Regulation of Hydrogen Storage Phase and Its Interface in Magnesium-Based Materials for Hydrogen Storage Performance

doi:10.11900/0412.1961.2022.00480

Acta Metall Sin

2023, Vol. 59

Issue (3): 349-370 DOI: 10.11900/0412.1961.2022.00480

Overview

Current Issue | Archive | Adv Search

Regulation of Hydrogen Storage Phase and Its Interface in Magnesium-Based Materials for Hydrogen Storage Performance

LI Qian¹^,²^,³, SUN Xuan³, LUO Qun³, LIU Bin³, WU Chengzhang³, PAN Fusheng¹^,²(

)

1 National Engineering Research Center for Magnesium Alloys, Chongqing University, Chongqing 400044, China
2 School of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
3 State Key Laboratory of Advanced Special Steel, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China

Cite this article:

LI Qian, SUN Xuan, LUO Qun, LIU Bin, WU Chengzhang, PAN Fusheng. Regulation of Hydrogen Storage Phase and Its Interface in Magnesium-Based Materials for Hydrogen Storage Performance. Acta Metall Sin, 2023, 59(3): 349-370.

Download:

HTML

PDF(6034KB)
Export: BibTeX | EndNote (RIS)

Abstract

Mg-based hydrogen storage materials have drawn a lot of attention due to the merit of high hydrogen storage density, earth-abundant resources, and environmental friendliness. However, the slow kinetics, high hydrogen absorption/desorption temperature, and poor cycling stability of Mg-based hydrogen storage materials prevent them from being used on a large scale. The developments of new alloys, nano-structure control, catalytic modification, and multiphase composites, among other things, have made significant progress in Mg-based hydrogen storage materials in recent years. However, challenges still exist, such as high hydrogen storage capacity, moderate adsorption/desorption temperature, rapid reaction rate, and long cycling life. In this review paper, the types of hydrogen storage phases and their interface in Mg-based materials, and the control methods of their microstructure/interface characteristics are systematically summarized. The mechanism of the hydrogen storage phase, microstructure, and surface/interface modifications on the improved thermal/kinetic performance of hydrogen storage are highlighted. This review concludes with an outlook and prospects on the challenge of designing Mg-based hydrogen storage materials by controlling the hydrogen storage phase and the corresponding interface.

Key words: Mg-based hydrogen storage material hydrogen storage phase surface/interface structure hydrogen storage performance regulation strategy

Received: 28 September 2022

ZTFLH:

TG139

Fund: National Natural Science Foundation of China(U2102212)

About author: PAN Fusheng, professor, Tel: (023)65102856, E-mail: fspan@cqu.edu.cn

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Qian LI
	Xuan SUN
	Qun LUO
	Bin LIU
	Chengzhang WU
	Fusheng PAN

URL:

https://www.ams.org.cn/EN/10.11900/0412.1961.2022.00480 OR https://www.ams.org.cn/EN/Y2023/V59/I3/349

Hydrogen	Pearson	Space group	Lattice	Hydride	Hydrogen storage	Ref.
storage	symbol		parameter		capacity
phase			nm		(mass fraction, %)
Mg	hP2	P63/mmc	a = b = 0.32, c = 0.52	MgH₂	7.60	[19]
Mg₂Ni	hP18	P6₂22	a = b = 0.52, c = 1.32	Mg₂NiH₄	3.62	[25]
Mg₂Cu	oF48	Fddd	a = 0.91, b = 1.8,	MgH₂	2.53	[25]
			c = 0.53
Mg₁₇Al₁₂	cI58	$I 4 ¯ 3 m$	bcc a = 1.06	MgH₂	4.40	[19]
Mg₃La	cF16	$F m 3 ¯ m$	bcc a = 0.75	MgH₂, LaH _x (x = 2-3)	2.89	[26]
Mg₁₇La₂	hP38	P63/mmc	a = b = 1.04,	MgH₂, LaH _x (x = 2-3)	4.87	[27,38]
			c =1.02
Mg₁₂Ce	tI26	I4/mmm	a = b = 1.03, c = 0.60	MgH₂, CeH_2.73	5.68	[28]
Mg₃Ce	cF16	$F m 3 ¯ m$	bcc a = 0.74	MgH₂, CeH_2.73	3.62	[28]
Mg₁₂Nd	tI26	I4/mmm	a = b = 1.03, c = 0.59	MgH₂, NdH_2.61	5.63	[29]
Mg₂₄Y₅	cI58	$I 4 ¯ 3 m$	bcc a = 1.13	MgH₂, YH _x (x = 2-3)	5.34	[30]
18R-LPSO (Mg₈₅Zn₆Y₉)	-	C2/m	a = 1.11, b = 1.93,	MgH₂, YH _x (x = 2-3)	4.60-5.30	[31]
18R-LPSO (Mg₈₅Zn₆Y₉)			c = 1.60
18R-LPSO	-	P6₃22	a = b = 0.31, c = 4.86	MgH₂, Mg₂NiH₄, YH _x	4.60	[32]
(Mg₁₂YNi)				(x = 2-3)
14H-LPSO	-	P6₃/mcm	a = b = 1.11, c = 3.66	MgH₂, YH _x (x = 2-3)	5.48	[33]
(Mg₉₂Cu_3.5Y_4.5)
Nd₄Mg₈₀Ni₈	tI92	I4₁/amd	a = b = 1.27, c = 1.59	MgH₂, Mg₂NiH₄, NdH_2.61	4.94	[37]
Nd₁₆Mg₉₆Ni₁₂	oS124	Cmc2₁	a = 1.53, b = 2.17,	MgH₂, Mg₂NiH₄, NdH_2.61	3.92	[36]
			c = 0.95
NdMg₂Ni	oS16	Cmcm	a = 0.41, b = 1.02,	MgH₂, Nd_2.61	2.07	[39]
			c = 0.83
LaMg₂Ni	oS16	Cmcm	a = 0.42, b = 1.03,	LaMg₂NiH₇	1.92	[39]
			c = 0.84
La₂MgNi₉	hR36	$R 3 ¯ m$	a = b = 0.50, c = 2.43	La₂MgNi₉H₁₂	1.60	[40]
LaMgNi₄	cF24	$F 4 ¯ 3 m$	bcc a =0.72	LaMgNi₄H₇	1.40	[41]
2H-La₃MgNi₁₄	-	P6₃/mmc	a = b = 0.50, c = 2.42	La₃MgNi₁₄H₁₈	-	[34]
3R-La₃MgNi₁₄	-	$R 3 ¯ m$	a = b = 0.50, c = 3.61
2H-La₄MgNi₁₉	-	P6₃/mmc	a = b = 0.50, c = 3.23	La₄MgNi₁₉H₂₄	1.50	[35]
3R-La₄MgNi₁₉	-	$R 3 ¯ m$	a = b = 0.50, c = 4.82

