Effect of Electromagnetic Stirring on Microstructure and Mechanical Properties of TiB2 Particle-Reinforced Steel
ZHANG Lin1, GUO Xiao1,2, GAO Jianwen1, DENG Anyuan1, WANG Engang1()
1 Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University, Shenyang 110819, China 2 School of Metallurgy, Northeastern University, Shenyang 110819, China
Cite this article:
ZHANG Lin, GUO Xiao, GAO Jianwen, DENG Anyuan, WANG Engang. Effect of Electromagnetic Stirring on Microstructure and Mechanical Properties of TiB2 Particle-Reinforced Steel. Acta Metall Sin, 2020, 56(9): 1239-1246.
TiB2 is a promising strengthening phase in steels applying in lightweight transportation systems due to its high Young's modulus and low density. However, the density difference between TiB2 particles and matrix leads to segregation during solidification. TiB2 particle-reinforced steels were solidified with a vertical linear-type electromagnetic stirring device. The effects of electromagnetic stirring on the morphology and size distribution of TiB2 particles were studied. Vickers hardness, mechanical properties in the tensile test were also discussed. The results show that electromagnetic stirring effectively refined the primary TiB2 particles in the steel, and the average particle size decreased with the increase of exciting current. The particles distributed dispersively and the structure was more homogenous under a higher exciting current. Besides, the defects of crackle around particles were eliminated under high current. Electromagnetic stirring reduced the macrosegregation of TiB2 particle-reinforced steels, which decreased the hardness discrepancy in the ingot at various heights. A higher exciting current attributed to higher average hardness, and the steel reached a hardness of 275 HV under 350 A exciting current. The ultimate tensile strength and the strain at break were both enhanced by electromagnetic stirring, and reached 520.2 MPa and 8.5% respectively under an exciting current of 350 A. The refinement of particles was caused by the smashing process under a strong convection driven by the moving magnetic field, and the effect of electromagnetic force acting on the particles. The influence factors of electromagnetic force were analyzed, which show the force increases with increasing magnetic intensity, decreases with increasing temperature of melt, and increases with increasing particle size.
Fig.1 Maximum values of magnetic flux density at various distances from the surface of electromagnetic stirrer
Fig.2 XRD spectra of TiB2 particle-reinforced steel with and without electromagnetic stirring (EMS)
Fig.3 Microstructures of TiB2 particle-reinforced steel under magnetic field with various current intensities
Fig.4 Morphologies of TiB2 particles in ingots under various current intensities (a~d) and EDS of points 1 (e) and 2 (f) in Fig.4a
Fig.5 The sizes of primary TiB2 particles in ingots under magnetic field with various current intensities
Fig.6 Hardness distributions of ingots under EMS with various current intensities
Fig.7 Tensile strengthes (a) and typical stress-strain curves (b) of ingots under EMS with various current intensity
Fig.8 Schematic of driving effect of magnetic field (B) on the melt of Fe-TiB2 particle-reinforced steel (a), and α value change with melt temperature and particle size (b)
[1]
Springer H, Fernandez R A, Duarte M J, et al. Microstructure refinement for high modulus in-situ metal matrix composite steels via controlled solidification of the system Fe-TiB2 [J]. Acta Mater., 2015, 96: 47
doi: 10.1016/j.actamat.2015.06.017
[2]
Munro R G. Material properties of titanium diboride [J]. J. Res. Nat. Inst. Stand. Technol., 2000, 105: 709
doi: 10.6028/jres
[3]
Huynh X K, Bae S W, Kim J S. In situ fabrication of Fe-TiB2 nanocomposite powder by planetary ball milling and subsequent heat-treatment of FeB and TiH2 powder mixture [J]. Korean J. Met. Mater., 2017, 55: 10
doi: 10.3365/KJMM.2016.
[4]
Storozhenko M S, Umanskii A P, Terentiev A E, et al. Effect of the structure of TiB2-(Fe-Mo) plasma coatings on mechanical and tribotechnical properties [J]. Powder Metall. Met. Ceram., 2017, 56: 60
doi: 10.1007/s11106-017-9872-x
[5]
Huynh X K, Kim J S. Fabrication of sintered compact of Fe-TiB2 composites by pressureless sintering of (FeB+TiH2) powder mixture [J]. J. Korean Powder Metall. Inst., 2016, 23: 282
doi: 10.4150/KPMI.
