腐蚀机理示意图[35]

图7 挤压镁合金AM60的点蚀模型[62]

图8 镁合金ZK60显微组织、晶间腐蚀形貌及晶间腐蚀模型[50]

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