Table 1 Crystal structures and hydrogen storage capacities of magnesium-based hydrogen storage phases in different systems^[19,25-41]

Fig.1 SEM-EDS and TEM analyses of Mg₄NiPd treated by high pressure torsion (HPT)^[70]
(a) elemental map of Mg₄NiPd treated by HPT for 0-1500 turns (N) (b, c) atom probe tomography (APT) elemental map (b) and XRD spectrum (c) of 1500 turns of Mg₄NiPd (d) bright-field TEM image (e) dark-field image and corresponding selected area electron diffraction (SAED) pattern (f) high-resolution TEM image and corresponding fast Fourier transform (FFT) pattern (inset) (g) lattice image of {110} diffraction reconstructed by inverse FFT (IFFT) (inset)

Fig.2 Magnesium-based nanoparticles of Mg₂Ni (a), Mg₂Co (b), and Mg₂Cu (c) prepared by hydrogen plasma-metal reaction (HPMR) method^[22]; surface and cross-sectional (insets) morphologies of Mg_0.83Nb_0.17 (d), Mg_0.70Nb_0.30 (e), and Mg_0.24Nb_0.76 (f) prepared by Co-sputtering^[75]; and SEM images of Mg nanowire synthesized by gas phase reaction at flow rates of 200 cm³/min (g), 300 cm³/min (h), and 400 cm³/min (i)^[21]

Table 2 Comparisons of hydrogen storage phase and microstructure/interface of Mg-based materials under different control methods^{[21,22,56-62,70-73,77-79,81-83]}

Table 3 Metastable phases prepared by HPT in different magnesium based systems^[65,67-70]

Fig.3 SEM image (a), TEM images (b, c), and XRD spectra (d) of Mg₅₅Co₄₅ alloy sample, and pressure-composition-isotherm (PCT) curves of the Mg₅₅Co₄₅ bcc alloy at 258 K (Inset: XRD curves of the Mg₅₅Co₄₅ bcc alloy before/after absorption and desorption cycle) (e)^[84]

Fig.4 Comparisons of hydrogen absorption kinetics of different nanostructured Mg^{[21,75,76,94]}

Fig.5 Cross-sectional SEM images (a-c) and kinetics of dehydrogenation at 393 K (d-f) of samples F₃₀₀ (a, d), F_2*250 (b, e), and F_10*50 (c, f) in Mg₈₅Ni₁₄Ce₁ amorphous films^[103] (One Mg-Ni-Ce layer film in 300 nm, two Mg-Ni-Ce layers films in 250 nm, and ten Mg-Ni-Ce layers films in 50 nm were marked as F₃₀₀, F_2*250, and F_10*50, respectively)

Fig.6 XRD spectra of melt-spun Mg₆₅Ce₁₀Ni₂₀Cu₅ alloy before and after HPT process for 1, 5, and 10 turns (inset: image of a disk after HPT process) (a), hydrogenation kinetics of sample processed by melt-spun and one HPT turns (b), and HRTEM image of sample processed by one HPT turns (c)^[104] (Rotation speed ω = 0.5 r/min)

Fig.7 OM image for annealed Mg sample (a), TEM images and SAED patterns (insets) for Mg samples processed by HPT for 0.25 (b) and 10 (c, d) turns (Fig.7d is a dark-field image of Fig.7c), and hydrogen absorption kinetics curves of annealed samples and HPT treated samples at 0.25 and 10 turns (e)^[66] (P—pressure, T—temperature, ε—equivalent strain)

Fig.8 TEM images, hydrogen absorption kinetic curves, and schematic of Mg₂Ni samples treated with 10 turns of HPT and annealed at 673 K^[55]
(a) bright field image
(b) HRTEM image of lattice and corresponding SAED pattern (inset)
(c) normal ABCABC stacked lattice image
(d) lattice image with a stacking layer dislocation
(e) hydrogen absorption kinetic curves of coarse crystal Mg₂Ni with and without stacking faults (t—annealed time)
(f) schematic of stacking faults as hydrogen transport pathways

Fig.9 EBSD maps and corresponding polar maps of pure Mg treated by the processes of HPT (a), cold rolling (CR) (b), and MS-CR (c), kinetics of hydrogen absorption after Mg activation by different SPD processes (d), and kinetics of hydrogen desorption by MS and MS-CR samples (e)^[52] (MS—melt spun, SPD—severe plastic deformation, RD—rolling direction, TD—transverse direction)

Fig.10 Morphologies and element distributions of the side (a-c) and surface (d-f) of 5.28%Ni (mass fraction) powder after cold spraying Mg strip, hydrogen absorption kinetics of different samples at 423 K, 8 × 10⁵ Pa (g), and hydrogen desorption kinetics of different samples at 473 K, 2 × 10⁴ Pa (h)^[111] (SEI—secondary electron image)

Fig.11 TEM images and schematic representations of the cross-section of Mg-LaNi₅-Soot obtained by accumulative roll bonding (ARB)^[115]
(a) TEM bright-field image of Mg-LaNi₅-Soot obtained by ARB 30 passes (cross-sectional view)
(b) TEM bright-field image of Mg-LaNi₅-Soot obtained by ARB 5 passes
(c) zoomed-in view encompassing a single particle at the Mg-Mg interface
(d) SEAD pattern confirming the presence of LaNi₅
(e) bright-field TEM image of Mg-Soot obtained by ARB 30 passes
(f) dark-field image with EDS line scan overlaid
(g) schematic representations of the cross-section of Mg-LaNi₅-Soot samples

