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金属学报  2014, Vol. 50 Issue (3): 355-360    DOI: 10.3724/SP.J.1037.2013.00478
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NZ30K镁合金时效析出动力学与强化模型的研究*
王小娜1, 韩利战1,2, 顾剑锋1,2()
1 上海交通大学材料科学与工程学院, 上海 200240
2 上海市激光制造与材料改性重点实验室, 上海 200240
PRECIPITATION KINETICS AND YIELD STRENGTH MODEL FOR NZ30K-Mg ALLOY
WANG Xiaona1, HAN Lizhan1,2, GU Jianfeng1,2()
1 School of Materials Science and Engineering, Shanghai Jiaotong University, Shanghai 200240
2 Shanghai Key Laboratory of Materials Laser Processing and Modification, Shanghai 200240
引用本文:

王小娜, 韩利战, 顾剑锋. NZ30K镁合金时效析出动力学与强化模型的研究*[J]. 金属学报, 2014, 50(3): 355-360.
Xiaona WANG, Lizhan HAN, Jianfeng GU. PRECIPITATION KINETICS AND YIELD STRENGTH MODEL FOR NZ30K-Mg ALLOY[J]. Acta Metall Sin, 2014, 50(3): 355-360.

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摘要: 

利用等转变量方法和恒速升温时效过程中的电阻实验研究了NZ30K镁合金的析出动力学, 获得了动力学模型的激活能 E α r 和修正指前因子 A ' α r , 可用于准确描述不同时效条件下强化相的析出过程. NZ30K镁合金欠时效阶段和峰时效的力学性能显示, 在180~250 ℃范围内峰时效屈服强度一致, 约为150 MPa. 通过最小二乘法确定了NZ30K镁合金180~250 ℃范围内时效时析出强化模型参数C, 约为93 MPa, 实验数据和模型预测数据一致, 证明该模型能应用于NZ30K镁合金欠时效和峰时效条件下屈服强度的预测.

关键词 NZ30K镁合金析出动力学沉淀强化固溶强化屈服强度    
Abstract

Age-hardening effect is considerably strong in magnesium alloys containing Nd, making it possible to develop magnesium alloys with low cost and high strength. Although there have been massive researches about the precipitation product sequence and strengthening models in magnesium, aluminum and other light alloys during their ageing processes, those of NZ30K-Mg alloy, a newly-developed magnesium alloy, has not been carefully investigated. The present work mainly focuses on the model of precipitation kinetics and strengthening of NZ30K-Mg alloy. The precipitation kinetics has been investigated using electrical resistivity testing during continuous heating with different heating rates and formulated based on the isoconversional method. Two related model parameters, modified pre-exponential factor A ' α r and activation energy E α r were respectively determined. The precipitation behavior of NZ30K-Mg alloy during ageing processes can also be intrinsically explained from the variations of E α r and ln A ' α r with the precipitation fraction. This kinetics model with two above-mentioned parameters can accurately describe the precipitation of strengthening phase during different ageing processes. The yield strength of under-aged and peak-aged NZ30K-Mg alloy have been tested and the results show that the testing samples isothermally aged at different temperature from 180 to 250 ℃ have almost the same peak yield strength of about 150 MPa, indicating that the strengthening effect of under-aged and peak-aged NZ30K-Mg alloy is only determined by the precipitation fraction within a certain range of temperatures. The precipitation strengthening model of NZ30K-Mg alloy has been carefully derived, and the parameter C in the model has then been determined by least squares method based on the tested yield strength data. The value of C is about 93 MPa. The prediction of yield strength of under-aged and peak-aged NZ30K-Mg alloy has been performed and fit well with the tested ones, demonstrating the effectiveness of precipitation strengthening model and its engineering application prospects.

Key wordsNZ30K-Mg alloy    precipitation kinetics    precipitation strengthening    solid solution strengthening    yield strength
收稿日期: 2013-08-05     
ZTFLH:  TG166.3  
基金资助:*国家科技重大专项资助项目 2011ZX04014-052和2012ZX04012011
作者简介: null

王小娜, 女, 1990年生, 硕士

图1  
图2  
图3  
图4  
Specimen No. T / ℃ t / h α r / % σ y / MPa
1 180 1 0.111 109.71
2 180 2 0.174 111.43
3 180 5 0.269 122.25
4 180 10 0.332 125.68
5 180 20 0.397 131.29
6 180 50 0.513 133.39
7 180 100 0.684 141.19
8 180 200 0.897 148.88
9 200 1 0.197 127.43
10 200 2 0.282 135.24
11 200 5 0.397 138.00
12 200 10 0.504 144.44
13 200 20 0.697 148.50
14 200 50 0.941 151.53
15 250 0.25 0.304 138.28
16 250 0.5 0.548 148.89
17 250 0.75 0.717 149.60
18 250 1 0.850 152.59
表1  NZ30K镁合金等温时效处理后试样的相对析出体积分数和屈服强度
图5  
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