金属学报  2007, Vol. 43 Issue (8): 797-802

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基于团簇线的Fe-B-Y基五元块体非晶合金

陈伟荣;王清;程旭;张庆瑜;董闯

大连理工大学；大连大学

(Fe-B-Y)-based quinary bulk metallic glasses designed using cluster line criterion

CHEN Wei-Rong;;;Qingyu Zhang;

大连理工大学；大连大学

陈伟荣; 王清; 程旭; 张庆瑜; 董闯 . 基于团簇线的Fe-B-Y基五元块体非晶合金[J]. 金属学报, 2007, 43(8): 797-802 .
, , , , . (Fe-B-Y)-based quinary bulk metallic glasses designed using cluster line criterion[J]. Acta Metall Sin, 2007, 43(8): 797-802 .

摘要 参考文献 相关文章 Metrics 全文: PDF(548 KB)   摘要: 在三元Fe-B-Y合金系中, 以团簇线判据设计了5个基础合金成分, 即5条成分线Fe8B3-Y, Fe8B2-Y, Fe83B17-Y, Fe6B-Y和Fe9B-Y与一条团簇线Fe12Y-B的交点. 在此基础上加入微量Nb和M(M=Ti, Hf, Ta, Mo, Ni和Sn)形成五元合金, 用铜模铸造方法制备出直径为3 mm的合金棒. 考虑到元素B和Y在合金制备过程中的损耗, 对每个合金进行了成分修正.在M=Ti, Hf, Ta和Mo时, 能够形成块体非晶合金的三元基础成分均接近Fe8B3-Y与Fe12Y-B两条团簇线交点成分, 表明其对应的基础团簇为Archimedes八面体反棱柱Fe8B3. 最佳非晶成分为(Fe69.9B24.6Y5.5)96Nb2Ti2,其Tg=944 K, Tx=997 K, Trg=0.666.当M=Ni和Sn时, 均没有得到块体非晶合金. 关键词 ： 团簇线,  铁基块体非晶合金,  成分设计     Abstract：This work investigates the glass formation of Fe-B-Y-based multicomponent alloys designed using a cluster line approach. Cluster lines Fe8B3-Y, Fe8B2-Y, Fe83B17-Y, Fe6B-Y and Fe9B-Y intersect with cluster line Fe12Y-B at five compositions in the Fe-B-Y phase diagram that are taken as basic compositions. Further minor alloying by additions of 2 at.% Nb and 2 at.% M (M=Ti, Hf, Ta, Mo, Ni, and Sn) was designed and alloy rods were synthesized with a diameter of 3mm by suction-casting in copper mold. A. Considering mass loss of B and Y during arc melting, the ingots were all weighted after each melting and the final compositions were revised accordingly. When M=Ti, Hf, Ta and Mo, the quinary alloys form BMGs at compositions close to the Fe8B3-Y cluster line. This signifies that the close-packed Archimedes octahedral antiprism Fe8B3 is the basic atomic cluster that favors glass formation. The best glass-forming composition is (Fe69.9B24.6Y5.5)96Nb2Ti2 with Tg=944K, Tx=997K, Trg=0.666. When M=Ni and Sn, no glass formation was observed. Key words： cluster line    Fe-based bulk metallic glass    composition design 收稿日期: 2006-12-08      ZTFLH:  TG139.8   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 陈伟荣 王清 程旭 张庆瑜 董闯 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y2007/V43/I8/797 [1]Inoue A,Shen B L,Takeuchi A.Mater Trans,2006;47: 1275 [2]Shen B L,Akiba M,Inoue A.Appl Phys Lett,2006;88: 131907 [3]Inoue A,Shinohara Y,Gook J S.Mater Trans JIM,1995; 36:1427 [4]Inoue A,Zhang T,Takeuchi A.Appl Phys Lett,1997;71: 464 [5]Inoue A,Chen B.Mater Trans,2002;43:766 [6]Inoue A,Nishiyama N,Matsuda T.Mater Trans JIM, 1996;37:181 [7]Inoue A,Zhang T,Mosumoto T.Mater Trans JIM,1990; 31:177 [8]Inoue A,Zhang W.Mater Trans,2002;43:2921 [9]Lin C Y,Tien H Y,Chin T S.Appl Phys Lett,2005;86: 162501 [10]Wang Y M,Zhang X F,Qiang J B,Wang Q,Wang D H, Li D J,Shek C H,Dong C.Scr Mater,2004;50:829 [11]Zhang X F,Wang Y M,Qiang J B,Wang Q,Wang D H, Li D J,Shek C H,Dong C.Intermetallics,2004;12:1275 [12]Wang Q,Wang Y M,Qiang J B,Zhang X F,Shek C H, Dong C.Intermetallics,2004;12:1229 [13]Wang Q,Qiang J B,Wang Y M,Xia J H,Lin Z,Zhang X F,Dong C. Acta Phys Sin,2006;55:378 (王清，羌建兵，王英敏，夏俊海，林哲，张新房，董闯．物理学报，2006；55：378) [14]Wu J,Wang Q,Qiang J B,Chen F,Dong C,Wang Y M, Shek C H.J Mater Res,2007:22:573 [15]Dong C,Qiang J B,Wang Y M,Jiang N,Wu J,Thiel P. Philos Mag,2006;86:263 [16]Inoue A,Takeuchi A,shen B.Mater Trans.2001;42:970 [17]Xia J H,Qiang J B,Wang Y M,Wang Q,Dong C.Appl Phys Lett,2006;88:101907 [18]Inoue A.Mater Trans JIM,1995;36:866 [19]Inoue A.Mater Sci Eng,2001;A304-306:1 [20]Miracle D B,Senkov O N,Sanders W S,Kending K L. Mater Sci Eng,2004:A375-377:150 [21]Miracle D B.J Non-Cryst Solids,2004;342:89 [22]Miracle D B,Sanders W S.Philos Mag,2003;83:2409 [1] 朱智浩, 陈志鹏, 刘田雨, 张爽, 董闯, 王清. 基于不同 α / β 团簇式比例的Ti-Al-V合金的铸态组织和力学性能[J]. 金属学报, 2023, 59(12): 1581-1589. [2] 何兴群, 付华栋, 张洪涛, 方继恒, 谢明, 谢建新. 机器学习辅助高性能银合金电接触材料的快速发现[J]. 金属学报, 2022, 58(6): 816-826. [3] 汪东红, 孙锋, 疏达, 陈晶阳, 肖程波, 孙宝德. 数据驱动镍基铸造高温合金设计及复杂铸件精确成形[J]. 金属学报, 2022, 58(1): 89-102. [4] 耿遥祥, 樊世敏, 简江林, 徐澍, 张志杰, 鞠洪博, 喻利花, 许俊华. 选区激光熔化专用AlSiMg合金成分设计及力学性能[J]. 金属学报, 2020, 56(6): 821-830. [5] 吴静,刘永长,李冲,伍宇婷,夏兴川,李会军. 高Fe、Cr含量多相Ni3Al基高温合金组织与性能研究进展[J]. 金属学报, 2020, 56(1): 21-35. [6] 耿遥祥,林鑫,羌建兵,王英敏,董闯. Finemet型纳米晶软磁合金的双团簇特征与成分优化[J]. 金属学报, 2017, 53(7): 833-841. [7] 耿遥祥,张志杰,王英敏,羌建兵,董闯,汪海斌,特古斯. 高Fe含量Fe-B-Si-Hf块体非晶合金的结构-性能关联[J]. 金属学报, 2017, 53(3): 369-375. [8] 周雪峰,陈光,严世坦, 郑功,李沛,陈锋. 新型无Re镍基单晶高温合金探索研究[J]. 金属学报, 2013, 49(11): 1467-1472. [9] 王清 查钱锋 刘恩雪 董闯 王学军 谭朝鑫 冀春俊. 基于团簇模型的高强度马氏体沉淀硬化不锈钢成分设计[J]. 金属学报, 2012, 48(10): 1201-1206. [10] 袁亮 羌建兵 庞厰 王英敏 王清 董闯. 源自Ni--Nb共晶团簇式的Ni-Nb-(Zr, Ta, Ag) 三元块体非晶合金成分设计[J]. 金属学报, 2011, 47(8): 1003-1008. [11] 马仁涛 郝传璞 王清 任明法 王英敏 董闯. 低弹bcc结构Ti-Mo-Nb-Zr固溶体合金的“团簇+连接原子”模型及其成分设计[J]. 金属学报, 2010, 46(9): 1034-1040. [12] 姜楠; 王清; 董闯 . Al-Cu-Ni-Fe四元体系中的准晶探讨[J]. 金属学报, 2007, 43(4): 374-378 . Viewed Full text Abstract Cited   Shared      Discussed