1	Zhu M, Ouyang L Z. Kinetics tuning and electrochemical performance of Mg-based hydrogen storage alloys [J]. Acta Metall. Sin., 2021, 57: 1416 doi: 10.11900/0412.1961.2021.00336
	朱敏, 欧阳柳章. 镁基储氢合金动力学调控及电化学性能 [J]. 金属学报, 2021, 57: 1416
2	Schlapbach L, Züttel A. Hydrogen-storage materials for mobile applications [J]. Nature, 2001, 414: 353 doi: 10.1038/35104634
3	Cohen R L, Wernick J H. Hydrogen storage materials: Properties and possibilities [J]. Science, 1981, 214: 1081 pmid: 17755872
4	An X H, Pan Y B, Luo Q, et al. Application of a new kinetic model for the hydriding kinetics of LaNi_{5 -} _x Al _x (0 ≤ x≤ 1.0) alloys [J]. J. Alloys Compd., 2010, 506: 63 doi: 10.1016/j.jallcom.2010.07.016
5	Ding W J, Zeng X Q. Research and applications of magnesium in China [J]. Acta Metall. Sin., 2010, 46: 1450 doi: 10.3724/SP.J.1037.2010.01450
	丁文江, 曾小勤. 中国Mg材料研发与应用 [J]. 金属学报, 2010, 46: 1450 doi: 10.3724/SP.J.1037.2010.00386
6	Fang W B, Zhang W C, Yu Z X, et al. Recent development of Mg-based hydrogen storage material [J]. Chin. J. Nonferrous Met., 2002, 12: 853
	房文斌, 张文丛, 于振兴等. 镁基储氢材料的研究进展 [J]. 中国有色金属学报, 2002, 12: 853
7	Feng Y, Chen C, Peng C Q, et al. Research progress on magnesium matrix composites [J]. Chin. J. Nonferrous Met., 2017, 27: 2385
	冯艳, 陈超, 彭超群等. 镁基复合材料的研究进展 [J]. 中国有色金属学报, 2017, 27: 2385
8	Li Q, Lu Y F, Luo Q, et al. Thermodynamics and kinetics of hydriding and dehydriding reactions in Mg-based hydrogen storage materials [J]. J. Magnes. Alloy., 2021, 9: 1922 doi: 10.1016/j.jma.2021.10.002
9	Zhang Q Y, Du S C, Ma Z W, et al. Recent advances in Mg-based hydrogen storage materials [J]. Chin. Sci. Bull., 2022, 67: 2158 doi: 10.1360/TB-2021-0430
	张秋雨, 杜四川, 马哲文等. 镁基储氢材料的研究进展 [J]. 科学通报, 2022, 67: 2158
10	Zhou G Z, Li Q. Thermodynamics and kinetics of magnesium-based hydrogen storage material [J]. Chin. J. Nat., 2011, 33: 6
	周国治, 李谦. 镁基储氢材料的热力学和动力学 [J]. 自然杂志, 2011, 33: 6
11	Liu J, Li Q, Zhou G Z, et al. Model investigation of hydrogen absorption and desorption kinetics of nanocrystalline magnesium [J]. Rare Met. Mater. Eng., 2007, 36: 1802
	刘静, 李谦, 周国治等. 纳米晶镁粉的吸放氢动力学模型分析 [J]. 稀有金属材料与工程, 2007, 36: 1802
12	Wu G X, Zhang J Y, Wu Y Q, et al. First-principle calculations of the adsorption, dissociation and diffusion of hydrogen on the Mg (0001) surface [J]. Acta Phys. Chim. Sin., 2008, 24: 55 doi: 10.1016/S1872-1508(08)60006-6
13	Zeng X Q, Ding W J, Ying Y J, et al. Research progress of Mg-based energy materials [J]. Mater. China, 2011, 30(2): 35
	曾小勤, 丁文江, 应燕君等. 镁基能源材料研究进展 [J]. 中国材料进展, 2011, 30(2): 35
14	Wu X J, Xue H Q, Peng Y, et al. Research progress of Mg and Mg-based alloy hydrogen storage materials [J]. Rare Met. Mater. Eng., 2022, 51: 727
	武晓娟, 薛华庆, 彭涌等. 镁及镁合金储氢材料的研究进展 [J]. 稀有金属材料与工程, 2022, 51: 727
15	El-Eskandarany M S, Shaban E, Aldakheel F, et al. Synthetic nanocomposite MgH₂/5 wt.% TiMn₂ powders for solid-hydrogen storage tank integrated with PEM fuel cell [J]. Sci. Rep., 2017, 7: 13296 doi: 10.1038/s41598-017-13483-0 pmid: 29038594
16	Lin H J, Lu Y S, Zhang L T, et al. Recent advances in metastable alloys for hydrogen storage: A review [J]. Rare Met., 2022, 41: 1797 doi: 10.1007/s12598-021-01917-8
17	Ding X, Chen R R, Zhang J X, et al. Recent progress on enhancing the hydrogen storage properties of Mg-based materials via fabricating nanostructures: A critical review [J]. J. Alloys Compd., 2022, 897: 163137 doi: 10.1016/j.jallcom.2021.163137
18	Liu J, Li Q, Zhou G Z. La_0.67Mg_0.33Ni₃ alloy prepared by magnetic field assisted sintering synthesis [J]. Rare Met. Mater. Eng., 2013, 42: 392
	刘静, 李谦, 周国治. 磁场辅助烧结法制备La₀ . ₆₇Mg 0.33Ni3储氢合金 [J]. 稀有金属材料与工程, 2013, 42: 392
19	Shang Y Y, Pistidda C, Gizer G, et al. Mg-based materials for hydrogen storage [J]. J. Magnes. Alloy., 2021, 9: 1837 doi: 10.1016/j.jma.2021.06.007
20	House S D, Vajo J J, Ren C, et al. Effect of ball-milling duration and dehydrogenation on the morphology, microstructure and catalyst dispersion in Ni-catalyzed MgH₂ hydrogen storage materials [J]. Acta Mater., 2015, 86: 55 doi: 10.1016/j.actamat.2014.11.047
21	Li W Y, Li C S, Ma H, et al. Magnesium nanowires: Enhanced kinetics for hydrogen absorption and desorption [J]. J. Am. Chem. Soc., 2007, 129: 6710 pmid: 17488082
22	Shao H Y, Xin G B, Zheng J, et al. Nanotechnology in Mg-based materials for hydrogen storage [J]. Nano Energy, 2012, 1: 590 doi: 10.1016/j.nanoen.2012.05.005
23	Huang Y Q, Xia G L, Chen J, et al. One-step uniform growth of magnesium hydride nanoparticles on graphene [J]. Prog. Natl. Sci., 2017, 27: 81 doi: 10.1016/j.pnsc.2016.12.015
24	Li Q, Zhou G Z. Relationships between key phases and their interfaces with properties in rare earth-magnesium alloys [J]. Chin. J. Nonferrous Met., 2019, 29: 1934
	李谦, 周国治. 稀土镁合金中关键相及其界面与性能的相关性 [J]. 中国有色金属学报, 2019, 29: 1934
25	Ouyang L Z, Liu F, Wang H, et al. Magnesium-based hydrogen storage compounds: A review [J]. J. Alloys Compd., 2020, 832: 154865 doi: 10.1016/j.jallcom.2020.154865
