|
|
CORROSION BEHAVIOR OF NUCLEAR GRADE ALLOYS 690 AND 800 IN SIMULATED HIGH TEMPERATURE AND HIGH PRESSURE PRIMARY WATER OF PRESSURIZED WATER REACTOR |
LI Xiaohui, WANG Jianqiu, HAN En–Hou, KE Wei |
State Key laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 |
|
Cite this article:
LI Xiaohui WANG Jianqiu HAN En–Hou KE Wei. CORROSION BEHAVIOR OF NUCLEAR GRADE ALLOYS 690 AND 800 IN SIMULATED HIGH TEMPERATURE AND HIGH PRESSURE PRIMARY WATER OF PRESSURIZED WATER REACTOR. Acta Metall Sin, 2012, 48(8): 941-950.
|
Abstract The corrosion behaviors of nuclear grade commercial alloys 690 and 800 were studied by in situ electrochemical measurements using a self–built high temperature and high pressure water loop system, combining with SEM observation and XPS analysis. The results show that the corrosion potentials of alloys 690 and 800 decrease gradually with immersion time increasing, while the immersion time has no obvious impact on the result from electrochemical impedance spectroscopy (EIS). A large number of needle–like oxides have been found on the surface of alloy 690 after being exposed to high temperature and high pressure water for 408 h. For alloy 800, except needle–like oxides, many particle oxides are also observed. For alloy 690, Cr is rich at inner side of oxide film, while it is rich at outer side of oxide film for alloy 800. Alloy 690 shows better corrosion resistance than alloy 800 in high temperature and high pressure water. After immersion experiment, the contents of Ni2+, Cr3+ and Fe3+ ions in the test water solutions are 0.1×10−6, 0.1×10−6 and 0.3×10−6, respectively
|
Received: 20 March 2012
|
|
Fund: Supported by National Basic Research Program of China (No.2011CB610502) and National Funds for Distinguished Young Scholars (No.51025104) |
[1] Dutta R S. J Nucl Mater, 2009; 393: 343[2] Staehle R W, Gorman J A. Corrosion, 2003; 59: 939[3] Betova I, Bojinov M, Kinnunen P, Lundgren K, Saario T. Electrochim Acta, 2009; 54: 1056[4] Montemor M F, Ferreira M G S, Hakiki N E, Belo M D C. Corros Sci, 2000; 42: 1635[5] Hwang S S, Kim H P, Lee D H, Kim U C, Kim J S. J Nucl Mater, 1999; 275: 28[6] Kim S W, Kim H P. Corros Sci, 2009; 51: 191[7] Panter J, Viguier B, Clou´e J M, Foucault M, Combrade P, Andrieu E. J Nucl Mater, 2006; 348: 213[8] Park I G, Lee C S, Hwang S S, Kim H P, Kim J S. Met Mater Int, 2005; 11: 401[9] Li X H, Huang F, Wang J Q, Han E H, Ke W. Acta Metall Sin, 2011; 47: 847(郦晓慧, 黄发, 王俭秋, 韩恩厚, 柯伟. 金属学报, 2011; 47: 847)[10] Canut J M L, Maximovitch S, Dalard F. J Nucl Mater, 2004; 334: 13[11] Huang J B, Wu X Q, Han E H. Corros Sci, 2009; 51: 2976[12] Carranza R M, Alvarez M G. Corros Sci, 1996; 38: 909[13] Olmedo A M, Villegas M, Alvarez M G. J Nucl Mater, 1996; 229: 102[14] Sennour M, Marchetti L, Martin F, Perrin S, Molins R, Pijolat M. J Nucl Mater, 2010; 402: 147[15] de Ara´ujo Figueiredo C, Bosch R W, Vankeerberghen M. Electrochim Acta, 2011; 56: 7871[16] Qiu Y B, Shoji T, Lu Z P. Corros Sci, 2011; 53: 1983[17] Zhang Z M, Wang J Q, Han E H, Ke W. Corros Sci, 2011; 53: 3623[18] Vaillant F, Buisine D, Prieux B. In: Airey G ed., Proc 7th Int Symp Environmental Degradation of Materials in Nuclear Power Systems—Water Reactors, Breckenridge, Colorado, USA, 1995: 219[19] Crum J, Scarberry R C. J Mater Energy Systems, 1982; 4: 125[20] Bosch R W, F´eron D, Celis J P. Electrochemistry in Light Water Reactors, Reference Electrodes, Measurement, Corrosion and Tribocorrosion Issues. Cambridge: Woodhead Publishing in Materials, 2007: 3[21] Li X H, Wang J Q, Han E H, Ke W. Chin Pat, ZL 201020521040.8, 2010(郦晓慧, 王俭秋, 韩恩厚, 柯伟. 中国实用新型专利, ZL 201020521040.8, 2010)[22] Sun H. PhD Thesis, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 2010(孙华. 中国科学院金属研究所博士论文, 沈阳, 2010)[23] Macdonald D D, Scott A C, Wentrcek P. J Electrochem Soc, 1979; 126: 908[24] Bosch R W, Vankeerberghen M. Electrochim Acta, 2007; 52: 7538[25] Bosch R W, W´eber M, Vankeerberghen M. J Nucl Mater, 2007; 360: 304[26] Macak J, Sajdl P, Kucera P, Novotny R, Vosta J. Electrochim Acta, 2006; 51: 3566[27] Li X H, Wang J Q, Han E H, Ke W. Corros Sci, 2012, submitted[28] Dutta R S, Tewari R. Br Corros J, 1999; 34: 201[29] Dutta R S, Lobo A, Purandare R, Kulkarni S K, Dey G K. Metall Mater Trans, 2002; 33A: 1437[30] Dutta R S, Purandare R, Lobo A, Kulkarni S K, Dey G K. Corros Sci, 2004; 46: 2937[31] Sun H, Wu X Q, Han E H. Corros Sci, 2009; 51: 2565[32] Machet A, Galtayries A, Zanna S, Klein L, Maurice V, Jolivet P, Foucault M, Combrade P, Scott P, Marcus P. Electrochim Acta, 2004; 49: 3957[33] Sun H, Wu X Q, Han E H. Corros Sci, 2009; 51: 2840[34] Marcus P, Grimal J M. Corros Sci, 1992; 33: 805[35] Li M S. High Temperature Corrosion of Metals. Beijing: Metallurgical Industry Press, 2001: 5(李美栓. 金属的高温腐蚀. 北京: 冶金工业出版社, 2001: 5)[36] Robertson J. Corros Sci, 1991; 32: 443 |
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|