The Role of Sn Substitution for Si And B to Enhance the Amorphization of Mechanically-Milled Ti50Ni22Cu18Al4Si4B2 Alloy

Acta Metall Sin

2004, Vol. 40

Issue (9): 981-986 DOI:

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The Role of Sn Substitution for Si And B to Enhance the Amorphization of Mechanically-Milled Ti50Ni22Cu18Al4Si4B2 Alloy

ZHANG Laichang; SHEN Zhiqi; XU Jian

Shenyang National Laboratory for Materials Science; Institute of Metal Research; The Chinese Academy of Sciences; Shenyang 110016

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ZHANG Laichang; SHEN Zhiqi; XU Jian. The Role of Sn Substitution for Si And B to Enhance the Amorphization of Mechanically-Milled Ti50Ni22Cu18Al4Si4B2 Alloy. Acta Metall Sin, 2004, 40(9): 981-986 .

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Abstract Elements Si and B in the Ti50Ni22Cu18Al4Si4B2 alloy are substituted with Sn to form the Ti50Ni22Cu18Al4Snx(Si0.67B0.33)6-x (x=0,3,6) series alloys. In all cases, mechanical milling of the prealloyed fragments results in the amorphization of the alloys. With increasing the Sn content in the alloys, the fraction of residual α-Ti crystallites in the final milled product was reduced. For the Ti50Ni22Cu18Al4Sn6 alloy, in which the Si and B are completely replaced with Sn, the nearly complete amorphization is achievable. A single amorphous phase, similar to the melt-quenched glass, formed in the milled alloy. Such a ball-milled glassy alloy exhibits a large supercooled liquid region about 66 K.

Key words: titanium alloy mechanical alloying amorphous alloy

Received: 05 April 2004

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TG139.8

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	ZHANG Laichang
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https://www.ams.org.cn/EN/ OR https://www.ams.org.cn/EN/Y2004/V40/I9/981

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