26	Ouyang L Z, Qin F Z, Zhu M. The hydrogen storage behavior of Mg₃La and Mg₃LaNi_0.1 [J]. Scr. Mater., 2006, 55: 1075 doi: 10.1016/j.scriptamat.2006.08.052
27	Sun D L, Gingl F, Nakamura Y, et al. In situ X-ray diffraction study of hydrogen-induced phase decomposition in LaMg₁₂ and La₂Mg₁₇ [J]. J. Alloys Compd., 2002, 333: 103 doi: 10.1016/S0925-8388(01)01712-1
28	Zhang X, Kevorkov D, Pekguleryuz M O. Study on the binary intermetallic compounds in the Mg-Ce system [J]. Intermetallics, 2009, 17: 496 doi: 10.1016/j.intermet.2009.01.002
29	Zhai C, Luo Q, Cai Q, et al. Thermodynamically analyzing the formation of Mg₁₂Nd and Mg₄₁Nd₅ in Mg-Nd system under a static magnetic field [J]. J. Alloys Compd., 2019, 773: 202 doi: 10.1016/j.jallcom.2018.09.203
30	Zhang J, Mao C, Long C G, et al. Phase stability, elastic properties and electronic structures of Mg-Y intermetallics from first-principles calculations [J]. J. Magnes. Alloy., 2015, 3: 127 doi: 10.1016/j.jma.2015.03.003
31	Ishikawa K, Kawasaki T, Yamada Y. Hydrogenation behavior of Mg₈₅Zn₆Y₉ crystalline alloy with long period stacking ordered structure [J]. Int. J. Hydrogen Energy, 2015, 40: 13014 doi: 10.1016/j.ijhydene.2015.07.103
32	Zhang Q A, Liu D D, Wang Q Q, et al. Superior hydrogen storage kinetics of Mg₁₂YNi alloy with a long-period stacking ordered phase [J]. Scr. Mater., 2011, 65: 233 doi: 10.1016/j.scriptamat.2011.04.014
33	Chen R R, Ding X, Chen X Y, et al. In-situ hydrogen-induced evolution and de-/hydrogenation behaviors of the Mg₉₃Cu_{7 -} _x Y _x alloys with equalized LPSO and eutectic structure [J]. Int. J. Hydrogen Energy, 2019, 44: 21999 doi: 10.1016/j.ijhydene.2019.06.089
34	Nakamura J, Iwase K, Hayakawa H, et al. Structural study of La₄MgNi₁₉ hydride by in situ X-ray and neutron powder diffraction [J]. J. Phys. Chem., 2009, 113C: 5853
35	Zhang Q A, Fang M H, Si T Z, et al. Phase stability, structural transition, and hydrogen absorption-desorption features of the polymorphic La₄MgNi₁₉ compound [J]. J. Phys. Chem., 2010, 114C: 11686
36	Li Q, Luo Q, Gu Q F. Insights into the composition exploration of novel hydrogen storage alloys: Evaluation of the Mg-Ni-Nd-H phase diagram [J]. J. Mater. Chem., 2017, 5A: 3848
37	Luo Q, Gu Q F, Liu B, et al. Achieving superior cycling stability by in situ forming NdH₂-Mg-Mg₂Ni nanocomposites [J]. J. Mater. Chem., 2018, 6A: 23308
38	Liu J, Zhang X, Li Q, et al. Investigation on kinetics mechanism of hydrogen absorption in the La₂Mg₁₇-based composites [J]. Int. J. Hydrogen Energy, 2009, 34: 1951 doi: 10.1016/j.ijhydene.2008.12.040
39	Pei L C, Han S M, Wang J S, et al. Hydrogen storage properties and phase structures of RMg₂Ni (R = La, Ce, Pr, Nd) alloys [J]. Mater. Sci. Eng., 2012, B177: 1589
40	Son V B, Volodin A A, Denys R V, et al. Hydrogen sorption and electrochemical properties of intermetallic compounds La₂MgNi₉ and La_1.9Mg_1.1Ni₉ [J]. Russ. Chem. Bull., 2016, 65: 1971 doi: 10.1007/s11172-016-1538-1
41	Li H X, Wan C B, Li X C, et al. Structural, hydrogen storage, and electrochemical performance of LaMgNi₄ alloy and theoretical investigation of its hydrides [J]. Int. J. Hydrogen Energy, 2022, 47: 1723 doi: 10.1016/j.ijhydene.2021.10.135
42	Liu Y F, Pan H G, Gao M X, et al. Investigation on the structure and electrochemical properties of the rare-earth Mg-based hydrogen storage electrode alloys [J]. Acta Metall. Sin., 2003, 39: 666
	刘永锋, 潘洪革, 高明霞等. 稀土镁基贮氢电极合金的结构与电化学性能研究 [J]. 金属学报, 2003, 39: 666
43	Luo Q, Guo Y L, Liu B, et al. Thermodynamics and kinetics of phase transformation in rare earth-magnesium alloys: A critical review [J]. J. Mater. Sci. Technol., 2020, 44: 171 doi: 10.1016/j.jmst.2020.01.022
44	Zhang J X, Ding X, Chen R R, et al. Design of LPSO-introduced Mg₉₆Y₂Zn₂ alloy and its improved hydrogen storage properties catalyzed by in-situ formed YH₂ [J]. J. Alloys Compd., 2022, 910: 164832 doi: 10.1016/j.jallcom.2022.164832
45	Sun Y, Wang D B, Wang J M, et al. Hydrogen storage properties of ultrahigh pressure Mg₁₂NiY alloys with a superfine LPSO structure [J]. Int. J. Hydrogen Energy, 2019, 44: 23179 doi: 10.1016/j.ijhydene.2019.06.191
46	Zhang J X, Ding X, Chen R R, et al. Comparative study of solid-solution treatment and hot-extrusion on hydrogen storage performance for Mg₉₆Y₂Zn₂ alloy: The nonnegligible role of elements distribution [J]. J. Power Sources, 2022, 548: 232037 doi: 10.1016/j.jpowsour.2022.232037
47	He J H, Zhang J, Zhou X J, et al. Hydrogen storage properties of Mg_98.5Gd₁Zn_0.5 and Mg_98.5Gd_0.5Y_0.5Zn_0.5 alloys containing LPSO phases [J]. Int. J. Hydrogen Energy, 2021, 46: 32949 doi: 10.1016/j.ijhydene.2021.07.140
48	Li Q. Design of Mg-based multicomponent hydrogen storage alloys based on thermodynamic and kinetic calculations and physical chemistry of hydrogenation reaction [J]. Mater. China, 2015, 34: 698
	李谦. 基于热力学和动力学计算的镁基多元储氢合金设计及其氢化反应的物理化学 [J]. 中国材料进展, 2015, 34: 698
49	Zhao X J, Li Q, Chou K, et al. Effect of Co substitution for Ni and magnetic-heat treatment on the structures and electrochemical properties of La-Mg-Ni-type hydrogen storage alloys [J]. J. Alloys Compd., 2009, 473: 428 doi: 10.1016/j.jallcom.2008.05.108
