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Acta Metall Sin  2021, Vol. 57 Issue (3): 283-294    DOI: 10.11900/0412.1961.2020.00165
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Research Progress on Corrosion Behavior of Gaseous CO2 Transportation Pipelines Containing Impurities
LI Yuxing1,2(), LIU Xinghao1,2, WANG Cailin1,2, HU Qihui1,2, WANG Jinghan1,2, MA Hongtao1,2, ZHANG Nan1,2
1.Provincial Key Laboratory of Oil and Gas Storage and Transportation Security, China University of Petroleum (East China), Qingdao 266580, China
2.Key Laboratory of Oil & Gas Storage and Transportation, PetroChina Company Limited, Qingdao 266580, China
Cite this article: 

LI Yuxing, LIU Xinghao, WANG Cailin, HU Qihui, WANG Jinghan, MA Hongtao, ZHANG Nan. Research Progress on Corrosion Behavior of Gaseous CO2 Transportation Pipelines Containing Impurities. Acta Metall Sin, 2021, 57(3): 283-294.

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Abstract  

Gaseous CO2 transportation pipelines are an important part of carbon capture and storage. Corrosion control of gaseous CO2 transportation pipelines containing impurities is important to the safe operation of pipelines. This paper reviews recent research progress on the corrosion of gaseous CO2 transportation pipelines containing impurities, and the impact factors of gaseous CO2 transportation pipelines are summarized. The influence of pipe impurities and environmental conditions on the mutual solubility of water and CO2, the corrosion behavior of pipelines, the characteristic of corrosion scales, and corrosion mechanism of transportation pipelines are discussed. The determination of critical water content for the corrosion of gaseous CO2 transportation pipelines is analyzed. Predictive corrosion models of gaseous CO2 transportation pipelines are also concluded. For further research on corrosion of gaseous CO2 transportation pipelines containing impurities, the following should be the focal points: the calculation of water and CO2 mutual solubility in gaseous CO2 environments containing impurities, the influence of impurities on corrosion product film characteristics and the corrosion mechanism in a gaseous CO2 environment, the determination of the critical water content of corrosion for gaseous CO2 transportation pipelines containing impurities, and the establishment of inner corrosion prediction models of gaseous CO2 transportation pipelines containing impurities.

Key words:  gaseous CO2 transportation      corrosion      impurity      mutual solubility      critical water content      corrosion prediction model     
Received:  18 May 2020     
ZTFLH:  TE988  
Fund: National Science and Technology Major Project(2016ZX05016-002);Key Laboratory of Oil & Gas Storage and Transportation, PetroChina(GDGS-KJZX-2016-JS-379)

URL: 

https://www.ams.org.cn/EN/10.11900/0412.1961.2020.00165     OR     https://www.ams.org.cn/EN/Y2021/V57/I3/283

Fig.1  Phase diagram of pure CO2
Steel

Temperature

oC

Pressure

MPa

H2O contentH2S contentO2 content

Corrosion rate

mm·a-1

Carbon steel[35]402Saturated0.1 MPa00.6223
Carbon steel[35]602Saturated1 MPa00.7706
X65[36]505Saturated000.0186
1000 × 10-60.0435
X65 (Ni-P coating)[36]505Saturated00~0
1000 × 10-60.0093
X65[37]504Saturated00~0.2
6~0.2
X65[38]501Saturated00~1
X65[39]243Saturated001.3077
X70[40]501Saturated000.025
3Cr steel[41]601Saturated000.22
0.950.05 MPa1.36
Low-alloy steel[42]751.2Saturated000.18
Carbon steel[43]603Saturated00~18
5Cr steel[43]~5
13Cr steel[43]~0.2
X65[44,45]354600 × 10-6000.04
60%RH0.05
80%RH0.02
Saturated0.08
Table 1  Relevant research results about gaseous CO2 transportation pipeline corrosion in recent years[35-45]
Fig.2  Phase envelopes of CO2 containing impurities[51]
Fig.3  Relationship between maximum water content and pressure, temperature of CO2-rich transportation pipeline[77]
ModelDeveloped byT / ℃P / MPapCO2 / MPa
MinMaxMaxMinMax
LIPUCOR[90]Total2015025-5
KSC[91]IFE515025-5
PREDICT[92,93]InterCorr20200--10
SweetCor[94]Shell5121-0.0217
OLI[95,96]OLI system-50300150-150
Table 2  Survey of corrosion rates prediction models for gaseous CO2 transportation pipelines[90-96]
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