[6]
Lartigue-Korinek S, Walls M, Haneche N, et al. Interfaces and defects in a successfully hot-rolled steel-based composite Fe-TiB2 [J]. Acta Mater., 2015, 98: 297
doi: 10.1016/j.actamat.2015.07.024
[7]
Antoni-Zdziobek A, Gospodinova M, Bonnet F, et al. Experimental determination of solid-liquid equilibria with reactive components: Example of the Fe-Ti-B ternary system [J]. J. Phase Equilib. Diffus., 2014, 35: 701
doi: 10.1007/s11669-014-0355-1
[8]
Aparicio-Fernández R, Springer H, Szczepaniak A, et al. In-situ metal matrix composite steels: Effect of alloying and annealing on morphology, structure and mechanical properties of TiB2 particle containing high modulus steels [J]. Acta Mater., 2016, 107: 38
doi: 10.1016/j.actamat.2016.01.048
[9]
Baron C, Springer H, Raabe D. Efficient liquid metallurgy synthesis of Fe-TiB2 high modulus steels via in-situ reduction of titanium oxides [J]. Mater. Des., 2016, 97: 357
doi: 10.1016/j.matdes.2016.02.076
[10]
Cha L M, Lartigue-Korinek S, Walls M, et al. Interface structure and chemistry in a novel steel-based composite Fe-TiB2 obtained by eutectic solidification [J]. Acta Mater., 2012, 60: 6382
doi: 10.1016/j.actamat.2012.08.017
[11]
Hadjem-Hamouche Z, Chevalier J P, Cui Y T, et al. Deformation behavior and damage evaluation in a new titanium diboride (TiB2) steel-based composite [J]. Steel Res. Int., 2012, 83: 538
doi: 10.1002/srin.v83.6
[12]
Li Y Z, Luo Z C, Yi H L, et al. Damage mechanisms of a TiB2-reinforced steel matrix composite for lightweight automotive application [J]. Metall. Mater. Trans., 2016, 3E: 203
[13]
Zhang H, Springer H, Aparicio-Fernández R, et al. Improving the mechanical properties of Fe-TiB2 high modulus steels through controlled solidification processes [J]. Acta Mater., 2016, 118: 187
doi: 10.1016/j.actamat.2016.07.056
[14]
Kim H S, Chang C H, Lee H G. Evolution of inclusions and resultant microstructural change with Mg addition in Mn/Si/Ti deoxidized steels [J]. Scr. Mater., 2005, 53: 1253
[15]
Zhang L, Gao J W, Huang M H, et al. Effect of Ce addition on the as-cast and as-forged microstructure of Fe-TiB2 composites [J]. JOM, 2019, 71: 4144
[16]
Xu Y, Xu R J, Fan Z J, et al. Analysis of cracking phenomena in continuous casting of 1Cr13 stainless steel billets with final electromagnetic stirring [J]. Int. J. Miner. Metall. Mater., 2016, 23: 534
[17]
Xu Y, Wang E G, Li Z, et al. Effects of vertical electromagnetic stirring on grain refinement and macrosegregation control of bearing steel billet in continuous casting [J]. J. Iron Steel Res. Int., 2017, 24: 483
[18]
Kobayashi S, Ishimura S, Yoshihara M, et al. Factors affecting equiaxed zone generation in electromagnetic stirring [J]. Trans. Iron Steel Inst. Jpn., 1988, 28: 939
[19]
Griffiths W D, McCartney D G. The effect of electromagnetic stirring during solidification on the structure of Al-Si alloys [J]. Mater. Sci. Eng., 1996, A216: 47
[20]
Yamanaka A, Ota K, Terunuma M, et al. Reduction of center porosity of round billet by electromagnetic stirring in horizontal continuous casting [J]. Tetsu Hagané, 1998, 84: 609
Dong Q P, Zhang J M, Zhao X K. Prediction of columnar-to-equiaxed transition and porosity in continuous cast billet [J]. Metall. Res. Technol., 2017, 114: 303
[22]
Kor G J W. Effect of circumferential electromagnetic stirring of steel on inclusion distribution [J]. Trans. Iron Steel Soc. AIME, 1984, 5: 1
[23]
Javurek M, Barna M, Gittler P, et al. Flow modelling in continuous casting of round bloom strands with electromagnetic stirring [J]. Steel Res. Int., 2008, 79: 617
doi: 10.1002/srin.2008.79.issue-8
[24]
Takatani K. Effects of electromagnetic field on fluid flow, heat transfer, and inclusion behavior in a continuous casting process [J]. Magnetohydrodynamics, 1996, 32: 128
[25]
Wang F, Wang E G, Zhang L T, et al. Influence of electromagnetic stirring (EMS) on the microstructure and mechanical property of Incoloy825 superalloy [J]. J. Manuf. Processes, 2017, 26: 364
[26]
Fu Y, Li J W, Song X Y, et al. Restraining solute segregation of Al-1%Si alloy in diverse physical field [J]. Mater. Technol., 2012, 27: 173
[27]
Liu B. The segregation behavior of alloying elements in the Al-5Fe-based alloys during the semisolid deformation [J]. JOM, 2015, 67: 3030
[28]
Jin Y L, Du S L. Precipitation behaviour and control of TiN inclusions in rail steels [J]. Ironmaking Steelmaking, 2018, 45: 224
[29]
Emmerich H, Siquieri R, Jurgk M, et al. A sharp interface model for the morphological evolution of precipitates in Al cast alloys [J]. Philos. Mag. Lett., 2007, 87: 863
[30]
ISO. ISO 6892-1:2009 Metallic materials—Tensile testing-Part 1: Method of test at room temperature [S]. Geneva, Switzerland: International Organization for Standardization (ISO), 2009
[31]
Golak S. Manufacture of locally reinforced composite discs by casting in the alternating electromagnetic field [J]. Adv. Mater. Sci. Eng., 2015, 2015: 681939
[32]
Leenov D, Kolin A. Theory of electromagnetophoresis. I. Magnetohydrodynamic forces experienced by spherical and symmetrically oriented cylindrical particles [J]. J. Chem. Phys., 1954, 22: 683
[33]
Ščepanskis M, Jakovičs A. The magnetohydrodynamic force experienced by spherical iron particles in liquid metal [J]. J. Magn. Magn. Mater., 2016, 403: 30
[34]
McLeod A D, Haggerty J S, Sadoway D R. Electrical resistivities of monocrystalline and polycrystalline TiB2 [J]. J. Am. Ceram. Soc., 1984, 67: 705
[35]
Kita Y, Ohguchi S, Morita Z I. Measurement of electrical resistivity of molten iron, cobalt, and nickel by improved four-probe method [J]. Tetsu Hagané, 1978, 64: 711