50	Conrad H, Ertl G, Latta E E. Adsorption of hydrogen on palladium single crystal surfaces [J]. Surf. Sci., 1974, 41: 435 doi: 10.1016/0039-6028(74)90060-0
51	Han Z Y, Chen H P, Zhou S X. Dissociation and diffusion of hydrogen on defect-free and vacancy defective Mg (0001) surfaces: A density functional theory study [J]. Appl. Surf. Sci., 2017, 394: 371 doi: 10.1016/j.apsusc.2016.10.101
52	Botta W J, Jorge Jr A M, Veron M, et al. H-sorption properties and structural evolution of Mg processed by severe plastic deformation [J]. J. Alloys Compd., 2013, 580(suppl.1) : S187
53	Song W J, Dong H P, Zhang G, et al. Enhanced hydrogen absorption kinetics by introducing fine eutectic and long-period stacking ordered structure in ternary eutectic Mg-Ni-Y alloy [J]. J. Alloys Compd., 2020, 820: 153187 doi: 10.1016/j.jallcom.2019.153187
54	Liang H, Li J, Shen X H, et al. The study of amorphous La@Mg catalyst for high efficiency hydrogen storage [J]. Int. J. Hydrogen Energy, 2022, 47: 18404 doi: 10.1016/j.ijhydene.2022.04.032
55	Hongo T, Edalati K, Arita M, et al. Significance of grain boundaries and stacking faults on hydrogen storage properties of Mg₂Ni intermetallics processed by high-pressure torsion [J]. Acta Mater., 2015, 92: 46 doi: 10.1016/j.actamat.2015.03.036
56	Ding X, Chen R R, Chen X Y, et al. A novel method towards improving the hydrogen storage properties of hypoeutectic Mg-Ni alloy via ultrasonic treatment [J]. J. Magnes. Alloy., 2021, doi: 10.1016/j.jma.2021.06.003
57	Fu H, Wu W S, Dou Y, et al. Hydrogen diffusion kinetics and structural integrity of superhigh pressure Mg-5 wt% Ni alloys with dendrite interface [J]. J. Power Sources, 2016, 320: 212 doi: 10.1016/j.jpowsour.2016.04.045
58	Luo Q, Li J D, Li B, et al. Kinetics in Mg-based hydrogen storage materials: Enhancement and mechanism [J]. J. Magnes. Alloy., 2019, 7: 58 doi: 10.1016/j.jma.2018.12.001
59	Lin H J, Ouyang L Z, Wang H, et al. Hydrogen storage properties of Mg-Ce-Ni nanocomposite induced from amorphous precursor with the highest Mg content [J]. Int. J. Hydrogen Energy, 2012, 37: 14329 doi: 10.1016/j.ijhydene.2012.07.073
60	Knotek V, Ekrt O, Michalcová A, et al. Electrochemical hydriding of nanocrystalline Mg-Ni-X (X = Co, Mn, Nd) alloys prepared by mechanical alloying and spark plasma sintering [J]. J. Alloys Compd., 2017, 726: 787 doi: 10.1016/j.jallcom.2017.08.059
61	Song X P, Zhang P L, Pei P, et al. The role of spark plasma sintering on the improvement of hydrogen storage properties of Mg-based composites [J]. Int. J. Hydrogen Energy, 2010, 35: 8080 doi: 10.1016/j.ijhydene.2010.01.048
62	Liu D M, Si T Z, Wang C C, et al. Phase component, microstructure and hydrogen storage properties of the laser sintered Mg-20wt.% LaNi₅ composite [J]. Scr. Mater., 2007, 57: 389 doi: 10.1016/j.scriptamat.2007.05.011
63	Li Q, Wu Z, Lu X G, et al. Hydrogen sorption-desorption properties of Mg-Ni-Ti_0.32Cr_0.35V_0.07Fe_0.26 composite by mechanochemical syntyhsis [J]. Rare Met. Mater. Eng., 2007, 36: 1672
	李谦, 吴铸, 鲁雄刚等. 机械化学法制备Mg-Ni-Ti_0.32Cr_0.35V_0.07-Fe_0.26复合材料的储放氢性能 [J]. 稀有金属材料与工程, 2007, 36: 1672
64	Zhu W H, Zhu M, Luo K C, et al. Mechanical alloying induced solid state reaction and formation of nano-phase composite hydrogen storage alloys in MmNi_{5 -} _x (Co, Al, Mn) _x /Mg system [J]. Acta Metall. Sin., 1999, 35: 541
	朱文辉, 朱敏, 罗堪昌等. 高能球磨在MmNi_{5 -} _x (Co, Al, Mn) _x /Mg体系中诱发的固态反应及纳米相复合储氢合金的形成 [J]. 金属学报, 1999, 35: 541
65	Edalati K, Uehiro R, Fujiwara K, et al. Ultra-severe plastic deformation: Evolution of microstructure, phase transformation and hardness in immiscible magnesium-based systems [J]. Mater. Sci. Eng., 2017, A701: 158
66	Edalati K, Yamamoto A, Horita Z, et al. High-pressure torsion of pure magnesium: Evolution of mechanical properties, microstructures and hydrogen storage capacity with equivalent strain [J]. Scr. Mater., 2011, 64: 880 doi: 10.1016/j.scriptamat.2011.01.023
67	Edalati K, Emami H, Ikeda Y, et al. New nanostructured phases with reversible hydrogen storage capability in immiscible magnesium-zirconium system produced by high-pressure torsion [J]. Acta Mater., 2016, 108: 293 doi: 10.1016/j.actamat.2016.02.026
68	Edalati K, Emami H, Staykov A, et al. Formation of metastable phases in magnesium-titanium system by high-pressure torsion and their hydrogen storage performance [J]. Acta Mater., 2015, 99: 150 doi: 10.1016/j.actamat.2015.07.060
69	Fujiwara K, Uehiro R, Edalati K, et al. New Mg-V-Cr BCC alloys synthesized by high-pressure torsion and ball milling [J]. Mater. Trans., 2018, 59: 741 doi: 10.2320/matertrans.M2018001
70	Edalati K, Uehiro R, Ikeda Y, et al. Design and synthesis of a magnesium alloy for room temperature hydrogen storage [J]. Acta Mater., 2018, 149: 88 doi: 10.1016/j.actamat.2018.02.033
71	Chiu C, Huang S J, Chou T Y, et al. Improving hydrogen storage performance of AZ31 Mg alloy by equal channel angular pressing and additives [J]. J. Alloys Compd., 2018, 743: 437 doi: 10.1016/j.jallcom.2018.01.412
