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SHAPE OF RAMAN SPECTRA OF MOLTEN KNO_3-NaNO_2 SOLUTION |
;WANG Yinting;YANG Jinxiu;LI Yu;MA Guang;CHEN Nianyi Shanghai University of Science and Technology; Shanghai Institute of Metallurgy; Academia Sinica YAN Licheng Assoctate Professor;Department of Chemistry;shanghai University of Seience and Technology |
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Cite this article:
;WANG Yinting;YANG Jinxiu;LI Yu;MA Guang;CHEN Nianyi Shanghai University of Science and Technology; Shanghai Institute of Metallurgy; Academia Sinica YAN Licheng Assoctate Professor;Department of Chemistry;shanghai University of Seience and Technology. SHAPE OF RAMAN SPECTRA OF MOLTEN KNO_3-NaNO_2 SOLUTION. Acta Metall Sin, 1988, 24(1): 133-134.
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Abstract The Raman spectra of molten KNO_3-NaNO_2 solution at 473--623 K have beenmeasured and the regularity of the shape of spectra investigated. The symmetrical stretching frequency peak v_1 of NO_3- or NO_2- becomes broaden as the temperature increases or the concentra-tion of NO_3- or NO_2- ions in KNO_3NaNO_3 mixture decreases. The results have been discussedbased on the view-point of a theoretical model obtained in previous work.
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Received: 18 January 1988
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1 Chen Nianyi, Jiang Naixiong, Li Tonghua. Proceedings of The First International Symposium on Molten Salt Chemistry and Technology, Kyoto, Japan, 1983: 349 2 徐驰,陈念贻,江乃雄,李庆芝,沈时英.金属学报,1986; 22:B68 3 #12 4 Wait S C Jr., Ward A T, Janz G J. J Chem Phys, 1966; 45(1) : 133P |
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