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DISSOLUTION BEHAVIOURS OF La IN KCl-NaCl AND LaCl_3-KCo-NaCl MELTS |
GUO Chuntai;FENG Li;DU Senlin;YANG Zhongbao;TANG Dingxiang Changchun Institute of Applied Chemistry; Laboratory of Rare Earth Chemistry and Physics; Academia Sinica Lab.No.22;Changchun Institute of Applied Chemistry; Academia Sinica;Changchun 130022 |
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Cite this article:
GUO Chuntai;FENG Li;DU Senlin;YANG Zhongbao;TANG Dingxiang Changchun Institute of Applied Chemistry; Laboratory of Rare Earth Chemistry and Physics; Academia Sinica Lab.No.22;Changchun Institute of Applied Chemistry; Academia Sinica;Changchun 130022. DISSOLUTION BEHAVIOURS OF La IN KCl-NaCl AND LaCl_3-KCo-NaCl MELTS. Acta Metall Sin, 1990, 26(4): 103-107.
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Abstract The dissolution behaviours of La in KCl-NaCl and LaCl_3-KCl-NaClmelts have been studied by means of the see-through cell, cyclic voltammetry andEHMO of quantum chemistry. The La dissolved in KCl-NaCl melt is found to be ina metallic state, and dissolved in LaCl_3-KCl-NaCl melt ionized into La~(2+) which mayreact furthermore with surrounding La~(3+) to form atom cluster La_m~(n+).
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Received: 18 April 1990
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