双非晶相铁基复合涂层的腐蚀与磨损行为

doi:10.11900/0412.1961.2023.00449

金属学报

2025, Vol. 61

Issue (8): 1267-1275 DOI: 10.11900/0412.1961.2023.00449

研究论文

本期目录 | 过刊浏览

双非晶相铁基复合涂层的腐蚀与磨损行为

臧勃林¹, 杨延格²(

), 曹京宜¹, 徐锋锋³, 姚海华³(

), 周正³

^1.中国人民解放军92228部队北京 100072
^2.中国科学院金属研究所师昌绪先进材料创新中心沈阳 110016
^3.北京工业大学材料与制造学部北京 100124

Corrosion and Wear Behaviors of Fe-Based Composite Coating with Dual Amorphous Phases

ZANG Bolin¹, YANG Yange²(

), CAO Jingyi¹, XU Fengfeng³, YAO Haihua³(

), ZHOU Zheng³

^1.Unit 92228, People's Liberation Army, Beijing 100072, China
^2.Shi -changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^3.Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, China

引用本文:

臧勃林, 杨延格, 曹京宜, 徐锋锋, 姚海华, 周正. 双非晶相铁基复合涂层的腐蚀与磨损行为[J]. 金属学报, 2025, 61(8): 1267-1275.
Bolin ZANG, Yange YANG, Jingyi CAO, Fengfeng XU, Haihua YAO, Zheng ZHOU. Corrosion and Wear Behaviors of Fe-Based Composite Coating with Dual Amorphous Phases[J]. Acta Metall Sin, 2025, 61(8): 1267-1275.

全文: PDF(3167 KB) HTML

摘要:

为提高铁基非晶涂层的综合性能，本工作设计并制备了双非晶相铁基复合涂层(FH)，并与Fe₄₈Cr₁₅Mo₁₄C₁₅B₆Y₂ (FM)和Fe₅₉Cr₁₂Nb₅B₂₀Si₄ (FN) 2种单一非晶相涂层的腐蚀与磨损行为进行对比研究。结果表明，FH涂层具有较高的非晶化程度和致密度，2种非晶相变形粒子分布均匀，无明显元素互扩散。在3.5%NaCl溶液中，FH涂层表现出与2种单一非晶相涂层相似的钝化行为，且具有更低的腐蚀电流密度和更高的极化电阻，耐腐蚀性能有所提高。在干摩擦磨损条件下，FH涂层的摩擦系数升高，磨损率接近耐磨性较好的FN非晶涂层，磨损机制主要为疲劳磨损。

关键词 ：铁基非晶涂层, 复合涂层, 双非晶相, 腐蚀, 摩擦磨损

Abstract：

Fe-based amorphous composite coatings have attracted great attention because their specific properties can be enhanced by introducing other metallic or ceramic particles. This work introduces a novel approach, distinct from traditional methods, by designing a composite coating with dual amorphous phases. The composite coating (named FH) was fabricated using high-velocity oxygen-fuel spraying of a blended amorphous powder. This powder comprised well-established Fe₄₈Cr₁₅Mo₁₄C₁₅B₆Y₂ (named FM) and Fe₅₉Cr₁₂Nb₅B₂₀Si₄ (named FN) amorphous powders. This study focuses on investigating the corrosion and wear behaviors of the FH coating in comparison with those of monolithic amorphous coatings. The findings reveal that the FH coating possesses a high amorphous content and a compact structure. It features a uniform distribution of two types of amorphous splats, with no evident element diffusion. In 3.5%NaCl solution, the FH coating exhibits passivation behavior, similar to the two monolithic amorphous coatings, and yields a lower corrosion current and higher polarization resistance, indicating enhanced its corrosion resistance. This improved corrosion resistance of the FH coating is attributed to a harmonious balance between beneficial alloy elements and its compact structure, addressing the limitations of monolithic amorphous coatings. Furthermore, the FH coating displays a high friction coefficient under dry friction conditions and maintains a low wear rate, comparable to those of the FN coating. The wear mechanisms of the three amorphous coatings under dry friction primarily involve fatigue wear, supplemented by minor abrasive and oxidative wear. Compared to the monolithic amorphous coating, the FH coating shows enhanced interfacial bonding of splats and a balanced combination of strengthening and toughening, which effectively inhibit crack propagation caused by fatigue wear, thereby endowing the coating with superior wear resistance. Therefore, the composite coating with dual amorphous phases achieves a balance in cost efficiency, corrosion resistance, and wear resistance.

Key words： Fe-based amorphous coating composite coating dual amorphous phase corrosion friction and wear

收稿日期: 2023-11-13

ZTFLH:

TG174

基金资助:国家自然科学基金项目(52371043);国家自然科学基金项目(51771005);国家自然科学基金项目(52171060)

通讯作者: 杨延格，ygyang@imr.ac.cn，主要从事海洋腐蚀与防护研究;
姚海华，yaohaihua@bjut.edu.cn，主要从事亚稳态金属材料研究

Corresponding author: YANG Yange, professor, Tel: (024)23881473, E-mail: ygyang@imr.ac.cn;
YAO Haihua, Tel: (010)67392168, E-mail: yaohaihua@bjut.edu.cn

作者简介: 臧勃林，男，1985年生，硕士

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图1 铁基非晶涂层的XRD谱

图2 铁基非晶涂层典型截面的背散射电子(BSE)像及EDS分析结果

图3 铁基非晶涂层微区TEM明场像及选区电子衍射(SAED)花样

图4 铁基非晶涂层在3.5%NaCl溶液中的动电位极化曲线

表1 根据动电位极化曲线得到的腐蚀参数

图5 铁基非晶涂层在3.5%NaCl溶液中的Nyquist图、Bode图和等效电路

表2 铁基非晶涂层的电化学阻抗参数

图6 铁基非晶涂层摩擦系数监测曲线

图7 铁基非晶涂层磨痕形貌及测量结果

图8 铁基非晶涂层的显微硬度及磨损率

图9 铁基非晶涂层磨痕表面形貌

表3 图9中标记区域的EDS结果 (mass fraction / %)

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