STUDY OF A NEW-TYPE HIGH STRENGTH Ni--BASED SUPERALLOY DZ68 WITH GOOD HOT CORROSION RESISTANCE
LIU Enze 1; 2; SUN Shunchen 1; TU Ganfeng1; ZHENG Zhi2; NING Likui2; ZHANG Lingfeng 3
1. School of Materials and Metallurgy; Northeastern University; Shenyang 110004
2. Institute of Metal Research; Chinese Academy of Sciences; Shenyang 110016
3. AVIC Xi'an Aero--Engine (Group) Ltd.; Xi'an 710021
Cite this article:
LIU Enze SUN Shunchen TU Ganfeng ZHENG Zhi NING Likui ZHANG Lingfeng . STUDY OF A NEW-TYPE HIGH STRENGTH Ni--BASED SUPERALLOY DZ68 WITH GOOD HOT CORROSION RESISTANCE. Acta Metall Sin, 2009, 45(10): 1217-1224.
In order to meet the requirements of marine gas turbine blade materials, a new–type directional solidification Ni–based superalloy named DZ68 was developed. The alloy composition was designed by low segregation technology. Its nominal chemical composition (mass fraction, %) is C
0.05, Cr 12.0, Mo 1.0, W 5.0, Co 8.5, Al 5.3, Ti 0.5, Ta 5.0, Re 2.0, B 0.01, and balance is Ni. The microstructures of as–cast DZ68 alloy and after heat treatment states were analyzed by OM, SEM and XRD. The tensile, rupture and hot corrosion resistance properties of DZ68 alloy were compared with
DZ125 and IN738 alloys. Results show that the microstructure of as–cast DZ68 alloy is composed of γ, γ', (γ+γ') eutectics, MC type carbides and a few borides. After heat treatment, the microstructureof DZ68 alloy is composed of γ, γ' and carbides. The carbides are mainly MC and M23C6. The tensile strength of DZ68 alloy decreases slightly with the increase of temperature, and reaches its minimum value at 700℃. When the temperature is higher than 700℃, the tensile stregth increases so evidently that reaches its maximum t oce at 760 ℃, But whethe temperature is higher than 760 ℃its tensile strength decreases obviously. It is well recognized the relatioship of the tensile strength of DZ68 alloy with temperature is abnormal, similar to that of its yield strength but oposite to that of its plasticity. The tensile and rupture properties of DZ68 alloy are nearly the same as those of DZ125 alloy and its hot corrosion resistance property is nearly the same as that of IN738 alloy under the same conditions.
[1] Liu X W, Huang J F. J Chongqing Inst Technol, 2000; 14(1): 48
(刘筱薇, 黄进峰. 重庆工学院学报, 2000; 14(1): 48)
[2] Gurrappa I. Oxid Met, 1999; 51: 353
[3] Huang Q Y, Li H K, Guo J T. Superalloy. Beijing: Metallurgical Industry Press, 2000: 115
(黄乾尧, 李汉康, 郭建亭. 高温合金. 北京: 冶金工业出版社, 2000: 115)
[4] Stringer J. Mater Sci Technol, 1987; 3: 482
[5] Li M S. High Temperature Corrosion of Metal. Beijing: Metallurgical Industry Press, 2001: 34
(李美栓. 金属的高温腐蚀. 北京: 冶金工业出版社, 2001: 34)
[6] Sidhu R K, Ojo O A, Chaturvedi M C. J Mater Sci, 2008; 43: 3612
[7] Zhou Y Z, Volek A, Green N R. Acta Mater, 2008; 56: 2631
[8] Gordon A P, Trexler M D, Neu R W. Acta Mater, 2007; 55: 3375
[9] Wright I G, Gibbons T B. Int J Hydrogen Energy, 2007; 32: 3610
[10] Zhu Y X, Zhang S N, Zhang T X, Zhang J H, Hu Z Q, Xie X S, Shi C X. In: Antolovich S D, Stusrud R W, Mackay R A, Anton D L, Khan T, Kissinger R D, Klarstrom D L eds., Superalloys 1992, PA: TMS, 1992: 145
[11] Shi C X, Yan M G, Zhu Z Q. China Aeronautical Materials Handbook. Beijing: Standards Press of China, 2001: 550
(师昌绪, 颜鸣皋, 朱之琴. 中国航空材料手册. 北京: 中国标准出版社, 2001: 550)
[12] Shi C X, Lu D, Rong K. Forty Years of China Superalloy. Beijing: Chinese Science and Technology Press, 1996: 8
(师昌绪, 陆达, 荣科. 中国高温合金四十年. 北京: 中国科学技术出版社, 1996: 8)
[13] Sun M C. Mechanics Property of Metal. Harbin: Harbin Institute of Technology Press, 2005: 240
(孙茂才. 金属力学性能. 哈尔滨: 哈尔滨工业大学出版社, 2005: 240)
[14] Ma C D, Huang Z H,Wang Q R. Aeronautical Engine Materials Handbooks for Designation. Beijing: Metallurgical Indusry Press, 1989: 61
(马翠娣, 黄志豪, 王庆如. 航空发动机设计用材料数据手册. 北京: 冶金工业出版社, 1989: 61)
[15] Ning L K, Zheng Z, Tan Y, Liu E Z, Tong J, Yu Y S,Wang H. Acta Metall Sin, 2009; 45: 161
(宁礼奎, 郑 志, 谭 毅, 刘恩泽, 佟 健, 于永泗, 王 华. 金属学报, 2009; 45: 161)
[16] Yu Z F, Zheng Z, Liu E Z, Yu Y S, Zhu Y X. J Chin Soc Corros Prot, 2008; 28: 277
(于忠锋, 郑 志, 刘恩泽, 于永泗, 朱耀宵. 中国腐蚀与防护学报, 2008; 28: 277)