72	Jorge Jr A M, Prokofiev E, De Lima G F, et al. An investigation of hydrogen storage in a magnesium-based alloy processed by equal-channel angular pressing [J]. Int. J. Hydrogen Energy, 2013, 38: 8306 doi: 10.1016/j.ijhydene.2013.03.158
73	Jorge Jr A M, De Lima G F, Triques M R M, et al. Correlation between hydrogen storage properties and textures induced in magnesium through ECAP and cold rolling [J]. Int. J. Hydrogen Energy, 2014, 39: 3810 doi: 10.1016/j.ijhydene.2013.12.154
74	Wen J, De Rango P, Allain N, et al. Improving hydrogen storage performance of Mg-based alloy through microstructure optimization [J]. J. Power Sources, 2020, 480: 228823 doi: 10.1016/j.jpowsour.2020.228823
75	Zhang J G, Huang W C, Liu J W, et al. Microstructural evolution and hydrogen storage properties of Mg_{1 -} _x Nb _x (x = 0.17-0.76) alloy films via co-sputtering [J]. Int. J. Hydrogen Energy, 2019, 44: 29100 doi: 10.1016/j.ijhydene.2019.07.101
76	Norberg N S, Arthur T S, Fredrick S J, et al. Size-dependent hydrogen storage properties of Mg nanocrystals prepared from solution [J]. J. Am. Chem. Soc., 2011, 133: 10679 doi: 10.1021/ja201791y pmid: 21671640
77	Liu Y N, Zou J X, Zeng X Q, et al. Study on hydrogen storage properties of Mg-X (X = Fe, Co, V) nano-composites co-precipitated from solution [J]. RSC Adv., 2015, 5: 7687 doi: 10.1039/C4RA12977F
78	Cui J, Liu J W, Wang H, et al. Mg-TM (TM: Ti, Nb, V, Co, Mo or Ni) core-shell like nanostructures: Synthesis, hydrogen storage performance and catalytic mechanism [J]. J. Mater. Chem., 2014, 2A: 9645
79	Cho E S, Ruminski A M, Aloni S, et al. Graphene oxide/metal nanocrystal multilaminates as the atomic limit for safe and selective hydrogen storage [J]. Nat. Commun., 2016, 7: 10804 doi: 10.1038/ncomms10804 pmid: 26902901
80	Hu Y Q, Zhang H F, Wang A M, et al. Catalysis functions of amorphous TiMn_1.5 during the hydriding process of magnesium [J]. Acta Metall. Sin., 2003, 39: 1094
	胡业奇, 张海峰, 王爱民等. TiMn_1.5非晶在镁氢化过程中催化作用的研究 [J]. 金属学报, 2003, 39: 1094
81	Qi Y, Zhang Y H, Zhang W, et al. Hydrogen storage thermodynamics and kinetics of RE-Mg-Ni-based alloys prepared by mechanical milling [J]. Int. J. Hydrogen Energy, 2017, 42: 18473 doi: 10.1016/j.ijhydene.2017.04.180
82	Zhang Y H, Feng D C, Sun H, et al. Structure and electrochemical hydrogen storage characteristics of Ce-Mg-Ni-based alloys synthesized by mechanical milling [J]. J. Rare Earths, 2017, 35: 280 doi: 10.1016/S1002-0721(17)60911-6
83	Zhang Y H, Yuan Z M, Yang T, et al. An investigation on hydrogen storage thermodynamics and kinetics of Pr-Mg-Ni-based PrMg₁₂-type alloys synthesized by mechanical milling [J]. J. Alloys Compd., 2016, 688: 585 doi: 10.1016/j.jallcom.2016.07.246
84	Li J D, Li B, Yu X Q, et al. Geometrical effect in Mg-based metastable nano alloys with BCC structure for hydrogen storage [J]. Int. J. Hydrogen Energy, 2019, 44: 29291 doi: 10.1016/j.ijhydene.2019.01.031
85	Kuji T, Nakayama S, Hanzawa N, et al. Synthesis of nano-structured b.c.c. Mg-Tm-V (Tm = Ni, Co, Cu) alloys and their hydrogen solubility [J]. J. Alloys Compd., 2003, 356-357: 456 doi: 10.1016/S0925-8388(03)00229-9
86	Kondo T, Sakurai Y. Hydrogen absorption-desorption properties of Mg-Ca-V BCC alloy prepared by mechanical alloying [J]. J. Alloys Compd., 2006, 417: 164 doi: 10.1016/j.jallcom.2005.05.054
87	Hitam C N C, Aziz M A A, Ruhaimi A H, et al. Magnesium-based alloys for solid-state hydrogen storage applications: A review [J]. Int. J. Hydrogen Energy, 2021, 46: 31067 doi: 10.1016/j.ijhydene.2021.03.153
88	Ouyang L Z, Yang X S, Zhu M, et al. Enhanced hydrogen storage kinetics and stability by synergistic effects of in situ formed CeH_2.73 and Ni in CeH_2.73-MgH₂-Ni nanocomposites [J]. J. Phys. Chem., 2014, 118C: 7808
89	Li Q, Li Y, Liu B, et al. The cycling stability of the in situ formed Mg-based nanocomposite catalyzed by YH₂ [J]. J. Mater. Chem., 2017, 5A: 17532
90	Wagemans R W P, Van Lenthe J H, De Jongh P E, et al. Hydrogen storage in magnesium clusters: Quantum chemical study [J]. J. Am. Chem. Soc., 2005, 127: 16675 pmid: 16305257
91	Zhang X, Liu Y F, Ren Z H, et al. Realizing 6.7 wt% reversible storage of hydrogen at ambient temperature with non-confined ultrafine magnesium hydrides [J]. Energy Environ. Sci., 2021, 14: 2302 doi: 10.1039/D0EE03160G
92	Tan Z P, Chiu C, Heilweil E J, et al. Thermodynamics, kinetics and microstructural evolution during hydrogenation of iron-doped magnesium thin films [J]. Int. J. Hydrogen Energy, 2011, 36: 9702 doi: 10.1016/j.ijhydene.2011.04.196
93	Li L L, Peng B, Ji W Q, et al. Studies on the hydrogen storage of magnesium nanowires by density functional theory [J]. J. Phys. Chem., 2009, 113C: 3007
94	Shao H Y, Ma W G, Kohno M, et al. Hydrogen storage and thermal conductivity properties of Mg-based materials with different structures [J]. Int. J. Hydrogen Energy, 2014, 39: 9893 doi: 10.1016/j.ijhydene.2014.02.063
