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金属学报    DOI: 10.3724/SP.J.1037.2013.00539
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新型无Re镍基单晶高温合金探索研究
周雪峰1,2),陈光1),严世坦1), 郑功1),李沛1),陈锋1)
1) 南京理工大学材料评价与设计教育部工程研究中心, 南京 210094
2) 常熟理工学院化学与材料工程学院, 常熟 215500
EXPLORATION AND RESEARCH OF A NEW Re-FREE Ni-BASED SINGLE CRYSTAL SUPERALLOY
ZHOU Xuefeng 1,2), CHEN Guang 1), YAN Shitan 1), ZHENG Gong 1), LI Pei 1), CHEN Feng 1)
1) Engineering Research Center of Materials Behavior and Design, Ministry of Education,Nanjing University of Science and Technology, Nanjing 210094
2) School of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu 215500
全文: PDF(1574 KB)  
摘要: 

综合运用电子空位理论和d-电子理论, 设计了一种新型无Re镍基单晶高温合金7.5Cr-5Co-2Mo-6.1Al-8W-6.5Ta-0.15Hf-0.05C-0.004B-0.015Y(质量分数, %),Ni余量. 采用光学显微镜、扫描电镜、X射线能谱观察了其铸态、固溶处理和时效处理后的组织特征,研究了完全热处理后合金的760℃拉伸力学行为及断口形貌. 结果表明,合金的组织稳定, 合金元素间共价键平均结合强度Bot, γ′相固溶温度Tγ′solvus, 成分性能预测参数P,抗拉强度σb等与第2代含Re镍基单晶高温合金相当.

关键词 镍基单晶高温合金成分设计组织特征拉伸性能    
Abstract

Ni-based single crystal superalloy has not only high temperature creep and fatigue resistance, but also excellent oxidation and corrosion resistance,which becomes a main selection of the advanced aero engine turbine blades. In order to enhance high temperature properties, Re is added into the superalloy, however, high density and high cost of the Re, especially promote the precipitation of harmful phases at high service temperature, which limit the use of Re. Therefore, how to reduce or even abolish the use of Re in the single crystal superalloy is the main trend to develop a new generation turbine engine material. A new Re-free Ni-based single crystal superalloy, 7.5Cr-5Co-2Mo-6.1Al-8W-6.5Ta-0.15Hf-0.05C-0.004B-0.015Y (mass fraction, %), Ni balance, has been designed by using the average electron vacancy number theory and the d-electrons concept. The microstructures of the as-cast, solution and aging treated specimens were observed by optical microscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy. The mechanical behavior of the fully heat treated single crystal superalloy and the appearance of fracture at 760℃ were studied. The calculation results indicate that the microstructure of the designed alloy is stable and the main performance criteria, such as Bot (the bond order between alloying elements and Ni atoms),Tγ′solvus (γ′ solvus temperature),P (the parameter which predicts the merit of the composition), etc.,are comparable to those of the second generation of the Ni-based single crystal superalloy.The experimental results indicate that W and Mo enriched in the dendrite cores,while Al and Ta enriched in the interdendritic region. The size and volume fraction of γ′ phase in the dendrite cores is smaller than that in the interdendritic region.After solution heat treatment at 1300℃, 3 h, air cooling,γ/γ′ eutectics are dissolved and composition segregation is significantly improved. After fully heat treatment at 1100℃, 4 h,air cooling and 870℃, 24 h, air cooling, γ′ phase with cube-shaped distributes in theγmatrix channels uniformly, whose ultimate tensile strength at 760℃ is 1009 MPa, comparable to the second generation of Re-containing Ni-based single crystal superalloy considerably.

Key wordsNi-based single crystal superalloy    composition design    microstructure characteristics, tensile property
收稿日期: 2013-08-30     
基金资助:

江苏省科技支撑计划(工业)项目BE201217, 科技创新基金项目CX2011028和CX2011029资助

通讯作者: 陈光     E-mail: gchen@njust.edu.cn
作者简介: 周雪峰, 男, 1979年生, 博士生

引用本文:

周雪峰,陈光,严世坦, 郑功,李沛,陈锋. 新型无Re镍基单晶高温合金探索研究[J]. 金属学报, 10.3724/SP.J.1037.2013.00539.
ZHOU Xuefeng, CHEN Guang, YAN Shitan, ZHENG Gong, LI Pei, CHEN Feng. EXPLORATION AND RESEARCH OF A NEW Re-FREE Ni-BASED SINGLE CRYSTAL SUPERALLOY. Acta Metall Sin, 2013, 49(11): 1467-1472.