95	Zhang Q Y, Zou J X, Ren L, et al. Research development of core-shell nanostructured Mg-based hydrogen storage composite materials [J]. Mater. Sci. Technol., 2020, 28(3): 58 doi: 10.1179/1743284711Y.0000000043
	张秋雨, 邹建新, 任莉等. 核壳结构纳米镁基复合储氢材料研究进展 [J]. 材料科学与工艺, 2020, 28(3): 58
96	Zhang J G, Zhu Y F, Zang X X, et al. Nickel-decorated graphene nanoplates for enhanced H₂ sorption properties of magnesium hydride at moderate temperatures [J]. J. Mater. Chem., 2016, 4A: 2560
97	Lotoskyy M, Denys R, Yartys V A, et al. An outstanding effect of graphite in nano-MgH₂-TiH₂ on hydrogen storage performance [J]. J. Mater. Chem., 2018, 6A: 10740
98	Jeon K J, Moon H R, Ruminski A M, et al. Air-stable magnesium nanocomposites provide rapid and high-capacity hydrogen storage without using heavy-metal catalysts [J]. Nat. Mater., 2011, 10: 286 doi: 10.1038/nmat2978
99	Iwakura C, Nohara S, Zhang S G, et al. Hydriding and dehydriding characteristics of an amorphous Mg₂Ni-Ni composite [J]. J. Alloys Compd., 1999, 285: 246 doi: 10.1016/S0925-8388(98)00966-9
100	Isogai K, Shoji T, Kimura H, et al. Increase in thermal stability of Mg₆₂Ni₃₃Ca₅ amorphous alloy by absorption of hydrogen [J]. Mater. Trans., JIM, 2000, 41: 1486 doi: 10.2320/matertrans1989.41.1486
101	Zhang Q A, Zhang L X, Wang Q Q. Crystallization behavior and hydrogen storage kinetics of amorphous Mg₁₁Y₂Ni₂ alloy [J]. J. Alloys Compd., 2013, 551: 376 doi: 10.1016/j.jallcom.2012.11.046
102	Zhang Y H, Wang H T, Zhai T T, et al. Hydrogen storage characteristics of the nanocrystalline and amorphous Mg-Nd-Ni-Cu-based alloys prepared by melt spinning [J]. Int. J. Hydrogen Energy, 2014, 39: 3790 doi: 10.1016/j.ijhydene.2013.12.139
103	Han B, Yu S B, Wang H, et al. Nanosize effect on the hydrogen storage properties of Mg-based amorphous alloy [J]. Scr. Mater., 2022, 216: 114736 doi: 10.1016/j.scriptamat.2022.114736
104	Xu C, Lin H J, Edalati K, et al. Superior hydrogenation properties in a Mg₆₅Ce₁₀Ni₂₀Cu₅ nanoglass processed by melt-spinning followed by high-pressure torsion [J]. Scr. Mater., 2018, 152: 137 doi: 10.1016/j.scriptamat.2018.04.036
105	Edalati K, Shao H Y, Emami H, et al. Activation of titanium-vanadium alloy for hydrogen storage by introduction of nanograins and edge dislocations using high-pressure torsion [J]. Int. J. Hydrogen Energy, 2016, 41: 8917 doi: 10.1016/j.ijhydene.2016.03.146
106	Ham B, Junkaew A, Arróyave R, et al. Size and stress dependent hydrogen desorption in metastable Mg hydride films [J]. Int. J. Hydrogen Energy, 2014, 39: 2597 doi: 10.1016/j.ijhydene.2013.12.017
107	Mooij L P A, Baldi A, Boelsma C, et al. Interface energy controlled thermodynamics of nanoscale metal hydrides [J]. Adv. Energy Mater., 2011, 1: 754 doi: 10.1002/aenm.201100316
108	Ouyang L Z, Ye S Y, Dong H W, et al. Effect of interfacial free energy on hydriding reaction of Mg-Ni thin films [J]. Appl. Phys. Lett., 2007, 90: 021917
109	Fujii H, Higuchi K, Yamamoto K, et al. Remarkable hydrogen storage, structural and optical properties in multi-layered Pd/Mg thin films [J]. Mater. Trans., 2002, 43: 2721 doi: 10.2320/matertrans.43.2721
110	Ouyang L Z, Tang J J, Zhao Y J, et al. Express penetration of hydrogen on Mg (10 1 ¯ 3) along the close-packed-planes [J]. Sci. Rep., 2015, 5: 10776 doi: 10.1038/srep10776
111	El-Eskandarany M S, Banyan M, Al-Ajmi F. Cold-rolled magnesium hydride strips decorated with cold-sprayed Ni powders for solid-state-hydrogen storage [J]. Int. J. Hydrogen Energy, 2019, 44: 16852 doi: 10.1016/j.ijhydene.2019.04.204
112	Karst J, Sterl F, Linnenbank H, et al. Watching in situ the hydrogen diffusion dynamics in magnesium on the nanoscale [J]. Sci. Adv., 2020, 6: eaaz0566 doi: 10.1126/sciadv.aaz0566
113	Krystian M, Zehetbauer M J, Kropik H, et al. Hydrogen storage properties of bulk nanostructured ZK60 Mg alloy processed by equal channel angular pressing [J]. J. Alloys Compd., 2011, 509: S449 doi: 10.1016/j.jallcom.2011.01.029
114	Faisal M, Gupta A, Shervani S, et al. Enhanced hydrogen storage in accumulative roll bonded Mg-based hybrid [J]. Int. J. Hydrogen Energy, 2015, 40: 11498 doi: 10.1016/j.ijhydene.2015.03.095
115	Faisal M, Balani K, Subramaniam A. Cross-sectional TEM investigation of Mg-LaNi₅-Soot hybrids for hydrogen storage [J]. Int. J. Hydrogen Energy, 2021, 46: 5507 doi: 10.1016/j.ijhydene.2020.11.134
116	Patelli N, Migliori A, Morandi V, et al. Interfaces within biphasic nanoparticles give a boost to magnesium-based hydrogen storage [J]. Nano Energy, 2020, 72: 104654 doi: 10.1016/j.nanoen.2020.104654
117	Zhang Y, Zheng J G, Lu Z Y, et al. Boosting the hydrogen storage performance of magnesium hydride with metal organic framework-derived cobalt@nickel oxide bimetallic catalyst [J]. Chin. J. Chem. Eng., 2022, 52: 161 doi: 10.1016/j.cjche.2022.06.026
118	Aymonier C, Denis A, Roig Y, et al. Supported metal NPs on magnesium using SCFs for hydrogen storage: Interface and interphase characterization [J]. J. Supercrit. Fluids, 2010, 53: 102 doi: 10.1016/j.supflu.2010.02.012