链接本文:

https://www.ams.org.cn/CN/10.3724/SP.J.1037.2013.00539      或      https://www.ams.org.cn/CN/Y2013/V49/I11/1467

[1] Ryokichi H, Akira Y, Takamasa K, Yoshinori M, Masahiko M. In: Green K A,Pollock T M, Harada H, Howson T E, Reed R C, Schirra J J, Walston S, eds.,Superalloys 2004, Warrendale, PA: TMS, 2004: 53

[2] Tresa M P, Sammy T.  J Propul Power, 2006; 22: 361
[3] Cetel A D, Duhl D N. In: Reichman S, Duhl D N, Maurer G, Antolovich S,Lund C, eds.,  Superalloys 1988, Warrendale, PA: TMS, 1988: 235
[4] Hu Z Q, Liu L R, Jin T, Sun X F.  Aeroengine, 2005; 31(3): 1
(胡壮麒, 刘丽荣, 金涛, 孙晓峰. 航空发动机, 2005; 31(3): 1)
[5] Reed R C, Tao T, Warnken N.  Acta Mater, 2009; 57: 5898
[6] Rae C M F, Reed R C.  Acta Mater, 2001; 49: 4113
[7] Rae C M F, Karunaratne M S A, Small C J, Broomfield R W, Jones C N, ReedR C. In: Pollock T M, Kissinger R D, Bowman R R, Green K A, McLean M, Olson S,Schirra J J, eds.,  Superalloys 2000, Warrendale, PA: TMS, 2000: 767
[8] Caldwell E, Fela F, Fuchs G.  JOM, 2004; 56(9): 44
[9] Yeh A C, Sato A , Kobayashi T, Harada H.  Mater Sci Eng, 2008; A490: 445
[10] Tian S G, Wang M G, Li T, Qian B J, Xie J.  Mater Sci Eng, 2010; A527: 5444
[11] Hobbs R A, Zhang L, Rae C M F, Tin S.  Metall Mater Trans, 2008; 39A: 1014
[12] Yukawa N, Morinaga M, Murata Y, Ezakin H, Inoue S. In: Reichman S, Duhl D N, Maurer G, Antolovich S, Lund C, eds.,  Superallovs 1988, Warrendale,PA: TMS, 1988: 225
[13] Murata Y, Miyazaki S, Morinaga M, Hashizume R. In: Kissinger R D,Deye D J, Anton D L, Cetel A D, Nathal M V, Pollock T M, Woodford D A, eds., Superalloys 1996, Warrendale, PA: TMS, 1996: 61
[14] Zhang J S, Hu Z Q, Murata Y, Morinaga M, Yukawa N.  Met Trans, 1993; 24A: 2443
[15] Morinaga M, Yukawa N, Adachi H.  J Phys Soc Jpn, 1984; 55: 653
[16] Morinaga M, Yuhwa N, Ezaki H, Adachi H.  Philos Mag, 1985; 51A: 223
[17] Sabo G P, Stickler R.  Phys Status Solidi, 1969; 35B(1): 11
[18] Barrows R G, Newkirk J B.  Metall Trans, 1972; 3A: 2889
[19] Wallace W.  Met Sci, 1975; 9: 547
[20] Caron P. In: Pollock T M, Kissinger R D, Bowman R R, Green K A, McLean M,Olson S, Schirra J J, eds.,  Superalloys 2000, Warrendale, PA: TMS, 2000: 737
[21] Rae C.  Mater Sci Technol, 2009; 25: 479
[22] Duhl D N, Cetel A D.  US Pat, 4719080, 1988
[23] Carroll L J, O'Hara K S.  US Pat, WO2009032578A1, 2009
[24] Wukusick C S, Buchakjian L.  UK Pat, GB 2235697, 1991
[25] Dwaine L K.  US Pat, 4476091, 1984
[26] Hata S, Kimura K, Gao H Y,Matsumura S, Doi M, Moritani T, Barnard J S,Tong J R, Sharp J H, Midgley P A.  Adv Mater, 2008; 20: 1905
[27] Doi M, Miki D, Moritani T, Kozakai T. In: Green K A, Pollock T M, Harada H,Howson T E, Reed R C, Schirra J J, Walston S, eds.,  Superalloys 2004, Warrendale,PA: TMS, 2004: 109
[28] Eridon J M, Harris K, Sikkenga S L.  US Pat, 5443789, 1995
[29] Wukusick C S, Buchakjian L.  US Pat, 6074602, 2000
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