[1]	LIU Junpeng, CHEN Hao, ZHANG Chi, YANG Zhigang, ZHANG Yong, DAI Lanhong. Progress of Cryogenic Deformation and Strengthening-Toughening Mechanisms of High-Entropy Alloys[J]. 金属学报, 2023, 59(6): 727-743.
[2]	MIAO Junwei, WANG Mingliang, ZHANG Aijun, LU Yiping, WANG Tongmin, LI Tingju. Tribological Properties and Wear Mechanism of AlCr_1.3TiNi₂ Eutectic High-Entropy Alloy at Elevated Temperature[J]. 金属学报, 2023, 59(2): 267-276.
[3]	CHEN Fei, QIU Pengcheng, LIU Yang, SUN Bingbing, ZHAO Haisheng, SHEN Qiang. Microstructure and Mechanical Properties of NiTi Shape Memory Alloys by In Situ Laser Directed Energy Deposition[J]. 金属学报, 2023, 59(1): 180-190.
[4]	HAN Luhui, KE Haibo, ZHANG Pei, SANG Ge, HUANG Huogen. Kinetic Crystallization Behavior of Amorphous U₆₀Fe_27.5Al_12.5 Alloy[J]. 金属学报, 2022, 58(10): 1316-1324.
[5]	. Precipitation Strengthening in Titanium Alloys from First Principles Investigation[J]. 金属学报, 0, (): 0-0.
[6]	LIU Shuaishuai, HOU Chaonan, WANG Engang, JIA Peng. Plastic Rheological Behaviors of Zr₆₁Cu₂₅Al₁₂Ti₂ and Zr_52.5Cu_17.9Ni_14.6Al₁₀Ti₅ Amorphous Alloys in the Supercooled Liquid Region[J]. 金属学报, 2022, 58(6): 807-815.
[7]	ZHANG Jinyong, ZHAO Congcong, WU Yijin, CHEN Changjiu, CHEN Zheng, SHEN Baolong. Structural Characteristic and Crystallization Behavior of the (Fe_0.33Co_0.33Ni_0.33)₈₄_-_x Cr₈Mn₈B _x High-Entropy-Amorphous Alloy Ribbons[J]. 金属学报, 2022, 58(2): 215-224.
[8]	ZHU Min, OUYANG Liuzhang. Kinetics Tuning and Electrochemical Performance of Mg-Based Hydrogen Storage Alloys[J]. 金属学报, 2021, 57(11): 1416-1428.
[9]	ZUO Liang, LI Zongbin, YAN Haile, YANG Bo, ZHAO Xiang. Texturation and Functional Behaviors of Polycrystalline Ni-Mn-X Phase Transformation Alloys[J]. 金属学报, 2021, 57(11): 1396-1415.
[10]	YANG Qun, PENG Sixu, BU Qingzhou, YU Haibin. Revealing Glass Transition and Supercooled Liquid in Ni₈₀P₂₀ Metallic Glass[J]. 金属学报, 2021, 57(4): 553-558.
[11]	BI Jiazi, LIU Xiaobin, LI Ran, ZHANG Tao. Tribological Properties of Polyalphaolefin (PAO6) Lubricant Modified with Particles Additives of Metallic Glass[J]. 金属学报, 2021, 57(4): 559-566.
[12]	QU Ruitao, WANG Xiaodi, WU Shaojie, ZHANG Zhefeng. Research Progress in Shear Banding Deformation and Fracture Mechanisms of Metallic Glasses[J]. 金属学报, 2021, 57(4): 453-472.
[13]	PAN Jie, DUAN Fenghui. Rejuvenation Behaviors in Metallic Glasses[J]. 金属学报, 2021, 57(4): 439-452.
[14]	LI Ning, HUANG Xin. Recent Advances on 3D Printed Bulk Metallic Glasses[J]. 金属学报, 2021, 57(4): 529-541.
[15]	LIU Riping, MA Mingzhen, ZHANG Xinyu. New Development of Research on Casting of Bulk Amorphous Alloys[J]. 金属学报, 2021, 57(4): 515-528.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed